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Experimental analysis and parameter optimization on the reduction of NOx from diesel engine using RSM and ANN Model

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Abstract

The major emission sources of NOX are from automobiles, trucks, and various non-road vehicles, power plants, coal fired boilers, cement kilns, turbines, etc. Plasma reactor technology is widely used in gas conversion applications, such as NOx conversion into useful chemical by-product. Among the plasma treatment techniques, nonthermal plasma (NTP) is widely used because it does not cause any damage to the surfaces of the reacting chamber. In this proposed work, the feasibility of Dielectric Barrier Discharge (DBD) reactor–based nonthermal plasma (NTP) process is examined based on four operating parameters including NOx concentration (300–400 ppm), gas flow rate (2–6 lpm), applied plasma voltage (20–30 kVpp), and electrode gap (3–5 mm) for removing NOx gas from diesel engine exhaust. Optimization of NTP process parameters has been carried out using response surface-based Box-Behnken design (BBD) method and artificial neural network (ANN) method and compared with the performance measures such as R2, MSE (mean square error), RMSE (root mean square error), and MAPE (mean absolute percentage error). Two kinds of analysis were carried out based on (1) NOx removal efficiency and (2) energy efficiency. Based on the simulation studies carried out for Nox removal efficiency, the RSM methodology produces the performance measures, 0.98 for R2, 1.274 for MSE, 1.128 for RMSE, and 2.053 for MAPE, and for ANN analysis method, 0.99 for R2, 2.167 for MSE, 1.472 for RMSE, and 1.276 for MAPE. These results shows that ANN method is having enhanced performance measures. For the second case, based on the energy efficiency study, the R2, MSE, RMSE, and MAPE values from the RSM model are 0.97, 2.230, 1.493, and 2.903 respectively. Similarly based on ANN model, the R2, MSE, RMSE, and MAPE values are 0.99, 0.246, 0.46, and 0.615, respectively. From the performance measures, it is found that the ANN model is accurate than the RSM model in predicting the NOx removal/reduction and efficiency. These models demonstrate that they have strong agreement with the experimental results. The experimental results are indicated that optimum conditions arrived based on the RSM model resulted in a maximum NOx reduction of 60.5% and an energy efficiency of 66.24 g/J. The comparison between the two models confirmed the findings, whereas this ANN model displayed a stronger correlation to the experimental evidence.

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source: CPCB-India, 2020)

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References

  • Aerts R, Somers W, Bogaerts A (2015) Carbon dioxide splitting in a dielectric barrier discharge plasma: a combined experimental and computational study. Chemsuschem 8:702–716

    Article  CAS  Google Scholar 

  • Agatonovic-Kustrin S, Beresford R (2000) Basic concepts of artificial neural network (ANN) modeling and its application in pharmaceutical research. J Pharm Biomed Anal 22:717–727

    Article  CAS  Google Scholar 

  • Amoatey P, Omidvarborna H, Baawain MS, Al-Mamun A (2019) Emissions and exposure assessments of SOX, NOX, PM10/2.5 and trace metals from oil industries: a review study (2000–2018). Process Saf Environ Prot 123:215–228

    Article  CAS  Google Scholar 

  • Ansari M, Hossein Mahvi A, Hossein Salmani M, Sharifian M, Fallahzadeh H, Hassan Ehrampoush M (2020) Dielectric barrier discharge plasma combined with nano catalyst for aqueous amoxicillin removal: performance modeling, kinetics and optimization study, energy yield, degradation pathway, and toxicity. Sep Purif Technol 251:117270

    Article  CAS  Google Scholar 

  • Armstrong RA, Eperjesi F, Gilmartin B (2002) The application of analysis of variance (ANOVA) to different experimental designs in optometry. Ophthalmic Physiol Opt 22:248–256

    Article  CAS  Google Scholar 

  • Arunkumar V, Krishnamurthy K, Maheswari C, Meenakshipriya B, Vinoth R (2019) Removal of NOX from diesel engine exhaust by using different chemical absorbent in a lab-scale packed column system. J Meas Control 52:1095–1101

    Article  Google Scholar 

  • Bhatti MS, Kapoor D, Kalia RK, Reddy AS, Thukral AK (2011) RSM and ANN modeling for electrocoagulation of copper from simulated wastewater: multi objective optimization using genetic algorithm approach. Desalination 274:74–80

