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Catalytic properties of the macromolecular polyoxomolybdate cluster in selective oxidation of sulfides

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Abstract

The catalytic properties of the iron-containing Keplerate [H4Mo72Fe30O254(CH3COO)10-Mo2O7(H2O)H2Mo2O8(H2O)3(H2O)87] • (~80)H2O (1) in the selective liquid-phase oxidation of thio ethers were studied. Compound 1 shows high catalytic activity and selectivity in the oxidation of organic sulfides to sulfoxides when hydrogen peroxide and tert-butyl hydroperoxide are used as oxidants.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentreva, 630090, Novosibirsk, Russian Federation

    N. V. Izarova, M. N. Sokolov & V. P. Fedin

  2. G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 prosp. Akad. Lavrentreva, 630090, Novosibirsk, Russian Federation

    O. A. Kholdeeva

  3. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    M. N. Sokolov & V. P. Fedin

Authors
  1. N. V. Izarova
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  2. O. A. Kholdeeva
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  3. M. N. Sokolov
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  4. V. P. Fedin
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Correspondence to N. V. Izarova.

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Dedicated to Academician A. I. Konovalov on his 75th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 134–137, January, 2009.

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Izarova, N.V., Kholdeeva, O.A., Sokolov, M.N. et al. Catalytic properties of the macromolecular polyoxomolybdate cluster in selective oxidation of sulfides. Russ Chem Bull 58, 134–137 (2009). https://doi.org/10.1007/s11172-009-0020-8

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  • DOI: https://doi.org/10.1007/s11172-009-0020-8

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