Abstract
The properties of tribochemical films play an important, or even the key, role with respect to friction in boundary lubrication. While their chemical behavior has already been widely studied, their mechanical properties are much less well understood. However, their nanoscale mechanical properties and behavior may reveal important information about a correlation with the macroscopic friction behavior. In this investigation, we looked at steel, a-C:H and Si-DLC in contact with steel lubricated using two commercial oils containing different amount of SAPS additives (E6 and E7 grade) and a mineral base oil containing the ZDDP additive. The tribofilms were characterized using an atomic force microscope with seven different parameters, i.e., the topography (features morphology), tribofilm surface coverage, nano-roughness, adhesion, film thickness, lateral force, i.e., nanoscale friction, and the film stiffness through force modulation. The results confirmed the formation of tribofilms on all the selected coatings and showed that the film formation and its nanoscale properties are dependent on the coating and the additive. Two distinctive groups of parameters were identified: one closely related to the surface energy of the materials and the other clearly distinguishing the DLC coatings from the steel. The adhesion and tribofilm thickness were found to correlate directly with the macroscopic friction, while the other parameters have higher-order dependences.
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Kalin, M., Velkavrh, I., Vižintin, J., Ožbolt, L.: Review of boundary lubrication mechanisms of DLC coatings used in mechanical applications. Meccanica 43(6), 623–637 (2008). doi:10.1007/s11012-008-9149-z
Kalin, M., Roman, E., Ožbolt, L., Vižintin, J.: Metal-doped (Ti, WC) diamond-like-carbon coatings: reactions with extreme-pressure oil additives under tribological and static conditions. Thin Solid Films 518(15), 4336–4344 (2010). doi:10.1016/j.tsf.2010.02.066
Vengudusamy, B., Mufti, R.A., Lamb, G.D., Green, J.H., Spikes, H.A.: Friction properties of DLC/DLC contacts in base oil. Tribol. Int. 44(7–8), 922–932 (2011). doi:10.1016/j.triboint.2011.03.006
Mabuchi, Y., Higuchi, T., Inagaki, Y., Kousaka, H., Umehara, N.: Wear analysis of hydrogen-free diamond-like carbon coatings under a lubricated condition. Wear 298–299, 48–56 (2013). doi:10.1016/j.wear.2012.11.046
Yang, L., Neville, A., Brown, A., Ransom, P., Morina, A.: Friction reduction mechanisms in boundary lubricated W-doped DLC coatings. Tribol. Int. 70, 26–33 (2014). doi:10.1016/j.triboint.2013.09.020
Shum, P.W., Zhou, Z.F., Li, K.Y.: Investigation of the tribological properties of the different textured DLC coatings under reciprocating lubricated conditions. Tribol. Int. 65, 259–264 (2013). doi:10.1016/j.triboint.2013.01.012
Topolovec-Miklozic, K., Lockwood, F., Spikes, H.: Behaviour of boundary lubricating additives on DLC coatings. Wear 265(11–12), 1893–1901 (2008). doi:10.1016/j.wear.2008.04.051
Kalin, M., Vižintin, J., Barriga, J., Vercammen, K., Acker, K., Arnšek, A.: The effect of doping elements and oil additives on the tribological performance of boundary-lubricated DLC/DLC contacts. Tribol. Lett. 17(4), 679–688 (2004)
