Abstract
Dry separation of iron mineral from low-grade coal-series kaolin in Hubei Province of China was investigated. The structure and chemical composition of the kaolin ore were determined by X-ray diffraction (XRD) and X-ray Fluorescence (XRF) analyses. The narrow particle size range classification, dry magnetic separation and calcination were carried out to evaluate the particle size distribution, and the relation between the content of iron and the whiteness. Experimental results revealed that the highest content of iron (3.70%) in kaolin ore was in the particle size range from 60 to 74 μm, and pyrite was the main occurrence of iron in the kaolin ore. Dry magnetic separation showed that the removal rate of iron in kaolin ore could be increased obviously after calcination, and the rate of iron removal was 60% in the particle size range from 60 to 74 μm. As pyrite can be transformed into hematite through calcination, thermodynamic studies and XRD analysis showed that the maximum content of hematite was obtained at 900 °C, which would be more beneficial to magnetic separation.
Similar content being viewed by others
References
Hong W. Study of Benefication and Purification on Hard Kaolin From Coal Tailings [D]. Wuhan: Wuhan University of Technology, 2014 (in Chinese)
Dai J. Study on Enhancing the Whiteness of Kaolin by Bleaching and Calcining [D]. Xiamen: Xiamen University, 2009 (in Chinese)
Zhao JP, Zhuang XN, Jiang X, et al. Experimental Research on Iron Removal by High-intensity Magnetic Separation for Coal-series Kaolin in North Anhui province[J]. Conservation and Utilization of Mineral Resources, 2002,10(5): 13–15 (in Chinese)
Wang WQ. Experimental Research on Certain Kaolin Deironing and Bleaching in Fuxi [D]. Fuxin: Liaoning Technical University, 2009 (in Chinese)
Zhang HX. Study on Dry Removing Iron From Huaibei Coal Series Kaolin [J]. China Non-metallic Mining Industry Herald, 2012, 3: 27–28
He C. Processes Study on Magnetization Roasting Method to Strengthen Whitening Kaolin by Magnetic Separating Removal Iron Method [D]. Jing Dezhen: Jing Dezhen Ceramic Institute, 2013 (in Chinese)
Fan BW. Heating Phases of Pyrite and Their Magnetic Property and Mechanism [D]. Cheng Du: Cheng Du University of Technology, 2011 (in Chinese)
Xu X. A Research on Processing Parameters of Calcined Kaolin[D]. Beijing: Beijing University of Technology, 2001 (in Chinese)
Lambert JM, Simkovich G and Walker PL. The Kinetics and Mechanism of the Pyrite-to-pyrrhotite Transformation[J]. Metallurgical and Materials Transactions, 1998, 29(B): 385–396
Hu G, Dam-Johansen K, Wedel S, et al. Decomposition and Oxidation of Pyrite[J]. Progress in Energy and Combustion Science, 2006, 32: 295–314
Bhargava SK, Garg A and Subasinghe ND. In Situ High-temperature Phase Transformation Studies on Pyrite [J]. Fuel, 2009,88: 988–993
Uslu T, Atalay U, Arol AI. Effect of Microwave Heating on Magnetic Separation of Pyrite[J]. Colloids and Surfaces, 2003, 225: 161–167
Hong Y and Fegley J. The Kinetics and Mechanism of Pyrite Thermal Decomposition [J]. Phys. Chem., 1997, 101: 1870–1881
Brady PV, Cygan RT, Nagy KL. Molecular Controls on Kaolinite Surface Charge[J]. Journal of Colloid and Interface Science, 1996, 183: 356–364
Bo F, Lu YP, Feng QM,et al. Solution Chemistry of Sodium Silicate and Implications for Pyrite Flotation[J]. Industrial & Engineering Chemistry Research, 2012, 51: 12089–12094
Wilson IR. Kaolin and Halloysite Deposits of China[J]. Clay Minerals, 2004 (39): 1–15
Bundy WM. The Diverse Industrial Applications of Kaolin[J]. The Clay Minerals Society, 1993, 1: 43–74
Haydn HM, Jessiea E K. Engineered Clay Products for the Paper Industry [J]. Applied Clay Science, 2005, 29: 199–206
Chandra B Maury, Sharad G Dixit. High Gradient Magnetic Separation of China Clays [J]. Bull. Mater. Sci., 1988, 10(5): 471–475
Cao ML, Yuan JZ, Li H, et al. Study on Enhancing the Whiteness of Calcined Kaolin by Using Additive[J]. Journal of Wuhan University of Technology, 1997,12(1-2): 42–46
Lei SM, Jin B, Chris Saint, et al. Optimization of an Annular Photoreactor Process for Degradation of Congo Red Using a Newly Synthesized Titania Impregnated Kaolinite Nano-photocatalyst[J]. Separation and Purification Technology, 2009, 67:355–363
Vipasiri Vimonses, Lei SM, Jin B, et al. Adsorption of Congo Red by Three Australian Kaolins[J]. Applied Clay Science, 2009, 43: 465–472
Vipasiri Vimonses, Lei SM, Jin B, et al. Kinetic Study and Equilibrium Isotherm Analysis of Congo Red Adsorption by Clay Materials[J]. Chemical Engineering Journal, 2009,148: 354–364
Author information
Authors and Affiliations
Corresponding author
Additional information
Funded by the Academician Workstation of Yichang HuiLong Science and Technology Co. Ltd., Association of Science and Technology of Hubei Province (No.[2013] 104-22)
Rights and permissions
About this article
Cite this article
Huang, T., Lei, S., Liu, M. et al. Dry separation of iron minerals from low-grade coal-series kaolin. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 30, 935–940 (2015). https://doi.org/10.1007/s11595-015-1253-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11595-015-1253-z