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Synthesis and characterization of dinuclear late transition-metal (copper(I), silver(I), rhenium(I)) complexes with a bis-pyridylimine ligand linked by S–S bonding

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Abstract

Two dinuclear complexes with novel coordination type, [Cu2(DPDIDT)2](PF6)2 (1) and [Ag2(DPDIDT)2](BF4)2 (2), plus a dinuclear complex of the usual coordination type, {Re(Cl)(CO)3}2(DPDIDT) (3) as a comparative complex were prepared from bis-(4-(2-pyridylmethyleneiminophenyl))disulfide (DPDIDT) and the relevant metal sources. Complexes (1) and (2) exist in solution as dimer structures of the square-pole type according to the interpretation of the ESI mass and 1H NMR spectra. The density functional theory calculations for the monomer and dimer models of the Cu(I) complex cations, [Cun(DPDIDT)n]n+ (n = 1, 2), demonstrated that the dimer form is structurally more stable than the monomer form. The UV–Vis absorption spectra of complexes (1) and (3) both exhibit a typical MLCT absorption band in the 400–700 nm region. The Re(I) complex (3) was revealed to possess a facial configuration with respect to the three carbonyl ligands by 1H NMR and IR data.

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Authors and Affiliations

  1. Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya, 466-8555, Aichi, Japan

    Michito Shiotsuka, Housei Koumura, Yasushi Suwaki, Masahiro Asai, Hitoshi Tatemitsu, Tomohiro Ozawa & Hideki Masuda

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  1. Michito Shiotsuka
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  2. Housei Koumura
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  3. Yasushi Suwaki
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  4. Masahiro Asai
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  5. Hitoshi Tatemitsu
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  6. Tomohiro Ozawa
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  7. Hideki Masuda
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Correspondence to Michito Shiotsuka.

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Shiotsuka, M., Koumura, H., Suwaki, Y. et al. Synthesis and characterization of dinuclear late transition-metal (copper(I), silver(I), rhenium(I)) complexes with a bis-pyridylimine ligand linked by S–S bonding. Transition Met Chem 34, 353–359 (2009). https://doi.org/10.1007/s11243-009-9202-3

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  • DOI: https://doi.org/10.1007/s11243-009-9202-3

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