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Ordered Mesoporous Aluminosilicates Assembled from Dissolved LTA Precursors

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Abstract

Aluminosilicate sols containing Si–O–Al bonds were obtained by dissolving zeolite LTA crystals in HCl solution. The solutions were used as single-source molecular precursors of silicon and aluminum. Highly ordered cage-like mesoporous aluminosilicates with Si/Al ratios ranging from 13 to 35 were synthesized using PEO106PPO70PEO106 triblock copolymer aqueous solution and LTA dissolved in HCl solution under mild acidic conditions.

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Acknowledgment

The authors wish to thank Associate Prof. J. Hayashi at Kansai University for nitrogen sorption measurements.

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Authors and Affiliations

  1. Department of Chemical Engineering, Faculty of Engineering, Kansai University, 3-3-35 Yamate-cho, Suita-shi, Osaka, 564-8680, Japan

    Shunsuke Tanaka, Norihito Nakatani, Hiroaki Okada & Yoshikazu Miyake

  2. High Technology Research Center, Kansai University, 3-3-35 Yamate-cho, Suita-shi, Osaka, 564-8680, Japan

    Shunsuke Tanaka & Yoshikazu Miyake

Authors
  1. Shunsuke Tanaka
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  2. Norihito Nakatani
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  3. Hiroaki Okada
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  4. Yoshikazu Miyake
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Correspondence to Shunsuke Tanaka.

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Tanaka, S., Nakatani, N., Okada, H. et al. Ordered Mesoporous Aluminosilicates Assembled from Dissolved LTA Precursors. Top Catal 53, 224–230 (2010). https://doi.org/10.1007/s11244-009-9415-x

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  • DOI: https://doi.org/10.1007/s11244-009-9415-x

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