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Molecular tectonics: silver coordination networks based on tetramercaptothiacalix[4]arene in 1,3-alternate conformation bearing four nitrile groups

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Abstract

Two tetrasubsituted derivatives of tetramercaptothiacalix[4]arene in 1,3-alternate conformation bearing either four (3-cyano)propyl (1) or (4-cyano)benzyl (2) moieties have been synthesized and characterized in solution as well as in the solid state by X-ray diffraction on single crystals. Their propensity to form coordination networks was investigated in the presence of silver cation as connecting metal and hexafluorophosphate as counter ion. Whereas the combination of AgPF6 and 1 bearing four (3-cyano)propyl groups leads to a 1D silver coordination network, for 2, containing four (4-cyano)benzyl units, a 3D diamond-like architecture is obtained.

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Correspondence to I. S. Antipin.

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Based on the materials of the XXVI International Chugaev Conference on Coordination Chemistry (October 6—10, 2014, Kazan).

Université de Strasbourg, Laboratoire de Tectonique Moléculaire, UMR-CNRS 7140, Institut Le Bel, 4 rue Blaise Pascal, 67070 Strasbourg, France.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1955—1962, August, 2015.

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Ovsyannikov, A.S., Ferlay, S., Solovieva, S.E. et al. Molecular tectonics: silver coordination networks based on tetramercaptothiacalix[4]arene in 1,3-alternate conformation bearing four nitrile groups. Russ Chem Bull 64, 1955–1962 (2015). https://doi.org/10.1007/s11172-015-1099-8

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  • DOI: https://doi.org/10.1007/s11172-015-1099-8

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