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Highly Stable Amine-modified Mesoporous Silica Materials for Efficient CO2 Capture

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Abstract

A highly efficient and stable solid adsorbent invoking a direct incorporation of tetraethylenepentamine (TEPA) onto the as-synthesized mesocelullar silica foam (MSF) has been developed for CO2 capture. Unlike most amine-functionalized silicas, which typically exhibit CO2 adsorption capacities less than 2.0 mmol/g, such organic template occluded mesoporous silica-amine composites exhibited remarkably high CO2 uptake as high as 4.5 mmol/g at 348 K and 1 atm. Moreover, notable increases in CO2 adsorption capacities of the composite materials were observed when in the presence of humidity. Durability test performed by cyclic adsorption–desorption revealed that such adsorbents also possess excellent stability, even though a slight decrease in adsorption capacity over time was observed.

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References

  1. Song C (2006) Catal Today 115:2

    Article  CAS  Google Scholar 

  2. Figueroa JD, Fout T, Plasynski S, Mcllvried H, Srivastava RD (2008) Int J Greenh Gas Control 2:9

    Article  CAS  Google Scholar 

  3. Morris RE, Wheatley PS (2008) Angew Chem Int Ed 47:4966

    Article  CAS  Google Scholar 

  4. Satyapal S, Filburn T, Trela J, Strange J (2001) Energy Fuels 15:250

    Article  CAS  Google Scholar 

  5. Rinker E, Ashour SS, Sandall OC (2000) Ind Eng Chem Res 39:4346

    Article  CAS  Google Scholar 

  6. Little RJ, Versteeg GF, Van Swaaij WPM (1992) Chem Eng Sci 47:2027

    Article  Google Scholar 

  7. Veawab A, Tontiwachwuthikul P, Chakma A (1999) Ind Eng Chem Res 38:3917

    Article  CAS  Google Scholar 

  8. Hook RJ (1997) Ind Eng Chem Res 36:1779

    Article  CAS  Google Scholar 

  9. Jensen MB, Petersson LGM, Swang O, Olsbye U (2005) J Phys Chem B 109:16774

    Article  CAS  Google Scholar 

  10. Feng B, Liu W, Li X, An H (2006) Energy Fuel 20:2417

    Article  CAS  Google Scholar 

  11. Mosqueda HA, Bazquez C, Bosch P, Pfeiffer H (2006) Chem Mater 18:2307

    Article  CAS  Google Scholar 

  12. Ebner AD, Reynolds SP, Ritter JA (2006) Ind Eng Chem Res 45:6378

    Article  CAS  Google Scholar 

  13. Essaki K, Nakagawa K, Kato M (2004) J Chem Eng Jpn 37:772

    Article  CAS  Google Scholar 

  14. Kato M, Essaki K, Yoshikawa S, Nakagawa K, Uemoto H (2004) J Ceram Soc Jpn 112:S1338

    Article  Google Scholar 

  15. Pfeiffer H, Bosch P (2005) Chem Mater 17:1704

    Article  CAS  Google Scholar 

