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Effect of the Structure and Acidity of Micro-Mesoporous Alumosilicates on Their Catalytic Activity in Cumene Cracking

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Theoretical and Experimental Chemistry Aims and scope

Micro-mesoporous alumosilicates derived from zeolite ZSM-5 were obtained in dual template reaction media and in the presence of dual functional templates. It was shown that aluminosilicates with 0.15-0.25 zeolitization exhibit high catalytic activity in cumene cracking, approaching the activity of ZSM-5 and superior to ZSM-5 in total selectivity relative to the major products (propylene and benzene). Greater oligomerization of propylene is observed with increasing micropore volume and concentration of strong acid sites in the alumosilicates along with increased cumene conversion.

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Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, Kyiv, 03028, Ukraine

    R. Yu. Barakov, N. D. Shcherban, P. S. Yaremov, V. V. Tsyrina & V. G. Ilyin

  2. Institute of Bioorganic Chemistry and Petrochemistry, National Academy of Sciences of Ukraine, Vul. Murmans’ka, 1, Kyiv, 02660, Ukraine

    Yu. G. Voloshyna & M. M. Krylova

Authors
  1. R. Yu. Barakov
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  2. N. D. Shcherban
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  3. P. S. Yaremov
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  4. Yu. G. Voloshyna
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  5. M. M. Krylova
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  6. V. V. Tsyrina
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  7. V. G. Ilyin
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Correspondence to R. Yu. Barakov.

Additional information

V. G. Ilyin is deceased.

Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 52, No. 4, pp. 213-221, July-August, 2016.

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Barakov, R.Y., Shcherban, N.D., Yaremov, P.S. et al. Effect of the Structure and Acidity of Micro-Mesoporous Alumosilicates on Their Catalytic Activity in Cumene Cracking. Theor Exp Chem 52, 212–220 (2016). https://doi.org/10.1007/s11237-016-9470-x

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  • DOI: https://doi.org/10.1007/s11237-016-9470-x

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