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Proton diffusion process manganese dioxide for use in rechargeable alkaline zinc manganese dioxide batteries and its electrochemical performance

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Abstract

The aim of the present work is the study of the performances of dry cells containing the electrolytic MnO2, natural MnO2, or a mixture of both. The two components have been characterized by chemical analysis. The continuous discharge tests done on the dry cells based on EMD present a discharge time largely greater than that of the pure NMD; however, the cells containing a mixture present intermediate values of the discharge time. The value of the diffusion coefficient estimated by the GITT or impedance spectroscopy shows that the H+ diffuses more quickly in the EMD variety that in the NMD one.

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Authors and Affiliations

  1. Laboratoire d’énergétique et Electrochimique de Solide, Université de Ferhat Abbas, 19000, Setif, Algeria

    Louiza Ouksel, Rachida Kerkour & Nacer Eddine Chelali

Authors
  1. Louiza Ouksel
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  2. Rachida Kerkour
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  3. Nacer Eddine Chelali
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Correspondence to Rachida Kerkour.

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Ouksel, L., Kerkour, R. & Chelali, N.E. Proton diffusion process manganese dioxide for use in rechargeable alkaline zinc manganese dioxide batteries and its electrochemical performance. Ionics 22, 1751–1757 (2016). https://doi.org/10.1007/s11581-016-1760-8

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  • DOI: https://doi.org/10.1007/s11581-016-1760-8

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