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Base-induced rearrangement of 4-amidino-3-R-furoxans into 1-substituted 3-(1-nitroalkyl)-5-R-1H-1,2,4-triazoles

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Abstract

A new base-induced rearrangement of furoxans, viz., a recyclization of 4-amidino-3-Rfuroxans into 1-substituted 3-(1-nitroalkyl)-5-R-1H-1,2,4-triazoles in the presence of alkali metal alkoxides and into 3-acyl-5-R-1H-1,2,4-triazoles in aqueous alkaline solutions, was found.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    S. I. Molotov, A. S. Kulikov & N. N. Makhova

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    K. A. Lyssenko

Authors
  1. S. I. Molotov
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  2. A. S. Kulikov
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  3. K. A. Lyssenko
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  4. N. N. Makhova
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Correspondence to N. N. Makhova.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1238–1243, May, 2013.

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Molotov, S.I., Kulikov, A.S., Lyssenko, K.A. et al. Base-induced rearrangement of 4-amidino-3-R-furoxans into 1-substituted 3-(1-nitroalkyl)-5-R-1H-1,2,4-triazoles. Russ Chem Bull 62, 1238–1243 (2013). https://doi.org/10.1007/s11172-013-0170-6

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  • DOI: https://doi.org/10.1007/s11172-013-0170-6

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