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A novel, ecofriendly 1H-1,2,4-triazole-3-thiol-functionalized Fe3O4@SiO2 magnetic nano-catalyst for the synthesis of 2H-indazolo[2,1-b] phthalazine-trione and triazolo[1,2-a]indazole-trione derivatives

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Abstract

The synthesis of 2H-indazolo[2,1-b] phthalazine-triones and triazolo[1,2-a]indazole-triones catalyzed by 1H-1,2,4-triazole-3-thiol-functionalized core–shell Fe3O4@SiO2 magnetic nanocomposite in one-pot three-component reactions under solvent-free conditions is introduced. The catalyst was fabricated through a four-step protocol and was characterized by different techniques. The catalytic activity of nano-catalyst to generate some products was assessed. The excellent yields for all products were obtained when 15 mg of the as-prepared magnetic nanocomposite was utilized in one-pot solvent-free three-component reactions at 100 °C. The investigation of the reusability of the catalyst showed the stability of 92% after five runs. The simplicity of use and easy separation are the additional advantages of the proposed procedure.

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Acknowledgements

We acknowledge the research council of Yasouj University.

Funding

This research work received partial support from Yasouj University.

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Authors and Affiliations

  1. Department of Chemistry, Yasouj University, PO Box 353, Yasouj, Iran

    Mehrdad Cheraghi, Bahador Karami & Mahnaz Farahi

  2. Department of Applied Chemistry, Faculty of Gas and Petroleum, Yasouj University, Gachsaran, Iran

    Mosadegh Keshavarz

Authors
  1. Mehrdad Cheraghi
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  2. Bahador Karami
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  3. Mahnaz Farahi
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  4. Mosadegh Keshavarz
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Contributions

All authors contributed to the study conception and design. Experimental was completed by MC; data analysis was performed by Mahnaz Farahi; study design was performed by MK; and the manuscript was written by Bahador Karami. All authors read and approved the final manuscript.

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Correspondence to Bahador Karami.

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Cheraghi, M., Karami, B., Farahi, M. et al. A novel, ecofriendly 1H-1,2,4-triazole-3-thiol-functionalized Fe3O4@SiO2 magnetic nano-catalyst for the synthesis of 2H-indazolo[2,1-b] phthalazine-trione and triazolo[1,2-a]indazole-trione derivatives. Res Chem Intermed 49, 1941–1958 (2023). https://doi.org/10.1007/s11164-023-04966-z

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