Skip to main content
Log in

Effects of steam on CO2 absorption ability of calcium-based sorbent modified by peanut husk ash

  • Article
  • Published:
Science China Technological Sciences Aims and scope Submit manuscript

Abstract

The CO2 absorption ability of synthetic calcium-based sorbent modified by peanut husk ash (PHA) was tested by Thermal Gravimetric Analyzer (TGA), and the effects of steam and calcination temperature were investigated. The PHA composition was analyzed by X-Ray Fluorescence (XRF), the apparent morphology was characterized by scanning electron microscope (SEM), and the phases of the sorbent before and after calcination were examined by X-ray diffraction (XRD). The addition of PHA effectively improved the cyclic stability of the calcium-based sorbent. The optimal molar ratio of SiO2 in PHA to CaO was around 0.07. Steam had positive effect on keeping porosity of the sorbent at the chemical reaction stage, and improved its CO2 absorption ability. Steam also reduced the diffusion resistance of the product layer, and depressed the influence of high temperature calcination. It was also found that the steam hydration after calcination was an effective way to recover the absorption ability of the sorbent, while the hydration duration of 10 min was enough.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. IPCC. Climate Change 2013-the Physical Science Basis: Working Group I Contribution to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change. Cambridge: Cambridge University Press, 2014

    Google Scholar 

  2. Elwell L C, Grant W S. Technology options for capturing CO2. Power, 2006, 149: 62–65

    Google Scholar 

  3. Curran G P, Fink C E, Gorin E. Carbon dioxide acceptor gasification process, studies of acceptor properties. Adv Chem Ser, 1967, 69: 141–165

    Article  Google Scholar 

  4. Qiao C Z, Xiao Y H, Tian W D, et al. Repetitive calcination-carbonation capability of Ca-based CO2 absorbent. J Chem Ind Eng, 2006, 57: 2953–2958

    Google Scholar 

  5. Li Z S, Cai N S, Huang Y Y, et al. Experimental research of CaO cyclic absorbing CO2. J Combust Sci Tech, 2005, 4: 17

    Google Scholar 

  6. Abanades J C, Anthony E J, Lu D Y, et al. Capture of CO2 from combustion gases in a fluidized bed of CaO. Aiche J, 2004, 50: 1614–1622

    Article  Google Scholar 

  7. Abanades J C, Alvarez D. Conversion limits in the reaction of CO2 with lime. Energy Fuels, 2003, 17: 308–315

    Article  Google Scholar 

  8. Li L, King D L, Nie Z, et al. Magnesia-stabilized calcium oxide absorbents with improved durability for high temperature CO2 capture. Ind Eng Chem Res, 2009, 48: 10604–10613

    Article  Google Scholar 

  9. Witoon T. Characterization of calcium oxide derived from waste eggshell and its application as CO2 sorbent. Ceram Int, 2011, 37: 3291–3298

    Article  Google Scholar 

  10. Luo C, Zheng Y, Ding N, et al. Development and performance of CaO/La2O3sorbents during calcium looping cycles for CO2 capture. Ind Eng Chem Res, 2010, 49: 11778–11784

    Article  Google Scholar 

  11. Fang F, Li Z S, Cai N S. Effects of Ca-based CO2 sorbent type and particle size on multiply carbonation/calcination cycle. J Eng Thermophys, 2008, 29: 699–702

    Google Scholar 

  12. Li Z S, Cai N S, Huang Y Y, et al. Synthesis, experimental studies, and analysis of a new calcium-based carbon dioxide absorbent. Energy Fuels, 2005, 19: 1447–1452

    Article  Google Scholar 

  13. Li Z S, Cai N S, Huang Y Y. Effect of preparation temperature on cyclic CO2capture and multiple carbonation-calcination cycles for a new Ca-based CO2 sorbent. Ind Eng Chem Res, 2006, 45: 1911–1917

    Article  Google Scholar 

  14. Wu R, Wu S. Performance of nano-CaCO3 coated with SiO2 on CO2 adsorption at high temperature (in Chinese). J Chem Ind Eng, 2006, 57: 1722–1726

    Google Scholar 

  15. Huang C H, Chang K P, Yu C T, et al. Development of high-temperature CO2 sorbents made of CaO-based mesoporous silica. Chem Eng J, 2010, 161: 129–135

    Article  Google Scholar 

  16. Al-Azzawi O M, Hofmann C M, Baker G A, et al. Nanosilica-supported polyethoxyamines as low-cost, reversible carbon dioxide sorbents. J Colloid Interf Sci, 2012, 385: 154–159