Abdullah Tasdemir, H., Tokoroyama, T., Kousaka, H., Umehara, N., Mabuchi, Y.: Influence of zinc dialkyldithiophosphate tribofilm formation on the tribological performance of self-mated diamond-like carbon contacts under boundary lubrication. Thin Solid Films 562, 389–397 (2014). doi:10.1016/j.tsf.2014.05.004
De Barros Bouchet, M.I., Martin, J.M.: New trends in boundary lubrication of DLC coatings. In: Donnet, C., Erdemir, A. (eds.) Tribology of Diamond-Like Carbon Films, pp. 591–619. Springer, US (2008)
Forsberg, P., Gustavsson, F., Renman, V., Hieke, A., Jacobson, S.: Performance of DLC coatings in heated commercial engine oils. Wear 304(1), 211–222 (2013)
Biswas, S.K.: Some mechanisms of tribofilm formation in metal/metal and ceramic/metal sliding interactions. Wear 245(1–2), 178–189 (2000). doi:10.1016/S0043-1648(00)00477-4
Kosarieh, S., Morina, A., Lainé, E., Flemming, J., Neville, A.: Tribological performance and tribochemical processes in a DLC/steel system when lubricated in a fully formulated oil and base oil. Surf. Coat. Technol. 217, 1–12 (2013). doi:10.1016/j.surfcoat.2012.11.065
Vengudusamy, B., Green, J.H., Lamb, G.D., Spikes, H.A.: Behaviour of MoDTC in DLC/DLC and DLC/steel contacts. Tribol. Int. 54, 68–76 (2012). doi:10.1016/j.triboint.2012.04.028
Vengudusamy, B., Green, J.H., Lamb, G.D., Spikes, H.A.: Tribological properties of tribofilms formed from ZDDP in DLC/DLC and DLC/steel contacts. Tribol. Int. 44(2), 165–174 (2011). doi:10.1016/j.triboint.2010.10.023
Kalin, M., Vizintin, J.: A comparison of the tribological behaviour of steel/steel, steel/DLC and DLC/DLC contacts when lubricated with mineral and biodegradable oils. Wear 261(1), 22–31 (2006)
de Barros’Bouchet, M.I., Martin, J.M., Le-Mogne, T., Vacher, B.: Boundary lubrication mechanisms of carbon coatings by MoDTC and ZDDP additives. Tribol. Int. 38(3), 257–264 (2005). doi:10.1016/j.triboint.2004.08.009
Equey, S., Roos, S., Mueller, U., Hauert, R., Spencer, N.D., Crockett, R.: Tribofilm formation from ZnDTP on diamond-like carbon. Wear 264(3–4), 316–321 (2008). doi:10.1016/j.wear.2007.03.012
Vengudusamy, B., Grafl, A., Preinfalk, K.: Tribological properties of hydrogenated amorphous carbon under dry and lubricated conditions. Diam. Relat. Mater. 41, 53–64 (2014). doi:10.1016/j.diamond.2013.11.009
Haque, T., Morina, A., Neville, A., Kapadia, R., Arrowsmith, S.: Study of the ZDDP Antiwear Tribofilm Formed on the DLC Coating Using AFM and XPS Techniques. Journal of ASTM International (JAI) 4(7), 11 (2007)
Topolovec-Miklozic, K., Forbus, T.R., Spikes, H.A.: Film thickness and roughness of ZDDP antiwear films. Tribol. Lett. 26(2), 161–171 (2007)
Equey, S., Roos, S., Mueller, U., Hauert, R., Spencer, N.D., Crockett, R.: Reactions of zinc-free anti-wear additives in DLC/DLC and steel/steel contacts. Tribol. Int. 41(11), 1090–1096 (2008)
Ahn, H.S., Chizhik, S.A., Dubravin, A.M., Kazachenko, V.P., Popov, V.V.: Application of phase contrast imaging atomic force microscopy to tribofilms on DLC coatings. Wear 249(7), 617–625 (2001). doi:10.1016/s0043-1648(01)00694-9
Xu, J., Kawaguchi, M., Kato, T.: Evolution of transfer layers on steel balls sliding against hydrogenated amorphous carbon coatings in ambient air. Tribol. Int. 70, 42–51 (2014)
Kubo, T., Fujiwara, S., Nanao, H., Minami, I., Mori, S.: Boundary film formation from overbased calcium sulfonate additives during running-in process of steel–DLC contact. Wear 265(3), 461–467 (2008)
