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Bimodal plate structures induced by pulsed laser in duplex-phase Zr alloy

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Abstract

A duplex-phase Zr-2.5Nb alloy was treated by pulsed laser, followed by careful microstructural characterization using field emission gun scanning electron microscope and attached electron backscatter diffraction. Beneath the modification zones with common uniform α-plate structures (UPS), a layer of unreported bimodal α-plate structures (BPS) featured by coarse (submicron) plates forming multiple cores surrounded by dense fine (nanoscale) plates was found. Presence of such BPS is attributed to non-equilibrium thermodynamic conditions induced by the pulsed laser treatments. Limited diffusion of Nb due to the short pulse during laser heating allows β phases with distinctly different Nb contents to be presented: Nb-enriched prior β films and Nb-depleted β phases, transforming into the fine and the coarse plates during cooling, respectively. Orientation analyses show that both types of plates in the BPS are aroused essentially from a single β orientation, suggesting epitaxial growth of the Nb-depleted β phases from the preexisting β films.

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References

  1. Holt R A. In-reactor deformation of cold-worked Zr-2.5Nb pressure tubes. J Nucl Mater, 2008, 372: 182–214

    Article  Google Scholar 

  2. Li Y, Rogge R, Holt R A. Development of local microstructure and crystallographic texture in extruded Zr-2.5Nb tubes. Mater Sci Eng-A, 2006, 437: 10–20

    Article  Google Scholar 

  3. Chai L J, Wang S Y, Luan B F, et al. Electron backscatter diffraction investigation of duplex-phase microstructure in a forged Zr-2.5Nb alloy. Sci China Tech Sci, 2016, 59: 673–679

    Article  Google Scholar 

  4. Helmi Attia M. On the fretting wear mechanism of Zr-alloys. Tribol Int, 2006, 39: 1320–1326

    Article  Google Scholar 

  5. Rawers J, Reitz W, Bullard S, et al. Surface and corrosion study of laser-processed zirconium alloys. Corrosion, 1991, 47: 769–777

    Article  Google Scholar 

  6. Amouzouvi K F, Clegg L J, Styles R C, et al. Microstructural changes in laser hardened Zr-2.5Nb alloy. Scr Metall Mater, 1995, 32: 289–294

    Article  Google Scholar 

  7. Lee S J, Park C J, Lim Y S, et al. Influences of laser surface alloying with niobium (Nb) on the corrosion resistance of Zircaloy-4. J Nucl Mater, 2003, 321: 177–183

    Article  Google Scholar 

  8. Chai L, Chen B, Wang S, et al. Microstructural changes of Zr702 induced by pulsed laser surface treatment. Appl Surf Sci, 2016, 364: 61–68

    Article  Google Scholar 

  9. Chai L, Chen B, Zhou Z, et al. A special twin relationship or a common Burgers misorientation between α plates after β quenching in Zr alloy? Mater Charact, 2015, 104: 61–65

    Article  Google Scholar 

  10. Kim H G, Park J Y, Jeong Y H. Phase boundary of the Zr-rich region in commercial grade Zr-Nb alloys. J Nucl Mater, 2005, 347: 140–150

    Article  Google Scholar 

  11. Choo K N, Kang Y H, Pyun S I, et al. Effect of composition and heat treatment on the microstructure and corrosion behavior of Zr-Nb alloys. J Nucl Mater, 1994, 209: 226–235

    Article  Google Scholar 

  12. Hovington P, Pinard P T, Lagacé M, et al. Towards a more comprehensive microstructural analysis of Zr-2.5Nb pressure tubing using image analysis and electron backscattered diffraction (EBSD). J Nucl Mater, 2009, 393: 162–174

    Article  Google Scholar 

  13. Humphreys F J. Review-grain and subgrain characterisation by electron backscatter diffraction. J Mater Sci, 2001, 36: 3833–3854

    Article  Google Scholar 

  14. Srivastava D, Mukhopadhyay P, Banerjee S, et al. Morphology and substructure of lath martensites in dilute Zr-Nb alloys. Mater Sci Eng-A, 2000, 288: 101–110

    Article  Google Scholar 

  15. Massih A R, Andersson T, Witt P, et al. Effect of quenching rate on the β-to-α phase transformation structure in zirconium alloy. J Nucl Mater, 2003, 322: 138–151

    Article  Google Scholar 

  16. Yang H L, Kano S, Matsukawa Y, et al. Effect of molybdenum on microstructures in Zr-1.2Nb alloys after β-quenching and subsequently 873 K annealing. Mater Des, 2016, 104: 355–364

    Article  Google Scholar 

  17. Wang Y, Chen M, Zhou F, et al. High tensile ductility in a nanostructured metal. Nature, 2002, 419: 912–915

    Article  Google Scholar 

  18. Zhao Y, Topping T, Bingert J F, et al. High tensile ductility and strength in bulk nanostructured nickel. Adv Mater, 2008, 20: 3028–3033

    Article  Google Scholar 

  19. Han B Q, Huang J Y, Zhu Y T, et al. Strain rate dependence of properties of cryomilled bimodal 5083 Al alloys. Acta Mater, 2006, 54: 3015–3024

    Article  Google Scholar 

  20. Guo D, Li M, Shi Y, et al. High strength and ductility in multimodalstructured Zr. Mater Des, 2012, 34: 275–278

    Article  Google Scholar 

  21. Tiwari G P, Sharma B D, Raghunathan V S, et al. Self- and solutediffusion in dilute zirconium-niobium alloys in β-phase. J Nucl Mater, 1973, 46: 35–40

    Article  Google Scholar 

  22. Jeong Y H, Lee K O, Kim H G. Correlation between microstructure and corrosion behavior of Zr-Nb binary alloy. J Nucl Mater, 2002, 302: 9–19

    Article  Google Scholar 

  23. Chai L, Luan B, Zhang M, et al. Experimental observation of 12 α variants inherited from one β grain in a Zr alloy. J Nucl Mater, 2013, 440: 377–381

    Article  Google Scholar 

  24. Daymond M R, Holt R A, Cai S, et al. Texture inheritance and variant selection through an hcp-bcc-hcp phase transformation. Acta Mater, 2010, 58: 4053–4066

    Article  Google Scholar 

  25. Sattari M, Holt R A, Daymond M R. Variant selection and transformation texture in zirconium alloy excel. J Nucl Mater, 2014, 453: 120–123

    Article  Google Scholar 

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Correspondence to LinJiang Chai or Ning Guo.

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Chai, L., Wang, S., Wu, H. et al. Bimodal plate structures induced by pulsed laser in duplex-phase Zr alloy. Sci. China Technol. Sci. 60, 587–592 (2017). https://doi.org/10.1007/s11431-016-0527-6

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  • DOI: https://doi.org/10.1007/s11431-016-0527-6

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