    Article  Google Scholar 

  17. Real C, Alcala M D, Criado J M. Preparation of silica from rice husks. J Am Ceram Soc, 1996, 79: 2012–2016

    Article  Google Scholar 

  18. Witoon T, Mungcharoen T, Limtrakul J. Biotemplated synthesis of highly stable calcium-based sorbents for CO2 capture via a precipitation method. Appl Energy, 2014, 118: 32–40

    Article  Google Scholar 

  19. Kalapathy U, Proctor A, Shultz J. A simple method for production of pure silica from rice hull ash. Bioresour Technol, 2000, 73: 257–262

    Article  Google Scholar 

  20. Liou T H. Preparation and characterization of nano-structured silica from rice husk. Mater Sci Eng A-Struct Mater Prop Microstruct Process, 2004, 364: 313–323

    Article  Google Scholar 

  21. Li Y J, Zhao C S, Ren Q, et al. Effect of rice husk ash addition on CO2 capture behavior of calcium-based sorbent during calcium looping cycle. Fuel Process Tech, 2009, 90: 825–834

    Article  Google Scholar 

  22. Wang C, Jia L, Tan Y, et al. Carbonation of fly ash in oxy-fuel CFB combustion. Fuel, 2008, 87: 1108–1114

    Article  Google Scholar 

  23. Maclntire W H, Stansel T B. Steam catalysis in calcinations of dolomite and limestone fines. Ind Eng Chem Res, 1953, 45: 1548–1555

    Article  Google Scholar 

  24. Manovic V, Anthony E J. Steam reactivation of spent CaO-based sorbent for multiple CO2 capture cycles. Environ Sci Technol, 2007, 41: 1420–1425

    Article  Google Scholar 

  25. Manovic V, Anthony E J. Carbonation of CaO-based sorbents enhanced by steam addition. Ind Eng Chem Res, 2010, 49: 9105–9110

    Article  Google Scholar 

  26. Donat F, Florin N H, Anthony E J, et al. Influence of high-temperature steam on the reactivity of CaO sorbent for CO2 capture. Environ Sci Technol, 2012, 46: 1262–1269

    Article  Google Scholar 

  27. Arias B, Grasa G, Abanades J C, et al. The effect of steam on the fast carbonation reaction rates of CaO. Ind Eng Chem Res, 2012, 51: 2478–2482

    Article  Google Scholar 

  28. Liu W, An H, Qin C, et al. Performance enhancement of calcium oxide sorbents for cyclic CO2 capture—A review. Energy Fuels, 2012, 26: 2751–2767

    Article  Google Scholar 

  29. Ma X T, Li Y J, Shi L, et al. Fabrication and CO2 capture performance of magnesia-stabilized carbide slag by by-product of biodiesel during calcium looping process. Appl Energy, 2016, 168: 85–95

    Article  Google Scholar 

  30. Yang X, Zhao L, Yang S, et al. Investigation of natural CaO-MgO sorbent for CO2 capture. Asia-Pac J Chem Eng, 2013, 8: 906–915

    Article  Google Scholar 

  31. Chen H, Zhao C, Ren Q. Feasibility of CO2/SO2 uptake enhancement of calcined limestone modified with rice husk ash during pressurized carbonation. J Environ Manage, 2012, 93: 235–244

    Article  Google Scholar 

  32. Wang Y, Thomson W J. The effects of steam and carbon dioxide on calcite decomposition using dynamic X-ray diffraction. Chem Eng Sci, 1995, 50: 1373–1382

    Article  Google Scholar 

  33. Symonds R T, Lu D Y, Hughes R W, et al. CO2 capture from simulated syngas via cyclic carbonation/calcination for a naturally occurring limestone: Pilot-plant testing. Ind Eng Chem Res, 2009, 48: 8431–8440

    Article  Google Scholar 

  34. Stanmore B R, Gilot P. Review—Calcination and carbonation of limestone during thermal cycling for CO2 sequestration. Fuel Process Tech, 2005, 86: 1707–1743

    Article  Google Scholar 

  35. Barker R. The reversibility of the reaction CaCO3⇄CaO+CO2. J Appl Chem, 2007, 23: 733–742

    Article  Google Scholar 

  36. Yin J J, Zhang C, Qin C L, et al. Reactivation of calcium-based sorbent by water hydration for CO2 capture. Chem Eng J, 2012, 198–199: 38–44

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to LiFeng Zhao.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Liu, Y., Yang, X., Zhao, L. et al. Effects of steam on CO2 absorption ability of calcium-based sorbent modified by peanut husk ash. Sci. China Technol. Sci. 60, 953–962 (2017). https://doi.org/10.1007/s11431-016-9031-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11431-016-9031-2

Keywords

Navigation