Abstract
Coking wastewater after biological treatment still possesses potential environmental risk and should be mineralized further. This work focused on the mineralization of bio-treated coking wastewater using catalytic ozonation by NiO. First, oxalic acid, the typical by-product of advanced oxidation process (AOPs), was used to test the catalytic performance of NiOs, prepared by modified hydrothermal methods upon addition of different surfactants. This demonstrated that NiO upon addition of hexadecyltrimethylammonium (CTAB) had the best catalytic activity, due to its high concentration surface hydroxyl density and strong stability. Moreover, the best NiO was applied for the catalytic ozonation of bio-treated coking wastewater. Under our experimental conditions, the total organic carbon (TOC) removal reached 100% after 420 min. In addition, the spectroscopic analysis suggested that compounds with conjugated structures could be significantly removed by both ozonation and catalytic ozonation. Some of these substances were transformed into by-products with aliphatic C–C and O=C–O groups such as organic acids that can inhibit further mineralization.
Similar content being viewed by others
Change history
29 December 2017
In Table 1, “SO2-4” and “NO-3” should be corrected to “ S O 4 2 − $$ \mathrm{S}{\mathrm{O}}_4^{2-} $$ ” and “ N O 3 − $$ \mathrm{N}{\mathrm{O}}_3^{-} $$ ”, respectively. The original article was corrected.
References
Ates N, Kitis M, Yetis U (2007) Formation of chlorination by-products. In waters with low SUVA-correlations with SUVA and differential UV spectroscopy. Water Res 41(18):4139–4148. https://doi.org/10.1016/j.watres.2007.05.042
Avramescu SM, Bradu C, Udrea I, Mihalache N, Ruta F (2008) Degradation of oxalic acid from aqueous solutions by ozonation in presence of Ni/Al(2)O3 catalysts. Catal Commun 9(14):2386–2391. https://doi.org/10.1016/j.catcom.2008.06.001
Beltran FJ, Rivas FJ, Montero-De-Espinosa R (2003) Ozone-enhanced oxidation of oxalic acid in water with cobalt catalysts. 2. Heterogeneous catalytic ozonation. Ind Eng Chem Res 42(14):3218–3224. https://doi.org/10.1021/ie020999u
Beltran FJ, Aguinaco A, Garcia-Araya JF, Oropesa AL (2008) Ozone and photocatalytic processes to remove the antibiotic sulfamethoxazole from water. Water Res 42(14):3799–3808. https://doi.org/10.1016/j.watres.2008.07.019
Blanco J, Avila P, Suarez S, Yates M, Martin JA, Marzo L, Knapp C (2004) CuO/NiO monolithic catalysts for NOx removal from nitric acid plant flue gas. Chem Eng J 97(1):1–9. https://doi.org/10.1016/S1385-8947(03)00085-8
Buxton GV, Greenstock CL, Helman WP, Ross AB (1988) Critical review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (.OH/.O-) in aqueous solution. J Phys Chem Ref Data 17(2):513–886. https://doi.org/10.1063/1.555805
Chen J, Tian S, Lu J, Xiong Y (2015) Catalytic performance of MgO with different exposed crystal facets towards the ozonation of 4-chlorophenol. Appl Catal A-Gen 506:118–125. https://doi.org/10.1016/j.apcata.2015.09.001
Flyunt R, Leitzke A, Mark G, Mvula E, Reisz E, Schick R, von Sonntag C (2003) Determination of (OH)-O-center dot, O-2(center dot-), and hydroperoxide yields in ozone reactions in aqueous solution. J Phys Chem B 107(30):7242–7253. https://doi.org/10.1021/jp022455b
Gnanam S, Rajendran V (2013) Influence of various surfactants on size, morphology, and optical properties of CeO2 nanostructures via facile hydrothermal route. J Nanopart 839391–839396. https://doi.org/10.1155/2013/839391
Grebel JE, Pignatello JJ, Mitch WA (2010) Effect of halide ions and carbonates on organic contaminant degradation by hydroxyl radical-based advanced oxidation processes in saline waters. Environ Sci Technol 44(17):6822–6828. https://doi.org/10.1021/es1010225
Huang YX, Cui CC, Zhang DF, Li L, Pan D (2015) Heterogeneous catalytic ozonation of dibutyl phthalate in aqueous solution in the presence of iron-loaded activated carbon. Chemosphere 119:295–301. https://doi.org/10.1016/j.chemosphere.2014.06.060
Huang Y, Sun Y, Xu Z, Luo M, Zhu C, Li L (2017) Removal of aqueous oxalic acid by heterogeneous catalytic ozonation with MnO x /sewage sludge-derived activated carbon as catalysts. Science of The Total Environment 575:50–57
