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Synthesis, characterization, X-ray structural analysis and study of oxidative properties of propyltriphenylphosphonium bromochromate

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Abstract

The complex of propyltriphenylphosphonium bromochromate(VI), PrPh3P[CrO3Br] is easily synthesized in nearly quantitative yield using a direct reaction of chromium(VI) oxide and propyltriphenylphosphonium bromide. This compound is a versatile reagent for the efficient and selective oxidation of organic substrates, in particular for alcohols to their corresponding aldehydes or ketones, under mild conditions. This compound was characterized by IR, UV/Visible, 13C-n.m.r. and 1H-n.m.r. techniques. It crystallized in the monoclinic form and its crystal and molecular structure have been determined by X-ray crystallography.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Imam Khomeini International University, Ghazvin, Iran

    Shahriare Ghammamy & Monir Rahnama Baghy

  2. Department of Chemistry, The University of Hong Kong, Pokfulam Road, Pokfulam, Hong Kong SAR, P.R. China

    Wong Wing-Tak

  3. Department of Chemistry, Faculty of Science, Azad Islamic University, Ardebil Branch, Ardebil, Iran

    Kheiroallah Mehrani & Saied Maleki

Authors
  1. Shahriare Ghammamy
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  2. Monir Rahnama Baghy
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  3. Wong Wing-Tak
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  4. Kheiroallah Mehrani
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  5. Saied Maleki
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Correspondence to Shahriare Ghammamy.

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Ghammamy, S., Baghy, M.R., Wing-Tak, W. et al. Synthesis, characterization, X-ray structural analysis and study of oxidative properties of propyltriphenylphosphonium bromochromate. Transition Met Chem 32, 257–261 (2007). https://doi.org/10.1007/s11243-006-0162-6

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  • DOI: https://doi.org/10.1007/s11243-006-0162-6

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