Abstract
The electrochemical behaviors of 2205 duplex stainless steel in NaCl solution with different temperatures and concentrations were studied by gravimetric tests, potentiodynamic polarization, electrochemical impedance spectroscopy and scanning electron microscopy. The experinental results show that temperature and chloride concentration have a great influence on the pitting resistance of 2205 duplex stainless steels. They not only effect the corrosion rate of pitting, but also change the shape of the pits. When NaCl solution was in low concentration and temperature below the critical pitting temperature, pits were very small and scattered with hemisphere-like shape. On the contrary, the pits of 2205 duplex stainless steel were large and sometimes had a lacy cover when the NaCl concentration was higher and the temperature was 70°C.
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Nilsson J -O. Super Duplex Stainless Steels[J]. Material Sci. Technol., 1992, 8: 685
Ivan N Bastos, Sérgio S M Tavares, Francis Dalard, et al. Effect of Microstructure on Corrosion Behavior of Superduplex Stainless Steel at Critical Environment Conditions[J]. Scripta. Mate., 2007, 57(10): 913–916
Perren R A, Suter T A, Uggowitzer P J, et al. Corrosion Resistance of Super Duplex Stainless Steels in Chloride Ion Containing Environments Investigations by Means of a New Microelectrochemical Method I Precipitation-free States[J]. Corros. Sci., 2001, 43:707–726
Chen T H, Wang K L, Yang J R. The Effect of High-temperature Exposure on the Microstructure Stability and Toughness Property in a 2205 Duplex Stainless Steel[J]. Mater. Sci. Eng. A, 2002, 338(1–2): 259–270
Cvijovic Z, Radenkovic G. Micro Structure and Pitting Corrosion Resistance of Annealed Duplex Stainless Steel [J]. Corros. Sci., 2006, 48(12): 3 887–3 906
Garfias-Mesias L F, Sykes J M. Metastable Pitting in 25 Cr Duplex Stainless Steel[J]. Corros. Sci., 1999, 41(5):959–987
Cheng Xue-qun, Li Xiao-gang, Dong Chao-fang. Study on the Passive Film Formed on 2205 Stainless Steel in Acetic Acid by AAS and XPS[J]. Int. J.Miner. Metall. Mater., 2009, 16(2):170–176.
Brigham R J, Tozer E W. Temperature as a Pitting Criterion[J]. Corros. Sci., 1973, 29(1):33–35
Qvarfort R. Critical Pitting Temperature Measurements of Stainless Steels with an Improved Electrochemical Method[J]. Corros. Sci., 1989, 29(8): 987–993
Pistorius P C and Burstein G T. Metastable Pitting Corrosion of Stainless Steel and the Transition to Stability[J]. Phil. Trans. R. Soc. Lond., 1992, 341(1662):531–559
Laycock N J, Moayed M H and Newman R C. Metastable Pitting and the Critical Pitting Temperature[J]. J. Electrochem. Soc., 1998, 145(8): 2 622–2 628
Olefjord I, Wegrelius L. Surface Analysis of Passive State[J]. Corros. Sci., 1990, 31:89–98
Marcus P, Olefjord I. A Round Robin on Combined Electrochemical and AES/ESCA Characterization of the Passive Films on Fe-Cr and Fe-Cr-Mo Alloys[J]. Corros. Sci., 1988, 28: 589–602
Qvarfort R. Some Observations Regarding the Influence of Molybdenum on the Ppitting Corrosion Resistance of Stainless Steels[J]. Corros. Sci., 1998, 40(2–3): 215–223
Liu C, Bi Q, Leyland A, et al. An Electrochemical Impedance Spectroscopy Study of the Corrosion Behaviour of PVD Coated Steels in 0.5 N NaCl Aqueous Solution: Part I. Establishment of Equivalent Eircuits for EIS Data Modeling[J]. Corros. Sci., 2003, 45(6):1 243–1 256
Liu C, Bi Q, Matthews A. EIS Comparison on Corrosion Performance of PVD TiN and CrN Coated Mild Steel in 0.5 N NaCl Aqueous Solution[J]. Corros. Sci., 2001, 43(10):1 953–1 961
Abreu C M, Cristóbal M J, Losada R, et al. High Frequency Impedance Spectroscopy Study of Passive Films Formed on AISI 316 Stainless Steel in Alkaline Medium[J]. J. Electroanal.Chem., 2004, 572(2): 335–345
Qiao Y X, Zheng Y G, Ke W, Okafor P C. Electrochemical Behaviour of High Nitrogen Stainless Steel in Acidic Solutions[J]. Corros. Sci., 2009, 51(5): 979–986
Pourbaix M. Atlas of Electrochemical Equilibria in Aqueous Solutions [M]. Pergamon Press, Oxford, 1966, 256–272
Wang J H, Siu C C, Szklarska-Smialowska Z. Effects of Cl exp — Concentration and Temperature on Pitting of AISI 304 Stainless Steel[J]. Corros., 1988, 44(10):732–737
Olsson C -O A, Landolt D. Passive Films on Stainless Steels-Chemistry, Structure and Growth[J]. Electrochimi. Acta., 2003, 48(9):1 093–1 104
Ernst P, Newman R C. Pit Growth Studies in Stainless Steel Foils. II. Effect of Temperature, Chloride Concentration and Sulphate Addition[J]. Corros. Sci., 2002, 44(5):943–954
Ernst P, Newman R C. Explanation of the Effect of High Chloride Concentration on the Critical Pitting Temperature of Stainless Steel[J]. Corros. Sci., 2007, 49(9):3 705–3 715
Ernst P, Laycock N J, Moayed M H, et al. The Mechanism of Lacy Cover Formation in Pitting[J]. Corros. Sci., 1997, 39(6):1 133–1 136
Moayed M H, Newman R C. Evolution of Current Transients and Morphology of Metastable and Stable Pitting on Stainless Steel Near the Critical Pitting Temperature[J]. Corros. Sci., 2006, 48(4): 1 004–1 018
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Funded by the National Program for Basic Conditions Platform (No.2005DKA10400) and the National Science Foundation of China (No. 50771020)
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Dong, C., Luo, H., Xiao, K. et al. Effect of temperature and Cl− concentration on pitting of 2205 duplex stainless steel. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 26, 641–647 (2011). https://doi.org/10.1007/s11595-011-0283-4
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DOI: https://doi.org/10.1007/s11595-011-0283-4