    Article  CAS  Google Scholar 

  • Chen M, Liu Y (2010) NOx removal from vehicle emissions by functionality surface of asphalt road. J Hazard Mater 174:375–379

    Article  CAS  Google Scholar 

  • Chen C-T, Tan W-L (2012) Mathematical modeling, optimal design and control of an SCR reactor for NOx removal. J Taiwan Inst Chem Eng 43:409–419

    Article  CAS  Google Scholar 

  • Chen JX, Pan KL, Yu SJ, Yen SY, Chang MB (2017) Combined fast selective reduction using Mn-based catalysts and nonthermal plasma for NOx removal. Environ Sci Pollut Res 24:21496–21508

    Article  CAS  Google Scholar 

  • Civelekoglu G, Yigit NO, Diamadopoulos E, Kitis M (2009) Modelling of COD removal in a biological wastewater treatment plant using adaptive neuro-fuzzy inference system and artificial neural network. Water Sci Technol 60:1475–1487

    Article  CAS  Google Scholar 

  • E J, Zhao M, Zuo Q, Zhang B, Zhang Z, Peng Q, Han D, Zhao X, Deng Y (2020): Effects analysis on diesel soot continuous regeneration performance of a rotary microwave-assisted regeneration diesel particulate filter. Fuel 260, 116353

  • Elmolla ES, Chaudhuri M, Eltoukhy MM (2010) The use of artificial neural network (ANN) for modeling of COD removal from antibiotic aqueous solution by the Fenton process. J Hazard Mater 179:127–134

    Article  CAS  Google Scholar 

  • Feng C, Deng Y, Chen L, Han W, E J, Wei K, Han D, Zhang B (2022): Hydrocarbon emission control of a hydrocarbon adsorber and converter under cold start of the gasoline engine. Energy 239, 122138

  • Goh AT (1995) Back-propagation neural networks for modeling complex systems. Artif Intell Eng 9:143–151

    Article  Google Scholar 

  • Jolibois J, Takashima K, Mizuno A (2012) Application of a non-thermal surface plasma discharge in wet condition for gas exhaust treatment: NOx removal. J Electrostat 70:300–308

    Article  CAS  Google Scholar 

  • Kampa M, Castanas E (2008) Human health effects of air pollution. Environ Pollut 151:362–367

    Article  CAS  Google Scholar 

  • Keselman HJ, Huberty CJ, Lix LM, Olejnik S, Cribbie RA, Donahue B, Kowalchuk RK, Lowman LL, Petoskey MD, Keselman JC, Levin JR (1998) Statistical practices of educational researchers: an analysis of their ANOVA, MANOVA, and ANCOVA analyses. Rev Educ Res 68:350–386

    Article  Google Scholar 

  • Khan MSI, Kim Y-J (2020) Dielectric barrier discharge (DBD) plasma induced flavonoid degradation kinetics and mechanism in water. LWT 118:108777

    Article  CAS  Google Scholar 

  • Kim Z, Shin Y, Yu J, Kim G, Hwang S (2019) Development of NOx removal process for LNG evaporation system: comparative assessment between response surface methodology (RSM) and artificial neural network (ANN). J Ind Eng Chem 74:136–147

    Article  CAS  Google Scholar 

  • Kinoshita H, Yasui K, Hamasuna T, Yuji T, Misawa N, Haraguchi T, Sasaki K, Mungkung NJP (2022): Porous ceramics adsorbents based on glass fiber-reinforced plastics for NOx and SOx Removal. 14, 164

  • Krosuri A, Wu S, Bashir MA, Walquist M (2021) Efficient degradation and mineralization of methylene blue via continuous-flow electrohydraulic plasma discharge. J Water Process Eng 40:101926

    Article  Google Scholar 

  • Kuwahara T, Nakaguchi H, Kuroki T, Okubo M (2016) Continuous reduction of cyclic adsorbed and desorbed NOx in diesel emission using nonthermal plasma. J Hazard Mater 308:216–224

    Article  CAS  Google Scholar 

  • Li Q, Yang H, Qiu F, Zhang X (2011) Promotional effects of carbon nanotubes on V2O5/TiO2 for NOX removal. J Hazard Mater 192:915–921

