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Self-assembly of nanosized aggregates based on the photoswitchable p-tert-butyl thiacalix[4]arene derivative and Fe III, CuII, and AgI cations

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Abstract

New p-tert-butyl thiacalix[4]arene tetrasubstituted at the lower rim and containing the azobenzene fragments in the 1,3-alternate configuration was synthesized. Its receptor properties with respect to d-metal cations (Fe 3+, Cu2+, Ag+) were studied using UV spectroscopy and dynamic light scattering (DLS). The ability of p-tert-butyl thiacalix[4]arene to molecular recognition of silver cations was estimated by UV spectroscopy. The aggregation of these systems was studied by the dynamic light scattering method.

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Correspondence to I. I. Stoikov.

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Dedicated to Academician A. I. Konovalov on his 75th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 101–107, January, 2009.

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Yushkova, E.A., Zaikov, E.N., Stoikov, I.I. et al. Self-assembly of nanosized aggregates based on the photoswitchable p-tert-butyl thiacalix[4]arene derivative and Fe III, CuII, and AgI cations. Russ Chem Bull 58, 101–107 (2009). https://doi.org/10.1007/s11172-009-0015-5

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  • DOI: https://doi.org/10.1007/s11172-009-0015-5

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