Jin PK, Jin X, Bjerkelund VA, Osterhus SW, Wang XC, Yang L (2016) A study on the reactivity characteristics of dissolved effluent organic matter (EfOM) from municipal wastewater treatment plant during ozonation. Water Res 88:643–652. https://doi.org/10.1016/j.watres.2015.10.060
Kasprzyk-Hordern B, Ziolek B, Nawrocki J (2003) Catalytic ozonation and methods of enhancing molecular ozone reactions in water treatment. Appl Catal B-Environ 46(4):639–669. https://doi.org/10.1016/S0926-3373(03)00326-6
Le RBY, Taube H (1949) The kinetics of the reaction of ozone and chloride ion in acid aqueous solution. J Am Chem Soc 71(12):4100–4105. https://doi.org/10.1021/ja01180a063
Magallanes D, Rodriguez JL, Poznyak T, Valenzuela MA, Lartundo L, Chairez I (2015) Efficient mineralization of benzoic and phthalic acids in water by catalytic ozonation using a nickel oxide catalyst. New J Chem 39(10):7839–7848. https://doi.org/10.1039/c5nj01385b
Mahmoud HR (2016) Novel amorphous mesoporous 0.25Cr(2)O(3)-0.75ZrO(2) nanomaterials synthesized by a surfactant-assisted hydrothermal method for ethanol oxidation. J Alloys Compd 687:954–963. https://doi.org/10.1016/j.jallcom.2016.06.265
Mansour AN (1994) Characterization of NiO by XPS. Surf Sci Spectra 3(3):231–238. https://doi.org/10.1116/1.1247751
Martins RC, Rodrigues V, Costa MR, Castro LM, Quinta-Ferreira RM (2016) Effect of calcination temperature over the performance of Mn-Ce-O on the catalytic ozonation of olive mill wastewater. Ozone-Sci Eng 38(4):261–271. https://doi.org/10.1080/01919512.2015.1134307
Mashayekh-Salehi A, Moussavi G, Yaghmaeian K (2017) Preparation, characterization and catalytic activity of a novel mesoporous nanocrystalline MgO nanoparticle for ozonation of acetaminophen as an emerging water contaminant. Chem Eng J 310(1):157–169. https://doi.org/10.1016/j.cej.2016.10.096
Orge CA, Orfao JJM, Pereira MFR (2012) Composites of manganese oxide with carbon materials as catalysts for the ozonation of oxalic acid. J Hazard Mater 213:133–139. https://doi.org/10.1016/j.jhazmat.2012.01.066
Purushothaman KK, Manohara Babu I, Sethuraman B, Muralidharan G (2013) Nanosheet-Assembled NiO Microstructures for High-Performance Supercapacitors. ACS Appl Mater Interfaces 5(21):10767–10773
Ren YM, Dong Q, Feng J, Ma J, Wen Q, Zhang ML (2012) Magnetic porous ferrospinel NiFe2O4: a novel ozonation catalyst with strong catalytic property for degradation of di-n-butyl phthalate and convenient separation from water. J Colloid Interface Sci 382:90–96. https://doi.org/10.1016/j.jcis.2012.05.053
Rodriguez JL, Valenzuela MA, Pola F, Tiznado H, Poznyak T (2012) Photodeposition of Ni nanoparticles on TiO2 and their application in the catalytic ozonation of 2,4-dichlorophenoxyacetic acid. J Mol Catal A Chem 353:29–36. https://doi.org/10.1016/j.molcata.2011.11.001
Rodriguez JL, Valenzuela MA, Poznyak T, Lartundo L, Chairez I (2013) Reactivity of NiO for 2,4-D degradation with ozone: XPS studies. J Hazard Mater 262:472–481. https://doi.org/10.1016/j.jhazmat.2013.08.041
Rong XS, Qiu FX, Qin J, Zhao H, Yan J, Yang DY (2015) A facile hydrothermal synthesis, adsorption kinetics and isotherms to Congo Red azo-dye from aqueous solution of NiO/graphene nanosheets adsorbent. J Ind Eng Chem 26:354–363. https://doi.org/10.1016/j.jiec.2014.12.009
Siddiqui H, Qureshi MS, Haque FZ (2016) Surfactant assisted wet chemical synthesis of copper oxide (CuO) nanostructures and their spectroscopic analysis. Optik 127(5):2740–2747. https://doi.org/10.1016/j.ijleo.2015.11.220
Stoyanova M, Konova P, Nikolov P, Naydenov A, Christoskova S, Mehandjiev D (2006) Alumina-supported nickel oxide for ozone decomposition and catalytic ozonation of CO and VOCs. Chem Eng J 122(1–2):41–46. https://doi.org/10.1016/j.cej.2006.05.018
Sun XM, Chen X, Deng ZX, Li YD (2003) A CTAB-assisted hydrothermal orientation growth of ZnO nanorods. Mater Chem Phys 78 (PII S0254–0584(02)00310–31):99–104. https://doi.org/10.1016/S0254-0584(02)00310-3
Sun J, Yan X, Lv K, Sun S, Deng KJ, DD D (2013) Photocatalytic degradation pathway for azo dye in TiO2/UV/O-3 system: hydroxyl radical versus hole. J Mol Catal A-Chem 367:31–37. https://doi.org/10.1016/j.molcata.2012.10.020
