Abstract
Granular systems with a wetting liquid phase produce an attractive normal force between the solid grains and a radial force that promotes bonding via neck growth. The classic force balance in the neck region relates the energy ratio of the grain boundary and solid-liquid interfaces to the dihedral angle φ as 2γ SL cos (φ/2)=γ SS . This relation is only applicable when the neck diameter is much larger than the neck thickness. This article presents a detailed analysis of two grains during liquidphase sintering, refining the linkage between the underlying surface energies and the microstructure and apparent effect of grain size on the neck size.
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Liu, J., German, R.M. Microstructure effect on dihedral angle in liquid-phase sintering. Metall Mater Trans A 32, 165–169 (2001). https://doi.org/10.1007/s11661-001-0112-z
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DOI: https://doi.org/10.1007/s11661-001-0112-z