Haque, T., Morina, A., Neville, A., Kapadia, R., Arrowsmith, S.: Non-ferrous coating/lubricant interactions in tribological contacts: assessment of tribofilms. Tribol. Int. 40(10–12), 1603–1612 (2007). doi:10.1016/j.triboint.2007.01.023
Morina, A., Neville, A.: Understanding the composition and low friction tribofilm formation/removal in boundary lubrication. Tribol. Int. 40(10), 1696–1704 (2007)
Gangopadhyay, A., Sinha, K., Uy, D., McWatt, D.G., Zdrodowski, R.J., Simko, S.J.: Friction, wear, and surface film formation characteristics of diamond-like carbon thin coating in valvetrain application. Tribol. Trans. 54(1), 104–114 (2010)
Lamberton, R.W., Zhao, J.F., Magill, D., McLaughlin, J.A., Maguire, P.D.: A study of ultra-thin film ion beam deposited (IBD) hydrogenated amorphous carbon (a-C:H) using atomic force microscopy (AFM) and transmission electron microscopy (TEM). Diam. Relat. Mater. 7(7), 1054–1058 (1998). doi:10.1016/S0925-9635(98)00153-8
Kalin, M., Vizintin, J.: Differences in the tribological mechanisms when using non-doped, metal-doped (Ti, WC), and non-metal-doped (Si) diamond-like carbon against steel under boundary lubrication, with and without oil additives. Thin Solid Films 515(4), 2734–2747 (2006)
Kalin, M., Polajnar, M.: The correlation between the surface energy, the contact angle and the spreading parameter, and their relevance for the wetting behaviour of DLC with lubricating oils. Tribol. Int. 66, 225–233 (2013). doi:10.1016/j.triboint.2013.05.007
Rudnick, L.R.: Synthetics, Mineral Oils, and Bio-based Lubricants: Chemistry and Technology. CRC Press, Boca Raton (2013)
Fuller, M.L.S., Kasrai, M., Bancroft, G.M., Fyfe, K., Tan, K.H.: Solution decomposition of zinc dialkyl dithiophosphate and its effect on antiwear and thermal film formation studied by X-ray absorption spectroscopy. Tribol. Int. 31(10), 627–644 (1998). doi:10.1016/S0301-679X(98)00084-X
Martin, J.M., Onodera, T., Minfray, C., Dassenoy, F., Miyamoto, A.: The origin of anti-wear chemistry of ZDDP. Faraday Discuss. 156, 311–323 (2012)
Spikes, H.: The history and mechanisms of ZDDP. Tribol. Lett. 17(3), 469–489 (2004). doi:10.1023/B:TRIL.0000044495.26882.b5
Zhang, Z., Yamaguchi, E.S., Kasrai, M., Bancroft, G.M.: Tribofilms generated from ZDDP and DDP on steel surfaces: part 1, growth, wear and morphology. Tribol. Lett. 19(3), 211–220 (2005). doi:10.1007/s11249-005-6148-2
Horcas, I., Fernández, R., Gómez-Rodríguez, J.M., Colchero, J., Gómez-Herrero, J., Baro, A.M.: WSXM: a software for scanning probe microscopy and a tool for nanotechnology. Rev. Sci. Instrum. 78(1), 013705 (2007). doi:10.1063/1.2432410
Maivald, P., Butt, H.J., Gould, S.A.C., Prater, C.B., Drake, B., Gurley, J.A., Elings, V.B., Hansma, P.K.: Using force modulation to image surface elasticities with the atomic force microscope. Nanotechnology 2(2), 103 (1991)
Li, F.-B., Thompson, G.E., Newman, R.C.: Force modulation atomic force microscopy: background, development and application to electrodeposited cerium oxide films. Appl. Surf. Sci. 126(1–2), 21–33 (1998). doi:10.1016/S0169-4332(97)00590-4
Martin, P.M.: Handbook of deposition technologies for films and coatings: science, applications and technology. William Andrew, Norwich (2009)
4287:1997, I.: ISO 4287:1997. In: Geometrical Product Specifications (GPS)—Surface Texture: Profile Method—Terms, Definitions and Surface Texture Parameters, p. 25 (1997)
