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Synthesis and spatial structure of novel organosilicon derivatives of p-tert-butylthiacalix[4]arene from two-dimensional NMR data

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Abstract

New organosilicon derivatives of p-tert-butylthiacalix[4]arene with one or two ring fragments at the macrocycle lower rim were synthesized. The spatial structures of the resulting compounds were established by two-dimensional NMR spectroscopy. On going from the methyl substituents at the silicon atom to phenyl substituents, closure of the second silicon-containing ring is hampered because of steric hindrance in the reaction site.

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Authors and Affiliations

  1. Kazan State University, 18 ul. Kremlevskaya, 420008, Kazan, Russian Federation

    I. I. Stoikov, O. A. Mostovaya, I. S. Antipin & A. I. Konovalov

  2. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    I. S. Antipin & A. I. Konovalov

  3. Institute of Organic Chemistry, Dresden Technical University, 13 Mommsenstrasse, D-01062, Dresden, Germany

    M. Grüner & W. D. Habicher

Authors
  1. I. I. Stoikov
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  2. O. A. Mostovaya
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  3. I. S. Antipin
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  4. A. I. Konovalov
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  5. M. Grüner
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  6. W. D. Habicher
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Corresponding author

Correspondence to I. I. Stoikov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 297–302, February, 2007.

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Stoikov, I.I., Mostovaya, O.A., Antipin, I.S. et al. Synthesis and spatial structure of novel organosilicon derivatives of p-tert-butylthiacalix[4]arene from two-dimensional NMR data. Russ Chem Bull 56, 307–312 (2007). https://doi.org/10.1007/s11172-007-0050-z

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  • DOI: https://doi.org/10.1007/s11172-007-0050-z

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