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Wear behaviour of carbon nanotube reinforced epoxy resin composites

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Abstract

This paper deals with the effect of a multi-walled carbon nanotube (MWCNT) reinforcement on the wear behaviour of Epoxy (EP) composites. Firstly, various dispersion methods were compared. Secondly, the optimum CNT amount was evaluated. In a third step, dry lubricants were added to the optimised EP/CNT composite. Finally, the influence of the steel counterpart (martensitic bearing steel 100Cr6 and austenitic stainless steel X5CrNi18-10) was studied. The preparation method was found to have a decisive effect on the wear behaviour of the composite. A pre-treatment of the CNTs in concentrated nitric acid proved beneficial. Even more important was the mixing method. A dual asymmetric centrifuge delivered so good wear results that the pre-treatment could be skipped. The optimum CNT content was at about 1 wt%, regardless of the preparation method. The lowest wear rates were found after addition of 10 wt% graphite. MoS2 proved to be less effective and Polytetrafluorethylene (PTFE) even increased the wear. The wear rates against the unalloyed martensitic steel were far higher than against austenitic stainless steel.

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References

  1. Ch. Roscher, J. Adam, Ch. Eger and M. Pyrlik, Proc. RadTech 2002, 28 April–1 May 2002, IN

  2. Gojny F.H., Wichmann M.H.G., Köpke U., Fiedler B., Schulte K. (2004) Comp. Sci. Technol. 64:2363–2371

    Article  CAS  Google Scholar 

  3. Wang Q.-H., Xue Q.-J., Liu W.-M., Chen J.-M. (2000) Wear 243:140–146

    Article  CAS  Google Scholar 

  4. Wang Q., Xue Q., Shen W., Zhang J. (1998) J. Appl. Polym. Sci. 69: 135–141

    Article  CAS  Google Scholar 

  5. Wang Q., Xue Q., Shen W., Liu W. (1996) Wear 196: 82–86

    Article  CAS  Google Scholar 

  6. O. Jacobs, B. Schädel and M. Cholewa, verschleißminimierte Nano-Composites auf Epoxidharzbasis, Proc. Tribologie-Fachtagung, Ges. f. Tribologie, 27–29 Sept. 2004, Göttingen

  7. Shi G., Zhang M.Q., Rong M.Z., Wetzel B., Friedrich K. (2004) Wear 256:1072–1081

    Article  CAS  Google Scholar 

  8. Shi G., Zhang M.Q., Rong M.Z., Wetzel B., Friedrich K. (2003) Wear 254:784–796

    Article  CAS  Google Scholar 

  9. M. Meyyappan, ed, Carbon nanotubes: Science and Applications (CRC Press, Boca Raton, Florida, 2005)

  10. Ruoff R.S., Lorents D.C. (1995) Carbon 33:925–930

    Article  CAS  Google Scholar 

  11. Gojny F.H., Schulte K. (2004) Comp. Sci. Technol. 64:2303–2308

    Article  CAS  Google Scholar 

  12. Allaoui A., Bai S., Cheng H.M., Bai J.B. (2002) Comp. Sci. Technol. 62:1993–1998

    Article  CAS  Google Scholar 

  13. Chen W.X., Li F., Han G., Xia J.B., Wang L.Y., Tu J.P., Xu Z.D. (2003) Tribol. Lett. 15: 275–278

    Article  CAS  Google Scholar 

  14. Chen W.X., Tu J.P., Wang L.Y., Gan H.Y., Xu Z.D., Zhang X.B. (2003) Carbon 41:215–222

    Article  CAS  Google Scholar 

  15. Lim D.-S., An J.-W., Lee H.J. (2002) Wear 252: 512–517

    Article  CAS  Google Scholar 

  16. Zoo Y.-S., An J.-W., Lim D.-P., Lim D.-S. (2004) Tribol. Lett. 16:305–309

    Article  CAS  Google Scholar 

  17. N.N., Neukadur EP 571, Data Sheet (Altropol, Stockelsdorf, Germany, 2005)

  18. N.N., Multi-Walled Carbon Nanotubes, Data Sheet (Namigang Co., Shenzhen, China, 2005)

  19. F.H. Gojny, Private communication, TU Hamburt-Harburg, 2005

  20. K. Schulte, NINa-Workshop Nanomaterialien in Norddeutschland, 17–18 May, 2005, Schleswig

  21. Jacobs O., Jaskulka R., Yang F., Wu W. (2004) Wear 256:9–15

    Article  CAS  Google Scholar 

  22. Jacobs O., Jaskulka R., Yan Ch., Wu W. (2005) Tribol. Lett. 18:359–372

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors would like to thank some colleagues from the Fachhochschule Lübeck for their support and helpful discussions: Prof. B. Voß conducted the SEM investigations, Dipl.-Ing. E.-O. Reimann introduced us to the viscosity measurements and provided the according test rig, Ms A.-Ch. Heidenreich and Dipl.-Ing. A. Frederich made the equipment available needed for the pre-treatment in nitric acid. Altropol, Stockelsdorf, Germany supplied the epoxy resin free of charge.

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Jacobs, O., Xu, W., Schädel, B. et al. Wear behaviour of carbon nanotube reinforced epoxy resin composites. Tribol Lett 23, 65–75 (2006). https://doi.org/10.1007/s11249-006-9042-7

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  • DOI: https://doi.org/10.1007/s11249-006-9042-7

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