  16. Ochoa-Fernández E, Rønning M, Grande T, Chen D (2006) Chem Mater 18:6037

    Article  CAS  Google Scholar 

  17. Venegas MJ, Fregoso-Israel E, Escamilla R, Pfeiffer H (2007) Ind Eng Chem Res 46:2407

    Article  CAS  Google Scholar 

  18. Tang J, Tang H, Sun W, Radosz M, Shen Y (2005) J Polym Sci A 43:5477

    Article  CAS  Google Scholar 

  19. Zhang J, Zhang S, Dong K, Zhang Y, Shen Y, Lv X (2006) Chem Eur J 12:4021

    Article  CAS  Google Scholar 

  20. Himeno S, Tomita T, Suzuki K, Yoshida S (2007) Microporous Mesoporous Mater 98:62

    Article  CAS  Google Scholar 

  21. Li P, Tezel H (2007) Microporous Mesoporous Mater 98:94

    Article  CAS  Google Scholar 

  22. Maurin G, Bell R, Kuchta B, Poyet T, Llewellyn P (2005) Adsorption 11:331

    Article  Google Scholar 

  23. Siriwardance RV, Shen MS, Fisher EP (2005) Energy Fuels 19:1153

    Article  CAS  Google Scholar 

  24. Walton KS, Abney MB, LeVan MD (2006) Microporous Mesoporous Mater 91:78

    Article  CAS  Google Scholar 

  25. Pulido A, Nachtigall P, Zukal A, Domínguez I, Čejka J (2009) J Phys Chem C 113:2928

    Article  CAS  Google Scholar 

  26. Zukal A, Pawlesa J, Čejka J (2009) Adsorption 15:264

    Article  CAS  Google Scholar 

  27. Himeno S, Komatsu T, Fujita S (2005) J Chem Eng Data 50:369

    Article  CAS  Google Scholar 

  28. Omi H, Ueda T, Miyakubo K, Eguchi T (2005) Appl Surf Sci 252:660

    Article  CAS  Google Scholar 

  29. Arenillas A, Smith KM, Drage TC, Snape CE (2005) Fuel 84:2204

    Article  CAS  Google Scholar 

  30. Larobina D, Sanguigno L, Venditto V, Guerra G, Mensitieri G (2004) Polymer 45:429

    Article  CAS  Google Scholar 

  31. Navarro JAR, Barea E, Salas JM, Masciocchi N, Galli S, Sironi A, Ania CO, Parra JB (2006) Inorg Chem 45:2397

    Article  CAS  Google Scholar 

  32. Thallapally PK, McGrail BP, Atwood JL, Gaeta C, Tedesco C, Neri P (2007) Chem Mater 19:3355

    Article  CAS  Google Scholar 

  33. Brandani F, Ruthven DM (2004) Ind Eng Chem Res 43:8339

    Article  CAS  Google Scholar 

  34. Li H, Eddaoudi M, Groy TL, Yaghi OM (1998) J Am Chem Soc 120:8571

    Article  CAS  Google Scholar 

  35. Walton KS, Millward AR, Dubbeldam D, Frost H, Low JJ, Yaghi OM, Snurr RQ (2008) J Am Chem Soc 130:406

    Article  CAS  Google Scholar 

  36. Serre C, Millange F, Thouvenot C, Nogues M, Marsolier G, Louer D, Férey G (2002) J Am Chem Soc 124:13519

    Article  CAS  Google Scholar 

  37. Serre C, Bourrelly S, Vimont A, Ramsahye NA, Maurin G, Llewellyn PL, Daturi M, Filinchuk Y, Leynaud O, Barnes P, Férey G (2007) Chem Mater 19:2246

