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Characterization of industrial odor sources in Binhai New Area of Tianjin, China

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Abstract

Samples were collected from six different organized industrial odor sources in Tianjin Binhai New Area, including pharmacy, paint spraying, oil refinery, petrochemical, resin synthesis, and rubber manufacturing. Chemical analysis was conducted to identify and quantify major odorous volatile organic compounds (VOCs) and subsequently, establish source profiles. Olfactory measurement was used to characterize the sensory stimulating intensity of odorous VOCs and express them as odor concentration. The TVOC mass concentrations of these six sources were between 10.9 and 225.3 mg/m3. Toluene was the most abundant component in profiles of both pharmacy and spraying sources with abundances of 79.1 and 94%, respectively. The petrochemical source was characterized by high levels of o,m,p-xylene (more than 60%). Sulfides were identified almost solely in the rubber manufacturing source. High levels of styrene were found in the resin synthesis source, whereas the oil refinery source was dominated by halocarbons. The odor concentration of oil refinery, spraying, rubber manufacturing, and resin synthesis all exceeded the Chinese emission standards for odor pollutants (GB14554-93) during the study period. Based on industrial processing analysis and factor analysis, toluene, m,p-xylene, carbon disulfide, toluene, three types of halogenated hydrocarbons, and styrene were the markers of pharmacy, petrochemical, rubber manufacturing, spraying, oil refinery, and resin synthesis sources, respectively. Production process and factor analysis methods were used to identify the markers of each odor source, which were based on instrument analysis and olfactory measurement.

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References

  • Abdul-Wahab SA, Bakheit CS, Al-Alawi SM (2005) Principal component and multiple regression analysis in modeling of ground level ozone and factors affecting its concentrations. Environ Model Softw 20:1263–1271

    Article  Google Scholar 

  • Bundy DS (1992) Odor issues with wastes. In: National Livestock Poultry and Aquaculture Waste Management. ASAE- Publication, St. Joseph, pp 288–292

    Google Scholar 

  • Cetin E, Odabasi M, Seyfioglu R (2003) Ambient volatile organic compound (VOC) concentrations around a petrochemical complex and a petroleum refinery. Sci Total Environ 313:103–102

    Article  CAS  Google Scholar 

  • China Association of Automobile Manufactures (2008) China Automotive Industry Yearbook 2008. China Machine Press, Beijing

  • Civan MY, Kuntasal OO, Tuncel G (2011) Source apportionment of ambient VOCs in Bursa, a heavily industrialized city in Turkey. Environ Forensic 12:357–370

    Article  CAS  Google Scholar 

  • Dumanoglu Y, Kara M, Altiok H, Odabasi M, Elbir T, Bayram A (2014) Spatial and seasonal variation and source apportionment of volatile organic compounds (VOCs) in a heavily industrialized region. Atmos Environ 98:168–178

    Article  CAS  Google Scholar 

  • Grosch W (2000) Specficity of the human nose in perceiving food odorants. In Schieberle P, Engel KH (eds) Frontiers of Flavour Science, Proceedings of the Ninth Weurman Flavour Research Symposium. Deutsche Forschungsanstalt fur Lebensmittelchemie, Garching, p 213–219

  • Guo H, Wang T, Louie PKK (2004) Source apportionment of ambient non–methane hydrocarbons in Hong Kong: Application of a principal component analysis/absolute principal component scores (PCA/APCS) receptor model. Environ Pollut 129:489–498

    Article  CAS  Google Scholar 

  • Guo HW, Duan ZH, Zhao Y, Liu YJ, Mustafa MF, Lu WJ, Wang H (2017) Characteristics of volatile compound emission and odor pollution from municipal solid waste treating/disposal facilities of a city in eastern China. Environ Sci Pollut Res 24:18383–18391

    Article  CAS  Google Scholar 

  • Henry RC (1987) Current factor analysis receptor models are ill-posed. Atmos Environ 21:1815–1820

    Article  CAS  Google Scholar 

  • Kabir E, Kim KH (2010) An on-line analysis of 7 odorous VOCs in the ambient air surrounding a large industrial complex. Atmos Environ 44:2492–3502

    Article  CAS  Google Scholar 

  • Kim KH (2006) The properties of calibration errors in the analysis of reduced sulfur compounds by the combination of a loop injection system and the GC/PFPD method. Anal Chim Acta 566:75–80

