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In situ polymerization of magnetic graphene oxide-diaminopyridine composite for the effective adsorption of Pb(II) and application in battery industry wastewater treatment

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Abstract

The efficient removal of heavy metals from aqueous environment is imperative and challenging. A novel ternary composite constructed of diaminopyridine polymers, graphene oxide, and ferrite magnetic nanoparticles was designed by a facile in situ polymerization strategy for the removal of Pb(II) from aqueous solution. Detailed characterization of morphological, chemical, and magnetic properties was employed systematically to confirm the formation of the composite material. Batch adsorption experiment studies suggested that the composite was an excellent adsorbent for Pb(II) which was easily collected after use via exposure to an external magnetic field for 30 s. The effects of different parameters such as solution pH, adsorbent dosage, contact time, initial Pb(II) concentration, temperature, and co-existing ions were examined. The maximum adsorption capacity at pH = 5 was estimated to be 387.2 mg g−1 at 298 K by the Langmuir isotherm model, accompanied by favorable adsorption recyclability according to the investigation of regeneration experiments. Thermodynamic studies revealed that the Pb(II) adsorption via our ternary composite was endothermic and spontaneous. The corresponding removal performance for effluent containing Pb(II) from the battery industry was successfully examined. The present results indicated that our designed adsorbent is beneficial to the practical Pb(II) removal in wastewater purification.

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Funding

This work was financially supported by the NSFC (Grant Nos. 21677047, U1604137, and 51808199), the China Postdoctoral Science Foundation (Grant No. 2018M630825), and the Plan for University Scientific Innovation Talent of Henan Province (19HASTIT046).

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Authors and Affiliations

  1. MOE Key Laboratory of Yellow River and Huai River Water Environmental and Pollution Control, Henan Key Laboratory for Environmental Pollution Control, School of Environment, Henan Normal University, Xinxiang, 453007, Henan, People’s Republic of China

    Zongwu Wang, Qing Wu, Jing Zhang, Huan Zhang, Jinglan Feng, Shuying Dong & Jianhui Sun

  2. Department of Environment Engineering, Yellow River Conservancy Technical Institute, Kaifeng Key Laboratory of Green Coating Materials, Kaifeng, 475004, Henan, People’s Republic of China

    Zongwu Wang

Authors
  1. Zongwu Wang
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  2. Qing Wu
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  3. Jing Zhang
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  4. Huan Zhang
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  5. Jinglan Feng
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  6. Shuying Dong
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  7. Jianhui Sun
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Correspondence to Shuying Dong or Jianhui Sun.

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Responsible editor: Tito Roberto Cadaval Jr

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Highlights

• Magnetic GO-PDAP/Fe3O4 composite is synthesized by in situ polymerization.

• The adsorbent possessed excellent adsorption capacity of 387.2 mg g−1 toward Pb(II).

• Easy separability, excellent selectivity, and good recyclability were observed.

• The adsorbent exhibited superior performance in battery industry wastewater.

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Wang, Z., Wu, Q., Zhang, J. et al. In situ polymerization of magnetic graphene oxide-diaminopyridine composite for the effective adsorption of Pb(II) and application in battery industry wastewater treatment. Environ Sci Pollut Res 26, 33427–33439 (2019). https://doi.org/10.1007/s11356-019-06511-1

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