    CAS  Google Scholar 

  38. Sozzani P, Bracco S, Comotti A, Ferretti L, Simonutti R (2005) Angew Chem Int Ed 44:1816

    Article  CAS  Google Scholar 

  39. Liu X, Li J, Zhou L, Huang D, Zhou Y (2005) Chem Phys Lett 415:198

    Article  CAS  Google Scholar 

  40. Khatri RA, Chuang SSC, Soong Y, Gray M (2005) Ind Eng Chem Res 44:3702

    Article  CAS  Google Scholar 

  41. Zheng F, Tran DN, Busche BJ, Fryxell GE, Addleman RS, Zemanian TS, Ardahl CL (2005) Ind Eng Chem Res 44:3099

    Article  CAS  Google Scholar 

  42. Macario A, Katovic A, Giordano G, Iucolano F, Caputo D (2005) Microporous Mesoporous Mater 81:139

    Article  CAS  Google Scholar 

  43. Xu X, Song CS, Andresen JM, Miller BG, Scaroni AW (2002) Energy Fuels 16:1463

    Article  CAS  Google Scholar 

  44. Xu X, Song CS, Andresen JM, Miller BG, Scaroni AW (2003) Microporous Mesoporous Mater 62:29

    Article  CAS  Google Scholar 

  45. Xu X, Song CS, Miller BG, Scaroni AW (2005) Fuel Proc Technol 86:1457

    Article  CAS  Google Scholar 

  46. Xu X, Song CS, Miller BG, Scaroni AW (2005) Ind Eng Chem Res 44:8113

    Article  CAS  Google Scholar 

  47. Zeleňák V, Badaničová M, Halamová D, Čejka J, Zukal A, Murafa N, Goerigk G (2008) Chem Eng J 144:336

    Article  CAS  Google Scholar 

  48. Kim S, Ida J, Guliants VV, Lin JYS (2005) J Phys Chem B 109:6287

    Article  CAS  Google Scholar 

  49. Knowles GP, Graham JC, Delaney SW, Chaffee AL (2005) Fuel Proc Technol 86:1435

    Article  CAS  Google Scholar 

  50. Knowles GP, Delaney SW, Chaffee AL (2006) Ind Eng Chem Res 45:2626

    Article  CAS  Google Scholar 

  51. Hiyoshi N, Yogo K, Yashima T (2005) Microporous Mesoporous Mater 84:357

    Article  CAS  Google Scholar 

  52. Liu X, Zhou L, Fu Z, Sun Y, Su W, Zhou Y (2007) Chem Eng Sci 62:1101

    Article  CAS  Google Scholar 

  53. Knöfel C, Descarpentries J, Benzaouia A, Zeleňák V, Mornet S, Llewellyn PL, Hornebecq V (2007) Microporous Mesoporous Mater 99:79

    Article  CAS  Google Scholar 

  54. Chang ACC, Chuang SSC, Gray M, Soong Y (2003) Energy Fuels 17:468

    Article  CAS  Google Scholar 

  55. Gray ML, Soong Y, Champagne KJ, Pennline HW, Baltrus J, Stevens RWJ, Khatri RA, Chuang SSC, Filburn T (2005) Fuel Proc Technol 86:1449

    Article  CAS  Google Scholar 

  56. Khatri RA, Chuang SSC, Soong Y, Gray M (2006) Energy Fuels 20:1514

    Article  CAS  Google Scholar 

  57. Yue MB, Chun Y, Cao Y, Dong X, Zhu JH (2006) Adv Funct Mater 16:1717

    Article  CAS  Google Scholar 

  58. Hicks JC, Drese JH, Fauth DJ, Gray ML, Qi G, Jones CW (2008) J Am Chem Soc 130:2902

    Article  CAS  Google Scholar 

  59. Franchi RS, Harlick PJE, Sayari A (2005) Ind Eng Chem Res 44:8007

    Article  CAS  Google Scholar 

  60. Reynhardt JPK, Yang Y, Sayari A, Alper H (2005) Adv Funct Mater 15:1641

    Article  CAS  Google Scholar 

  61. Harlick PJE, Sayari A (2006) Ind Eng Chem Res 45:3248

    Article  CAS  Google Scholar 

  62. Harlick PJE, Sayari A (2007) Ind Eng Chem Res 46:446

    Article  CAS  Google Scholar 

  63. Serna-Guerrero R, Da’na E, Sayari A (2008) Ind Eng Chem Res 47:9406

    Article  CAS  Google Scholar 

  64. Zhao D, Feng J, Huo Q, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD (1998) Science 279:548

    Article  CAS  Google Scholar 

  65. Lee J, Sohn K, Hyeon T (2001) J Am Chem Soc 123:5146

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The support of this work by the National Science Council, Taiwan (NSC95-2113-M-001-040-MY3) is gratefully acknowledged. The authors thank Drs. Shing-Jong Huang and Ningya Yu for helpful discussions.

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Author notes

  1. Shou-Heng Liu

    Present address: Department of Chemical and Materials Engineering, National Kaohsiung University of Applied Sciences, Kaohsiung, 80778, Taiwan

Authors and Affiliations

  1. Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei, 10617, Taiwan

    Shou-Heng Liu, Chia-Hua Wu & Shang-Bin Liu

  2. Institute of Materials Science and Nanotechnology, Chinese Culture University, Taipei, 11114, Taiwan

    Chia-Hua Wu & Huang-Kuei Lee

Authors
  1. Shou-Heng Liu
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  2. Chia-Hua Wu
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Correspondence to Shang-Bin Liu.

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Liu, SH., Wu, CH., Lee, HK. et al. Highly Stable Amine-modified Mesoporous Silica Materials for Efficient CO2 Capture. Top Catal 53, 210–217 (2010). https://doi.org/10.1007/s11244-009-9413-z

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  • DOI: https://doi.org/10.1007/s11244-009-9413-z

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