    Article  CAS  Google Scholar 

  • Kuran P, Sojak L (1996) Environmental analysis of volatile organic compounds in water and sediment by gas chromatography. J Chromatogr A 733:119–141

    Article  CAS  Google Scholar 

  • Lee WS, Chang-Chien GP, Wang LC, Lee WJ, Tsai PJ, Wu KY, Lin C (2004) Source identification of PCDD/fs for various atmospheric environments in a highly Industrialized City. Environ Sci Technol 38:4937–4944

    Article  CAS  Google Scholar 

  • Liu Y, Shao M, Fu LL, Lu SH, Zeng LM, Tang DG (2008) Source profiles of volatile organic compounds (VOCs) measured in China: part I. Atmos Environ 42:6247–6260

    Article  CAS  Google Scholar 

  • Mackie RI, Stroot PG, Varel VH (1998) Biochemical identification and biological origin of key odour components in livestock waste. J Anim Sci 76:1331–1342

    Article  CAS  Google Scholar 

  • Odden W, Barth T (2000) A study of the composition of light hydrocarbons (C5-C13) from pyrolysis of source rock samples. Org Chem 31:211–229

    CAS  Google Scholar 

  • Peng CY, Lan CH, Wu TJ (2009) Investigation of indoor chemical pollutants and perceived odor in an area with complaints of unpleasant odors. Build Environ 44:2106–2113

    Article  Google Scholar 

  • Powers WJ, Van Kempen T, Bundy DS, Sutton A, Hoff SJ (2000) Objective measurement of odours using gas chromatography/mass spectrometry and instrumental technologies. In: Air Pollution from Agricultural Operations. Proceedings of the Second International Conference. St. Joseph, Michigan: ASAEPublication. p. 33–41

  • Rappert S, Muller R (2005) Odor compounds in waste gas emissions from agricultural operations and food industries. Waste Manag 25:877–907

    Google Scholar 

  • Sharma S, Goel A, Gupta D, Kumar A, Mishra A, Kundu S, Chatani S, Klimont Z (2015) Emission inventory of non-methane volatile organic compounds from anthropogenic sources in India. Atmos Environ 102:209–219

    Article  CAS  Google Scholar 

  • Shi GL, Zeng F, Li X, Feng YC, Wang YQ, Liu GX, Zhu T (2011) Estimated contributions and uncertainties of PCA/MLR-CMB results: source apportionment for synthetic and ambient datasets. Atmos Environ 45:2811–2819

    Article  CAS  Google Scholar 

  • State Environmental Protection Administration of China (1993) Air quality-determination of odor-triangle odor bag method (GB/T 14675-93). National Standards of the People's Republic of China : 86–92

  • Stuetz RM, Nicolas J. (2001) Sensor arrays: an inspired idea or and objective measurement of environmental odours. Wat Sci Tech 44(9):53–58

  • U.S. Environmental Protection Agency (1999a) Compendium method TO-14A- determination of volatile organic compounds (VOCs) in ambient air using specially prepared canisters with subsequent analysis by gas chromatography. Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air

  • U.S. Environmental Protection Agency (1999b) Compendium method TO-15- determination of volatile organic compounds (VOCs) in air collected in specially-prepared canisters and analyzed by gas chromatography/mass spectrometry (GC/MS). Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air

  • Yuan B, Shao M, Lu SH, Wang B (2010) Source profiles of volatile organic compounds associated with solvent use in Beijing, China. Atmos Environ 44:1919–1926

    Article  CAS  Google Scholar 

  • Zhang RX, Xu SZ (1993) Odor, odor measurement and assessment standard. Yanshan Petrochemical 4:231–235

    Google Scholar 

  • Zheng JY, Yu YF, Mo ZW, Zhang Z, Wang XM, Yin SS (2013) Industrial sector-based volatile organic compound (VOC) source profiles measured in manufacturing facilities in the Pearl River Delta, China. Sci Total Environ 456–457:127–136

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (21407174) and the Fundamental Research Fund for the Central University (3122016A012).

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Correspondence to Jian-hui Wu.

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Responsible editor: Constantini Samara

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Han, B., Liu, Yt., Wu, Jh. et al. Characterization of industrial odor sources in Binhai New Area of Tianjin, China. Environ Sci Pollut Res 25, 14006–14017 (2018). https://doi.org/10.1007/s11356-018-1596-z

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  • DOI: https://doi.org/10.1007/s11356-018-1596-z

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