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Oscillatory carbonylation of poly(ethylene glycol)methyl ether acetylene. Improved model of reaction mechanism

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Abstract

The study presents a mathematical model of Bruk Temkin-Gorodsky Novakovic (BT-GN) reaction system employing palladium-catalyzed oscillatory carbonylation reaction of mono alkyne-terminated poly(ethylene glycol) methyl ether. The proposed model advances simulation capabilities of this particular chemical oscillator but also BT-GN reactions in general. The model was verified using experimental data where good agreement is achieved and existence of complex pH oscillations like burst oscillations was matched. Furthermore, the model was used to predict reaction conditions capable of producing further complexities and initial conditions that would lead to desired period of pH oscillations. Having such a powerful tool, enhances our capabilities to study and further develop BT-GN oscillators with a reduced experimental effort.

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References

  1. Bray WC (1921) J Am Chem Soc 43:1262–1267

    Article  CAS  Google Scholar 

  2. Bray WC, Liebhafsky HA (1931) J Am Chem Soc 53:38–44

    Article  CAS  Google Scholar 

  3. Furrow SD (1985) Oscillations and traveling waves in chemical systems. Wiley, New York

    Google Scholar 

  4. Kolar-Anić Lj, Anić S, Čupić Ž, Ivanović-Šašić A, Pejić N, Blagojević Sl, Vukojević V (2017) Chapter 23 oscillating reactions in encyclopedia of physical organic chemistry, vol 6. Wiley, New York

    Google Scholar 

  5. Lj K-A, Čupić Ž, Vukojević V, Anić S (2011) Dynamics of nonlinear processes. University of Belgrade, Belgrade

    Google Scholar 

  6. Belousov BP (1958) Sbornik Referatov po Radiatsionnoi Meditsine. Moskow, Medigz, p 145

    Google Scholar 

  7. Zhabotinskii AM (1974) Koncentrationnye avtokolebaniya. Nauka, Moskva

    Google Scholar 

  8. Briggs TS, Rauscher W (1973) J Chem Educ 50:496–496

    Article  CAS  Google Scholar 

  9. Malashkevich V, Bruk LG, Temkin ON (1997) J Phys Chem A 101:9825–9827

    Article  CAS  Google Scholar 

  10. Gorodskii SN, Zakharov AN, Kulik AV, Bruk LG, Temkin ON (2001) Kinet Katal 42(2):280–293

    Article  Google Scholar 

  11. Novakovic K, Grosjean C, Scott SK, Whiting A, Willis MJ, Wright AR (2007) Chem Phys Lett 435(1–3):142–147

    Article  CAS  Google Scholar 

  12. Donlon L, Parker J, Novakovic K (2014) React Kinet Mech Cat 112(1):1–13

    Article  CAS  Google Scholar 

  13. Parker J, Novakovic K (2016) React Kinet Mech Cat 118(1):73–85

    Article  CAS  Google Scholar 

  14. Parker J, Novakovic K (2017) Chem Phys Chem 18(15):1981–1986

    Article  CAS  Google Scholar 

  15. Yoshida BR, Takahashi T, Yamaguchi T, Ichijo H (2004) Adv Mater 9:175–178

    Article  Google Scholar 

  16. Donlon L, Novakovic K (2014) Chem Comm 50(98):15506–15508

    Article  CAS  Google Scholar 

  17. Isakova A, Parkes GE, Murdoch BJ, Topham PD, Novakovic K (2018) Eur Polym J 109:537–543

    Article  CAS  Google Scholar 

  18. Isakova A, Novakovic K (2018) J Mater Chem B 6:5003–5010

    Article  Google Scholar 

  19. Isakova A, Parker J, Nwosu CJ, Howse JR, Novakovic K (2019) React Kinet Mech Cat 127(1):161–174

    Article  CAS  Google Scholar 

  20. Grosjean C, Novakovic K, Scott SK, Whiting A, Willis MJ, Wright AR (2008) J Mol Catal A 284(1–2):33–39

    Article  CAS  Google Scholar 

  21. Novakovic K, Grosjean C, Scott SK, Whiting A, Willis MJ, Wright AR (2008) Phys Chem Chem Phys 10(5):749–753

    Article  CAS  Google Scholar 

  22. Novakovic K, Mukherjee A, Willis M, Wright A, Scott S (2009) Phys Chem Chem Phys 11(40):9044–9049

    Article  CAS  Google Scholar 

  23. Isakova A, Novakovic K (2017) Eur Polym J 95:430–439

    Article  CAS  Google Scholar 

  24. Novakovic K, Bruk L, Temkin O (2021) RSC Adv 11:24336–24344

    Article  CAS  Google Scholar 

  25. Čupić Ž, Maćešić S, Novakovic K, Anić S, Kolar-Anić L (2018) Chaos 28(8):083114

    Article  Google Scholar 

  26. Maćešić S, Čupić Ž, Novaković K, Parker J, Anić S, Kolar-Anić Lj (2019) MATCH Commun Math Comput Chem 81:5–34

    Google Scholar 

  27. Nwosu CJ (2019) Mono and bi-alkyne functionalised polyethylene glycols: polymeric substrates in palladium catalysed oscillatory carbonylation reactions, Thesis

  28. Porras S, Kenndler E (2004) Chromatogr A 1037(1–2):455–465

    Article  CAS  Google Scholar 

  29. Novaković K, Parker J (2011). Int J Chem Eng. https://doi.org/10.1155/2011/518592

    Article  Google Scholar 

  30. Kuznetsov YA (2013) Elements of applied bifurcation theory, vol 112. Springer, Berlin

    Google Scholar 

  31. Isakova A, Murdoch BJ, Novakovic K (2018) Phys Chem Chem Phys 20:9281–9288

    Article  CAS  Google Scholar 

Download references

Acknowledgements

KN would like to acknowledge UK Engineering and Physical Sciences Research Council (EPSRC) grant number EP/N033655/1 for financial support. Support from the Ministry of Education, Science and Technological Development of the Republic of Serbia (Grant Numbers 172015 and 45001, and Contract numbers 451-03-9/2021-14/200026 and 451-03-9/2021-14/200146), is gratefully acknowledged by ŽČ, SM, SA, LjKA and AIŠ.

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Authors and Affiliations

  1. University of Belgrade, Institute of Chemistry, Technology and Metallurgy, Belgrade, Serbia

    Željko Čupić & Ana Ivanović-Šašić

  2. University of Belgrade, Faculty of Physical Chemistry, Belgrade, Serbia

    Stevan Maćešić, Slobodan Anić & Ljiljana Kolar-Anić

  3. School of Engineering, Newcastle University, Newcastle upon Tyne, UK

    Katarina Novakovic

Authors
  1. Željko Čupić
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  2. Stevan Maćešić
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  3. Slobodan Anić
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  4. Ljiljana Kolar-Anić
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  5. Ana Ivanović-Šašić
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  6. Katarina Novakovic
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Correspondence to Željko Čupić.

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Čupić, Ž., Maćešić, S., Anić, S. et al. Oscillatory carbonylation of poly(ethylene glycol)methyl ether acetylene. Improved model of reaction mechanism. Reac Kinet Mech Cat 135, 3–14 (2022). https://doi.org/10.1007/s11144-021-02148-9

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  • DOI: https://doi.org/10.1007/s11144-021-02148-9

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