Abstract
Bismuth vanadate (BiVO4) nanostructured films were prepared and successfully applied for peroxymonosulfate (PMS) activation for the degradation of rhodamine B (RhB) in aqueous solution. The BiVO4 thin films were obtained by thermal reaction between electrodeposited bismuth (Bi) films and vanadium precursor. The as-prepared BiVO4 porous, nanoflowers, and cluster nanostructures were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Raman spectroscopy, and BET analysis. The catalytic performance of BiVO4 nanostructures has been carefully evaluated in activating PMS for the degradation of RhB. The nanoflower-like BiVO4 nanostructures exhibit the best catalytic activity. Under optimized conditions, the complete catalytic degradation of RhB using BiVO4 nanoflowers/PMS system was achieved in 17 min at room temperature as revealed by high-performance liquid chromatography (HPLC) analysis. Quenching experiments suggested that sulfate radicals are the main active species in the degradation process. Additionally, BiVO4 catalyst remained stable without any apparent activity loss after five cycling runs.
Similar content being viewed by others
Availability of data and material
Not applicable.
References
Anipsitakis GP, Dionysiou DD (2003) Degradation of organic contaminants in water with sulfate radicals generated by the conjunction of peroxymonosulfate with cobalt Environ. Sci Technol 37:4790–4797
Babuponnusami A, Muthukumar K (2013) A review on Fenton and improvements to the Fenton process for wastewater treatment. J Environ Chem Eng 2:557–572
Banerjee M, Konar RS (1984) Comment on the paper “polymerization of acrylonitrile initiated by K2–S2–O8–Fe(II) redox system”. J Polym Sci Polym Chem Ed 22:1193–119x
Ben Ali M, Barras A, Addad A, Sieber B, Elhouichet H, Ferid M, Szunerits S, Boukherroub R (2017) Co2SnO4 nanoparticles as a high performance catalyst for oxidative degradation of rhodamine B dye and pentachlorophenol by activation of peroxymonosulfate. Phys Chem Chem Phys 19:6569–6578
Chen Q, Wu P, Li Y, Zhu N, Dang Z (2009) Heterogeneous photo-Fenton photodegradation of reactive brilliant orange X-GN over iron-pillared montmorillonite under visible irradiation. J Hazard Mater 168:901–908
Chen Q, Ji F, Liu T, Yan P, Guan W, Xu X (2013) Synergistic effect of bifunctional Co-TiO2 catalyst on degradation of Rhodamine B: Fenton-photo hybrid process. Chem Eng J 229:57–65
Chi F, Song B, Yang B, Lv Y, Ran S, Huo Q (2015) Activation of peroxymonosulfate by BiFeO3 microspheres under visible light irradiation for decomposition of organic pollutants. RSC Adv 5:67412–67417
Deng J, Ya C, Ge Y, Cheng Y, Chen Y, Xuan M, Wang H (2018) Activation of peroxymonosulfate by metal (Fe, Mn, Cu and Ni) doping ordered mesoporous Co3O4 for the degradation of enrofloxacin. RSC Adv 8:2338–2349
Dhakshinamoorthy A, Navalon S, Alvaro M, Garcia H (2012) Metal nanoparticles as heterogeneous Fenton catalysts. ChemSusChem. 5:46–64
Dijkstra JJ, Meeussen JCL, Comans RNJ (2004) Leaching of heavy metals from contaminated soils: an experimental and modeling study. Environ Sci Technol 38:4390–4395
Du Y, Ma W, Liu P, Zou B, Ma J (2016) Magnetic CoFe2O4 nanoparticles supported on titanate nanotubes (CoFe2O4/TNTs) as a novel heterogeneous catalyst for peroxymonosulfate activation and degradation of organic pollutants. J Hazard Mater 308:58–66
Duarte F, Maldonado-Hódar FJ, Pérez-Cadenas AF, Madeira LM (2009) Fenton-like degradation of azo-dye Orange II catalyzed by transition metals on carbon aerogels. Appl Catal B 85:139–147
Fan H, Wang D, Wang L, Li H, Wang P, Jiang T, Xie T (2011) Hydrothermal synthesis and photoelectric properties of BiVO4 with different morphologies: an efficient visible-light photocatalyst. Appl Surf Sci 257:7758–7762