    Article  CAS  Google Scholar 

  • Maheswari C, Krishnamurthy K, Parameshwaran R (2013) Experimental investigations on SO2 removal process using wet scrubber. J Pollut Res 32:655–662

    CAS  Google Scholar 

  • Maheswari C, Krishnamurthy K, Parameshwaran R (2014a) Modelling and experimental analysis of packed column for SO2 emission control process. J Atmos Pollut Res 5:464–470

    Article  CAS  Google Scholar 

  • Maheswari C, Krishnamurthy K, Meenakshipriya B, Bhaba PK (2014b) Application of CDM-PI-P controller for SO2 control process. J Control Appl Inform 16:40–49

    Google Scholar 

  • Maheswari C, Krishnamurthy K, Arun SR, Magalingam V, Jeevanraj K (2015) Optimization of PID controller parameters for SO2 emission control process using PSO Algorithm. J Ind Pollut Control 74:522–525

    CAS  Google Scholar 

  • Maheswari C, Priyanka E, Meenakshipriya B (2017) Fractional-order PIλDµ controller tuned by coefficient diagram method and particle swarm optimization algorithms for SO2 emission control process. Proceedings of the Institution of Mechanical Engineers, Part i: Journal of Systems and Control Engineering 231:587–599

    Google Scholar 

  • C Maheswari RV, B Meenakshipriya,V Arunkumar (2015): Review paper on simultaneous reduction techniques of SO2 and Nox gases from industrial boilers. International Journal of Applied Engineering Research 10

  • Mansouri F, Khavanin A, Jafari AJ, Asilian H, Ghomi HR, Mousavi SM (2020) Energy efficiency improvement in nitric oxide reduction by packed DBD plasma: optimization and modeling using response surface methodology(RSM). Environ Sci Pollut Res 27:16100–16109

    Article  CAS  Google Scholar 

  • McHugh ML (2011) Multiple comparison analysis testing in ANOVA. Biochemia Medica 21:203–209

    Article  CAS  Google Scholar 

  • Mizuno A (2007) Industrial applications of atmospheric non-thermal plasma in environmental remediation. Plasma Phys Controlled Fusion 49:A1–A15

    Article  CAS  Google Scholar 

  • Mizuno A (2013) Generation of non-thermal plasma combined with catalysts and their application in environmental technology. Catal Today 211:2–8

    Article  CAS  Google Scholar 

  • Nishanth K, Rajanikanth BJPC, Processing P (2021): Red mud packed surface discharge reactor for Nox/THC removal: exploring plasma catalysis of diesel exhaust. 41, 1293-1311

  • Picos-Benítez AR, López-Hincapié JD, Chávez-Ramírez AU, Rodríguez-García A (2017) Artificial intelligence based model for optimization of COD removal efficiency of an up-flow anaerobic sludge blanket reactor in the saline wastewater treatment. Water Sci Technol 75:1351–1361

    Article  CAS  Google Scholar 

  • Sakiewicz P, Piotrowski K, Ober J, Karwot J (2020) Innovative artificial neural network approach for integrated biogas – wastewater treatment system modelling: effect of plant operating parameters on process intensification. Renew Sustain Energy Rev 124:109784

    Article  CAS  Google Scholar 

  • Shin Y, Kim Z, Yu J, Kim G, Hwang S (2019) Development of NOx reduction system utilizing artificial neural network (ANN) and genetic algorithm (GA). J Clean Prod 232:1418–1429

    Article  CAS  Google Scholar 

  • Skalska K, Miller JS, Ledakowicz S (2010) Trends in NOx abatement: a review. Sci Total Environ 408:3976–3989

    Article  CAS  Google Scholar 

  • Sohn J, Hwang IS, Hwang J (2021) Improvement of ammonia mixing in an industrial scale selective catalytic reduction De-NOx system of a coal-fired power plant: a numerical analysis. Process Saf Environ Prot 147:334–345

    Article  CAS  Google Scholar 

  • Soleimanzadeh H, Niaei A, Salari D, Tarjomannejad A, Penner S, Grünbacher M, Hosseini SA, Mousavi SM (2019) Modeling and optimization of V2O5/TiO2 nanocatalysts for NH3-Selective catalytic reduction (SCR) of NOx by RSM and ANN techniques. J Environ Manage 238:360–367

