Abstract
The photocatalytic technology provides a promising and effective strategy for the transformation and degradation of contaminants. Herein, we accurately fabricated a novel ternary photocatalyst, namely, metal silver (Ag) and carbon dots (CDots) co-doped BiOI nanocomposite (Ag/CDots/BiOI) via the reduction method with ionic liquids 1-butyl-3-methylimidazolium iodine ([Bmim]I) at room temperature. The morphologies and microstructures showed the Ag and CDots were uniformly loaded on the surface of BiOI, forming a ternary system. The characterization results implied that an intense interaction was formed between Ag and CDots on the BiOI, which could achieve the broad spectrum utilization of visible light and boosted the photocatalytic performances. The 0.9-Ag/2-CDots/BiOI (0.9 wt% of Ag, 2 wt% of CDots) presented the highest photocatalytic activity with ~ 100% in 4-Chlorophenol, 68.8% in mineralization, and 87.4% in dechlorination in 6 h under visible light illumination. The enhanced photocatalytic activity could be ascribed to the surface plasmon resonance effect of Ag, the up-converted photoluminescence (PL) properties of CDots, and the electron transfer properties of both Ag and CDots. Moreover, a possible photocatalytic reaction mechanism was discussed in detail by band structure analysis and radical scavenger quenching experiments. This study provides a promising approach for promoting the utilization efficiency for solar energy and sustainable environmental remediation.
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The authors sincerely thank the National Natural Science Foundation of China (51678270, 51761145031) and 111 Project (B16020) for their financial support.
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Guo, Y., Lay, CH., Zhou, D. et al. Enhanced photocatalytic performance of metal silver and carbon dots co-doped BiOI photocatalysts and mechanism investigation. Environ Sci Pollut Res 27, 17516–17529 (2020). https://doi.org/10.1007/s11356-019-05684-z
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DOI: https://doi.org/10.1007/s11356-019-05684-z