Galembeck JA, Alves OL (2000) BiVO4 thin film preparation by metalorganic decomposition. Thin Solid Films 365:90–93
Gao Y, Fang J, Gao N, Yi X, Maoc W, Zhanga J (2018) Kinetic and mechanistic investigations of the degradation of propranolol in heat activated persulfate process. Royal Soc Chem 8:41163–44117
Ghanbari F, Moradi M (2017) Application of peroxymonosulfate and its activation methods for degradation of environmental organic pollutants: review. Chem Eng J 310:41–62
Giannakis S, Papoutsakis S, Darakas E (2015) A. Escalas-Ca˜nellas, C. Pétrier, C. Pul-garin, Ultrasound enhancement of near-neutral photo-Fenton for effective E. coli inactivation in wastewater. Ultrason Sonochem 22:515–526
Gotić M, Musić S, Ivanda M, Šoufek M, Popović S (2005) Synthesis and characterization of bismuth (III) vanadate. J Mol Struct 744–747:535–540
Hardcastle FD, Wachs IE (1991) Determination of vanadium–oxygen bond distances and bond orders by Raman spectroscopy. J Phys Chem 95:5031–5041
Huang SZ, Bao H, Yao Y, Lu W, Chen W (2014) Novel green activation processes and mechanism of peroxymonosulfate based on supported cobalt phthalocyanine catalyst. Appl Catal B 154–155:36–43
Hussain A, Liu Y, Bin-afta T, Li D, Sand W (2019) Engineering reusable sponge of cobalt heterostructures for highly-efficient organic pollutants degradation via peroxymonosulfate activation. ChemNanoMat. 5:547–557
Janzen EG, Kotake Y, Hinton RD (1992) Stabilities of hydroxyl radical spin adducts of PBN-type spin traps. Free Radic Biol Med 12:169–173
Jiang H, Meng X, Dai H, Deng J, Liu Y, Zhang L, Zhao Z, Zhang R (2012) High-performance porous spherical or octapod-like single-crystalline BiVO4 photocatalysts for the removal of phenol and methylene blue under visible-light illumination. Hazard Mater 217–218:92–99
Kang D, Park Y, Hill JC, Choi K-S (2014) Preparation of Bi-based ternary oxide photoanodes BiVO4, Bi2WO6, and Bi2Mo3O12 using dendritic Bi metal electrodes. J Phys Chem Lett 5:2994–2999
Kourdali S, Badis A, Boucherit A (2014) Degradation of direct yellow 9 by electro-Fenton: process study and optimization and, monitoring of treated water toxicity using catalase. Ecotoxicol Environ Saf 110:110–120
Kudo A, Ueda K, Kato H, Mikami I (1998) Photocatalytic O2 evolution under visible light irradiation on BiVO4 in aqueous AgNO3 solution. Catal Lett 53:229–230
Lan H, Wang A, Liu R, Liu H, Qu J (2015) Heterogeneous photo-Fenton degradation of acid red B over Fe2O3 supported on activated carbon fiber. J Hazard Mater 285:167–172
Lei Y, Chen C-S, Ai J, Lin H, Huang Y-H, Zhang H (2016) Selective decolorization of cationic dyes by peroxymonosulfate: non-radical mechanism and effect of chloride. RSC Adv 6:866–871
Lellis B, Fávaro-Polonio CZ, Pamphile JA, Polonio JC (2019) Effects of textile dyes on health and the environment and bioremediation potential of living organisms. Biotechnol Res Innov 3:275–290
Leng Y, Guo W, Shi X, Li Y, Wang A, Hao F, Xing L (2014) Degradation of Rhodamine B by persulfate activated with Fe3O4: effect of polyhydroquinone serving as an electron shuttle. Chem Eng J 240:338–343
Liang C, Bruell CJ, Marley MC, Sperry KL (2004) Persulfate oxidation for in situ remediation of TCE. I. Activated by ferrous ion with and without a persulfate–thiosulfate redox couple. Chemosphere 55:1213–1223
Liang Y, Tsubota T, Mooij LPA, van de Krol R (2011) Highly improved quantum efficienciesfor thin film BiVO4 photoanodes. J Phys Chem C 115:17594–17598
Lin F, Wang D, Jiang Z, Ma Y, Li J, Li R, Li C (2012) Photocatalytic oxidation of thiophene on BiVO4 with dual co-catalysts Pt and RuO2 under visible light irradiation using molecular oxygen as oxidant. Energy Environ Sci 5:6400–6406