    Article  CAS  Google Scholar 

  • Srikanth H, Venkatesh J, Godiganur S (2021) Box-Behnken response surface methodology for optimization of process parameters for dairy washed milk scum biodiesel production. Biofuels 12:113–123

    Article  CAS  Google Scholar 

  • Suresh R, Rajoo B, Chenniappan M, Palanichamy M (2021a) Treatment possibilities of electrical discharge non-thermal plasma for industrial wastewater treatment-review, IOP Conference Series: Materials Science and Engineering. IOP Publishing, pp. 012018

  • Suresh R, Rajoo B, Chenniappan M, Palanisamy M (2021b) Feasibility of applying nonthermal plasma for dairy effluent treatment and optimization of process parameters. Water and Environment Journal n/a

  • Takaki K, Shimizu M, Mukaigawa S, Fujiwara T (2004) Effect of electrode shape in dielectric barrier discharge plasma reactor for NOx removal. IEEE Trans Plasma Sci 32:32–38

    Article  CAS  Google Scholar 

  • Talebizadeh P, Babaie M, Brown R, Rahimzadeh H, Ristovski Z, Arai M (2014) The role of non-thermal plasma technique in NOx treatment: a review. Renew Sustain Energy Rev 40:886–901

    Article  CAS  Google Scholar 

  • Tang X, Zhang R, Yi H, Gao F, Zhao S, Wang J, Yang K (2021) Byproducts generation characteristics of non-thermal plasma for no conversion: effect of reaction conditions. Plasma Chem Plasma Process 41:369–387

    Article  CAS  Google Scholar 

  • Vishal S, Srihari B (2020) Recent advancements in emission reduction for diesel vehicles using non thermal plasma activation. Int J Innov Sci Res Technol 5:1–7

    Google Scholar 

  • Wang B, Su H, Yao S (2020) Oxidation of NO with O3 under different conditions and the effects of SO2 and H2O vapor. Process Saf Environ Prot 133:216–223

    Article  CAS  Google Scholar 

  • Yamasaki H, Mizuguchi Y, Nishioka R, Fukuda Y, Kuroki T, Yamamoto H, Okubo M (2022) Pilot-scale NOx and SOx aftertreatment by semi-dry plasma-chemical hybrid process in glass-melting-furnace exhaust gas. Plasma Chem Plasma Process 42:51–71

    Article  CAS  Google Scholar 

  • Zhao G, Li N, Li B, Li W, Liu Y, Chai T (2020) ANN model for predicting acrylonitrile wastewater degradation in supercritical water oxidation. Sci Total Environ 704:135336

    Article  CAS  Google Scholar 

  • Zhao X, E J, Liao G, Zhang F, Chen J, Deng Y (2021): Numerical simulation study on soot continuous regeneration combustion model of diesel particulate filter under exhaust gas heavy load. Fuel 290, 119795

  • Zhou B, Vogt RD, Lu X, Xu C, Zhu L, Shao X, Liu H, Xing M (2015) Relative importance analysis of a refined multi-parameter phosphorus index employed in a strongly agriculturally influenced watershed. Water Air Soil Pollut 226:1–13

    Google Scholar 

  • Zhu T, Zhang X, Niu W, Liu Y, Yuan B, Li Z, Liu H (2020) Selective catalytic reduction of NO by NH3 using a combination of non-thermal plasma and Mn-Cu/ZSM5 catalyst. Catalysts 10:1044

    Article  CAS  Google Scholar 

  • Zwanenburg G, Hoefsloot HCJ, Westerhuis JA, Jansen JJ, Smilde AK (2011) ANOVA–principal component analysis and ANOVA–simultaneous component analysis: a comparison. J Chemom 25:561–567

    Article  CAS  Google Scholar 

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Funding

This project work was funded by UGC– Government of India under the scheme of major research project (File No. 39–883/2010(SR)).

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CM supervised and validated the whole project. ASR analyzed, interpreted, and wrote the manuscript. RB helped in the ANN analyze. NS, RR, and MV conducted the experiments.

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Chenniappan, M., Suresh, R., Rajoo, B. et al. Experimental analysis and parameter optimization on the reduction of NOx from diesel engine using RSM and ANN Model. Environ Sci Pollut Res 29, 66068–66084 (2022). https://doi.org/10.1007/s11356-022-20396-7

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  • DOI: https://doi.org/10.1007/s11356-022-20396-7

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