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Green synthesis of bis pyrazole-triazole and azo-linked triazole hybrids using an efficient and novel cobalt nanocatalyst

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Abstract

In the current work, new cobalt incorporated fluorapatite encapsulated iron oxide nanocatalyst (γ-Fe2O3@FAp@Co) was prepared and characterized by using FT-IR, XRD, SEM, TEM, VSM, and EDX techniques. The catalyst was utilized in the synthesis of novel derivatives of symmetric bis-triazoles by the reaction of various aldehydes and butane-1,4-diyl bis(hydrazinecarbimidothioate) in ethanol at room temperature. γ-Fe2O3@FAp@Co was easily removed from the reaction mixture using an external magnet and was used several times without decreased catalytic properties. This method provided a novel approach for the green synthesis of bis-triazoles in excellent yield (88–95%) and reasonable reaction time (60–80 min). The structures of prepared compounds were confirmed by analytical methods.

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Acknowledgements

Partial financial support of the Research Council of University of Guilan for this research work is sincerely acknowledged.

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  1. Department of Chemistry, Faculty of Sciences, University of Guilan, P.O. Box 41335-1914, Rasht, Iran

    Iman Rezaei & Manouchehr Mamaghani

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  1. Iman Rezaei
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Rezaei, I., Mamaghani, M. Green synthesis of bis pyrazole-triazole and azo-linked triazole hybrids using an efficient and novel cobalt nanocatalyst. Reac Kinet Mech Cat 134, 385–400 (2021). https://doi.org/10.1007/s11144-021-02076-8

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