Liu JB, Wang H, Wang S, Yan H (2003) Hydrothermal preparation of BiVO4 powders. Mater Sci Eng B104:36–39
Liu Y, Guo H, Zhang Y, Tang W, Cheng X, Liu H (2016) Activation of peroxymonosulfate by BiVO4 under visible light for degradation of Rhodamine B. Chem Phys Lett 653:101–107
Lu Y, Shang H, Guan H, Zhao Y, Zhang H, Zhang B (2015) Enhanced visible-light photocatalytic activity of BiVO4 microstructures via annealing process. Supperlatice Microst 88:591–599
Luo M, Lv L, Deng G, Yao W, Ruan Y, Li X, Xu A (2014a) The mechanism of bound hydroxyl radical formation and degradation pathway of Acid Orange II in Fenton-like Co2+-HCO3– system. Appl Catal A 469:198–205
Luo Y, Guo W, Ngo HH, Nghiem LD, Hai FI, Zhang J, Liang S, Wang XC (2014b) A review on the occurrence of micropollutants in the aquatic environment and their fate and removal during wastewater treatment. Sci Total Environ 473–474:619–641
Monfort O, Pop LC, Sfaelou S, Plecenik T, Roch T, Dracopoulos V, Stathatos E, Plesch G, Lianos P (2016) Photoelectrocatalytic hydrogen production by water splitting using BiVO4 photoanode. Chem Eng J 286:91–97
Oh W-D, Dong Z, Lim T-T (2016) Generation of sulfate radical through heterogeneous catalysis for organic contaminants removal: current development, challenges and prospects. Appl Catal B Environ 194:169–201
Olvera-Vargas H, Oturan N, Brillas E, Buisson D, Esposito G, Oturan MA (2014) Electrochemical Tremendous efforts were devoted cal advanced oxidation for cold incineration of the pharmaceutical ranitidine: mineralization pathway and toxicity evolution. Chemosphere. 117:644–665
Park Y, McDonald KJ, Choi K-S (2013) Progress in bismuth vanadate photoanodes for use in solar water oxidation. Chem Soc Rev 42:2321–2337
Perez M, Torrades F, Garcia-Hortal JA, Domenech X, Peral J (2002) Removal of organic contaminants in paper pulp treatment effluents under Fenton and photo-Fenton conditions. Appl Catal B 36:63–74
Qu Z, Liu P, Yang X, Wang F, Zhan W, Fei C (2016) Microstructure and characteristic of BiVO4 prepared under different pH values: photocatalytic efficiency and antibacterial activity. Materials 9:129
Richter H, Wang ZP, Ley L (1981) The one phonon Raman spectrum in microcrystalline silicon. Solid State Commun 39:625–629
Rim Kim H, Kimb G, Ina S, Park Y (2016) Optimization of porous BiVO4 photoanode from electrodeposited Bi electrode: Structural factors affecting photoelectrochemical performance. Electrochim Acta 189:252–258
Seabold JA, Choi K (2012) Efficient and stable photo-oxidation of water by a bismuth vanadate photoanode coupled with an iron oxyhydroxide oxygen evolution catalyst. Am ChemSoc 134:2186–2192
Shao H, Wang Y, Zeng H, Zhang J, Wang Y, Sillanpaa M, Zhao X (2020) Enhancedphotoelectrocatalytic degradation of bisphenol A by BiVO4 photoanode coupling with peroxymonosulfate. J Hazard Mater 394
Sleight AW, Chen H-Y, Ferretti A, Cox DE (1979) Crystal growth and structure of BiVO4. Mater Res Bull 14:1571–1581
Somasiri W, Xiufen L, Wenquan R, Chen J (2008) Evaluation of the efficacy of up-flow anaerobic sludge blanket reactor in removal of color and reduction of COD in real textile wastewater. Bioresour Technol 99:3692–3699
Tabit R, Amadine O, Essamlali Y, Dânoun K, Rhihil A, Zahouily M (2018) Magnetic CoFe2O4 nanoparticles supported on graphene oxide (CoFe2O4/GO) with high catalytic activity for peroxymonosulfate activation and degradation of rhodamine B. RSC Adv 8:1351–1360
Tekbas M, Yatmaz HC, Bektas N (2008) Heterogeneous photo-Fenton oxidation of reactive azo dye solutions using iron exchanged zeolite as a catalyst. J Micropor Mesopor Mater 115:594–602
Vaishnave P, Kumar A, Ameta R, Punjabi PB, Ameta SC (2014) Photo oxidative degradation of azure-B by sono-photo-Fenton and photo-Fenton reagents. Arab J Chem 7:981–985
