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Proton conductivity of calix[n]arene-para-sulfonic acids (n = 4, 8)

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Abstract

High proton conductivity in calix[n]arene-para-sulfonic acid hydrates (n = 4, 8) reaching a value of 10−1 Ohm−1 cm−1 at a relative humidity of 80% was revealed for the first time. This value is close to the record conductivity of solid proton conductors and acid water solutions. The dependence of proton transfer parameters and water quantity in the title compounds dependent on the relative humidity of air was investigated.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    A. V. Pisareva, R. V. Pisarev, A. I. Karelin, L. V. Shmygleva, Yu. A. Dobrovolsky & S. M. Aldoshin

  2. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Centre, Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    I. S. Antipin, A. I. Konovalov & S. E. Solovieva

Authors
  1. A. V. Pisareva
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  2. R. V. Pisarev
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  3. A. I. Karelin
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  4. L. V. Shmygleva
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  5. I. S. Antipin
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  6. A. I. Konovalov
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  7. S. E. Solovieva
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  8. Yu. A. Dobrovolsky
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  9. S. M. Aldoshin
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Correspondence to A. V. Pisareva.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1877–1884, October, 2012.

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Pisareva, A.V., Pisarev, R.V., Karelin, A.I. et al. Proton conductivity of calix[n]arene-para-sulfonic acids (n = 4, 8). Russ Chem Bull 61, 1892–1899 (2012). https://doi.org/10.1007/s11172-012-0263-7

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  • DOI: https://doi.org/10.1007/s11172-012-0263-7

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