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Synthesis and properties of ZnII and CdII complexes with chiral N-derivatives of aminoacetic acid based on natural monoterpenes (+)-3-carene and (−)-α-pinene. Crystal structure of coordination polymer [Zn(HL)Cl·2H2O] n

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Abstract

Chiral sodium salts of N-derivatives of aminoacetic acid based on (+)-3-carene (HLNa) and (−)-α-pinene (HLNa) were synthesized. Complexes Zn(HL)Cl (1), Cd(HL)Cl·0.5H2O (3), Zn(HL′)Cl·0.5H2O (4), and Cd(HL′)Cl·0.5H2O (5) were obtained. The single crystals of the coordination polymer [Zn(HL)Cl·2H2O] n (2) were grown. According to the X-ray diffraction analysis, the crystal structure of 2 consists of 1D chains built of Zn(HL)Cl and water molecules. The coordination polyhedron ClN2O2 is a distorted square pyramid. The HL− ligand performs the chelating tetradentate-bridging function, and the COO− group binds two adjacent Zn atoms. The IR spectroscopy data for compounds 1 and 3–5 indicate the coordination of the COO−, NOH, and NH functional groups. The excitation and photoluminescence (PLM) spectra of the solid samples of compounds HLNa, HL’Na, 1, and 3–5 were recorded at room temperature. The compounds exhibit blue PLM. The intensity of PLM of the CdII complexes is higher than that of the ZnII complexes, which is a characteristic feature of PLM of the studied compounds.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentéva, 630090, Novosibirsk, Russia Federation

    S. V. Larionov, T. E. Kokina, L. A. Glinskaya, I. V. Korol’kov, M. I. Rakhmanova, E. M. Uskov & P. E. Plyusnin

  2. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russia Federation

    T. E. Kokina, P. E. Plyusnin & A. V. Tkachev

  3. N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrentéva, 630090, Novosibirsk, Russia Federation

    A. M. Agafontsev, K. S. Marenin & A. V. Tkachev

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  1. S. V. Larionov
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  2. T. E. Kokina
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  3. A. M. Agafontsev
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  4. K. S. Marenin
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  5. L. A. Glinskaya
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  6. I. V. Korol’kov
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  7. M. I. Rakhmanova
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  8. E. M. Uskov
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  9. P. E. Plyusnin
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  10. A. V. Tkachev
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Corresponding author

Correspondence to T. E. Kokina.

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Dedicated to Academician of the Russian Academy of Sciences R. Z. Sagdeev on the occasion of his 70th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2506–2513,December, 2011.

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Larionov, S.V., Kokina, T.E., Agafontsev, A.M. et al. Synthesis and properties of ZnII and CdII complexes with chiral N-derivatives of aminoacetic acid based on natural monoterpenes (+)-3-carene and (−)-α-pinene. Crystal structure of coordination polymer [Zn(HL)Cl·2H2O] n . Russ Chem Bull 60, 2555–2563 (2011). https://doi.org/10.1007/s11172-011-0393-3

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  • DOI: https://doi.org/10.1007/s11172-011-0393-3

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