Wang C, Shih Y (2015) Degradation and detoxification of diazinon by sono-Fenton and sono-Fenton-like processes. Sep Purif Technol 140:6–12
Wang T, Li C, Ji J, Wei Y, Zhang P, Wang S, Fan X, Gong J (2014a) Reduced Graphene Oxide (rGO)/BiVO4 Composites with Maximized Interfacial Coupling for Visible Light Photocatalysis. ACS Sustain Chem Eng 2:2253–2258
Wang Y, Wang W, Mao H, Lu Y, Lu J, Huang J, Ye Z, Lu B (2014b) Electrostatic self-assembly of BiVO4–reduced graphene oxide nanocomposites for highly efficient visible light photocatalytic activities. ACS Appl Mater Interfaces 6:12698–12706
Wang S, Chen P, Yun J-H, Hu Y, Wang L (2017) An electrochemically treated BiVO4 photoanode for efficient photoelectrochemical water splitting. Angew Chem Int Ed 56:8500–8504
Wang C, Xu J, Yang B, Xia F, Zhu Y, Xiao J (2018) Effect of MgO doping on the BiVO4 sensing electrode performance for YSZ-based potentiometric ammonia sensor. Solid State Electron Lett 147:19–25
Wu X, Zhao J, Guo S, Wang L, Shi W, Huang H, Liu Y, Kang Z (2016) Carbon dots and BiVO4 quantum dots composite for overall water splitting via two-electron pathway. Nanoscale 8:17314–17321
Xiao R, Luo Z, Wei Z, Luo S, Spinney R, Yang W, Dionysiou DD (2018) Activation of peroxymonosulfate/persulfate by nanomaterials for sulfate radical-based advanced oxidation technologies. Curr Opin Chem Eng 19:51–58
Yao Y, Cai Y, Wu G, Wei F, Li X, Chen H, Wang S (2015) Sulfate radicals induced from peroxymonosulfate by cobalt manganese oxides (CoxMn3−xO4) for Fenton-Like reaction in water. J Hazard Mater 296:128–137
Yu J, Kudo A (2005) Hydrothermal synthesis of nanofibrous bismuth vanadate. Chem Lett 34:850–851
Yu J, Kudo A (2006) Effects of structural variation on the photocatalytic performance of hydrothermally synthesized BiVO4. Adv Funct Mater 16:2163–2169
Yu J-G, Zhao X-H, Yang H, Chen X-H, Yang Q, Yua L-Y, Jiang J-H, Chen X-Q (2014) Aqueous adsorption and removal of organic contaminants by carbon nanotubes. Sci Total Environ 482–483:241–251
Zeng T, Yu M, Zhang H, He Z, Zhang X, Chen J, Song S (2017) In situ synthesis of cobalt ferrites embedded hollow N-doped carbon as an outstanding catalyst for elimination of organic pollutants. Sci Total Environ 593:286–296
Zhang A, Zhang Y, Teng Y, Fan M (2015) Sulfate radical and its application in decontamination technologies. Crit Rev Environ Sci Technol 45:1756–1800
Acknowledgements
K. Missaoui acknowledges the Ministry of High Education and Scientific Research (MHESR-Tunisia) and the Photovoltaic Laboratory of CRTEnfor having awarded her a research grant.
Author information
Authors and Affiliations
Contributions
KM is the student responsible for carrying out the work. RO had initiated work with KM. LJ assisted in the acquisition of X-ray diffraction diagrams. RB contributed to measurements of catalysis kinetics, interpretation of scanning electron microscopy images and Raman spectroscopy, and contributed to the revision of the manuscript. BB supervised all of the work and contributed to the writing and editing of the manuscript.
Corresponding author
Ethics declarations
Ethical approval
Not applicable.
Consent to participate
Not applicable.
Consent for publication
Not applicable.
Competing interests
The authors declare no competing interests.
Additional information
Responsible Editor: Santiago V. Luis
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Missaoui, K., Ouertani, R., Jbira, E. et al. Morphological influence of BiVO4 nanostructures on peroxymonosulfate activation for highly efficient catalytic degradation of rhodamine B. Environ Sci Pollut Res 28, 52236–52246 (2021). https://doi.org/10.1007/s11356-021-14320-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11356-021-14320-8