Tan XQ, Wan YF, Huang YJ, He C, Zhang ZL, He ZY, Hu LL, Zeng JW, Shu D (2017) Three-dimensional MnO2 porous hollow microspheres for enhanced activity as ozonation catalysts in degradation of bisphenol A. J Hazard Mater 321:162–172. https://doi.org/10.1016/j.jhazmat.2016.09.013
Wang ZH, Yuan RX, Guo YG, Xu L, Liu JS (2011) Effects of chloride ions on bleaching of azo dyes by Co2+/oxone regent: kinetic analysis. J Hazard Mater 190(1–3):1083–1087. https://doi.org/10.1016/j.jhazmat.2011.04.016
Wang YX, Xie YB, Sun HQ, Xiao JD, Cao HB, Wang SB (2016) Efficient catalytic ozonation over reduced graphene oxide for p-hydroxylbenzoic acid (PHBA) destruction: active site and mechanism. ACS Appl Mater Interfaces 8(15):9710–9720. https://doi.org/10.1021/acsami.6b01175
Wei CH, Zhang FZ, Hu Y, Feng CH, HZ W (2017) Ozonation in water treatment: the generation, basic properties of ozone and its practical application. Rev Chem Eng 33(1):49–89. https://doi.org/10.1515/revce-2016-0008
Wu MS, Huang YA, Yang CH, Jow HH (2007) Electrodeposition of nanoporous nickel oxide film for electrochemical capacitors. Int J Hydrog Energy 32(17):4153–4159. https://doi.org/10.1016/j.ijhydene.2007.06.001
Xu Y, Xu R (2015) Nickel-based cocatalysts for photocatalytic hydrogen production. Appl Surf Sci 351:779–793. https://doi.org/10.1016/j.apsusc.2015.05.171
Yu XY (2004) Critical evaluation of rate constants and equilibrium constants of hydrogen peroxide photolysis in acidic aqueous solutions containing chloride ions. J Phys Chem Ref Data 33(3):747. https://doi.org/10.1063/1.1695414
Yu XB, Xu RH, Wei CH, Wu HZ (2016) Removal of cyanide compounds from coking wastewater by ferrous sulfate: improvement of biodegradability. J Hazard Mater 302:468–474. https://doi.org/10.1016/j.jhazmat.2015.10.013
Zhang T, Croue J (2014) Catalytic ozonation not relying on hydroxyl radical oxidation: a selective and competitive reaction process related to metal-carboxylate complexes. Appl Catal B-Environ 144:831–839. https://doi.org/10.1016/j.apcatb.2013.08.023
Zhang T, Li CJ, Ma J, Tian H, Qiang ZM (2008) Surface hydroxyl groups of synthetic alpha-FeOOH in promoting (OH)-O-center dot generation from aqueous ozone: property and activity relationship. Appl Catal B-Environ 82(1–2):131–137. https://doi.org/10.1016/j.apcatb.2008.01.008
Zhang T, Li WW, Croue J (2011) Catalytic ozonation of oxalate with a cerium supported palladium oxide: an efficient degradation not relying on hydroxyl radical oxidation. Environ Sci Technol 45(21):9339–9346. https://doi.org/10.1021/es202209j
Zhang WH, Wei CH, Feng CH, Yan B, Li N, Peng PG, JM F (2012) Coking wastewater treatment plant as a source of polycyclic aromatic hydrocarbons (PAHs) to the atmosphere and health-risk assessment for workers. Sci Total Environ 432:396–403. https://doi.org/10.1016/j.scitotenv.2012.06.010
Zhang FZ, Wei CH, Hu Y, Wu HZ (2015) Zinc ferrite catalysts for ozonation of aqueous organic contaminants: phenol and bio-treated coking wastewater. Sep Purif Technol 156:625–635. https://doi.org/10.1016/j.seppur.2015.10.058
Zhao H, Dong YM, Jiang PP, Wang GL, Zhang JJ, Zhang C (2015) ZnAl2O4 as a novel high-surface-area ozonation catalyst: one-step green synthesis, catalytic performance and mechanism. Chem Eng J 260:623–630. https://doi.org/10.1016/j.cej.2014.09.034
Author information
Authors and Affiliations
Corresponding author
Additional information
Responsible editor: Bingcai Pan
In Table 1, “SO2-4” and “NO-3” should be corrected to “\( {\mathrm{SO}}_4^{2-} \)” and \( {\mathrm{NO}}_3^{-} \), respectively. The original article was revised.
A correction to this article is available online at https://doi.org/10.1007/s11356-017-1095-7.
Electronic supplementary material
ESM 1
(DOCX 195 kb)
Rights and permissions
About this article
Cite this article
Wu, K., Zhang, F., Wu, H. et al. The mineralization of oxalic acid and bio-treated coking wastewater by catalytic ozonation using nickel oxide. Environ Sci Pollut Res 25, 2389–2400 (2018). https://doi.org/10.1007/s11356-017-0597-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11356-017-0597-7