Aktary, M., McDermott, M.T., McAlpine, G.A.: Morphology and nanomechanical properties of ZDDP antiwear films as a function of tribological contact time. Tribol. Lett. 12(3), 155–162 (2002)
Mourhatch, R., Aswath, P.B.: Tribological behavior and nature of tribofilms generated from fluorinated ZDDP in comparison to ZDDP under extreme pressure conditions—part II: morphology and nanoscale properties of tribofilms. Tribol. Int. 44(3), 201–210 (2011). doi:10.1016/j.triboint.2010.10.035
Boyde, S.: Green lubricants. Environmental benefits and impacts of lubrication. Green Chem. 4(4), 293–307 (2002)
Bec, S., Tonck, A., Georges, J.-M., Coy, R.C., Bell, J.C., Roper, G.W.: Relationship between mechanical properties and structures of zinc dithiophosphate anti-wear films. Proc. R. Soc. Lond. Ser. A Math. Phys. Eng. Sci. 455(1992), 4181–4203 (1999)
Kalin, M., Velkavrh, I.: Non-conventional inverse-Stribeck-curve behaviour and other characteristics of DLC coatings in all lubrication regimes. Wear 297(1–2), 911–918 (2013). doi:10.1016/j.wear.2012.11.010
Qu, J., Meyer Iii, H.M., Cai, Z.-B., Ma, C., Luo, H.: Characterization of ZDDP and ionic liquid tribofilms on non-metallic coatings providing insights of tribofilm formation mechanisms. Wear 332–333, 1273–1285 (2015). doi:10.1016/j.wear.2015.01.076
Miyake, S., Saito, T., Yasuda, Y., Okamoto, Y., Kano, M.: Improvement of boundary lubrication properties of diamond-like carbon (DLC) films due to metal addition. Tribol. Int. 37(9), 751–761 (2004). doi:10.1016/j.triboint.2004.01.014
Ban, M., Ryoji, M., Fujii, S., Fujioka, J.: Tribological characteristics of Si-containing diamond-like carbon films under oil-lubrication. Wear 253(3–4), 331–338 (2002). doi:10.1016/s0043-1648(02)00156-4
Kalin, M., Vižintin, J., Vercammen, K., Barriga, J., Arnšek, A.: The lubrication of DLC coatings with mineral and biodegradable oils having different polar and saturation characteristics. Surf. Coat. Technol. 200(14–15), 4515–4522 (2006). doi:10.1016/j.surfcoat.2005.03.016
Ouyang, J.H., Sasaki, S.: Friction and wear characteristics of a Ti-containing diamond-like carbon coating with an SRV tester at high contact load and elevated temperature. Surf. Coat. Technol. 195(2–3), 234–244 (2005). doi:10.1016/j.surfcoat.2004.06.041
Velkavrh, I., Kalin, M., Vizintin, J.: The performance and mechanisms of DLC-coated surfaces in contact with steel in boundary-lubrication conditions: a review. Strojniški vestn. 54(3), 189–206 (2008)
Ye, J., Kano, M., Yasuda, Y.: Evaluation of local mechanical properties in depth in MoDTC/ZDDP and ZDDP tribochemical reacted films using nanoindentation. Tribol. Lett. 13(1), 41–47 (2002). doi:10.1023/a:1016559807453
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The authors wish to acknowledge Slovenian Research Agency of the Republic of Slovenia for financial support, Contracts No. 1000-11-310114.
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Oblak, E., Kalin, M. Relationship Between the Nanoscale Topographical and Mechanical Properties of Tribochemical Films on DLC Coatings and Their Macroscopic Friction Behavior. Tribol Lett 59, 49 (2015). https://doi.org/10.1007/s11249-015-0575-5
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DOI: https://doi.org/10.1007/s11249-015-0575-5