Skip to main content
SpringerLink
Log in

Ketonization kinetics of stearic acid

  • Published:
Reaction Kinetics, Mechanisms and Catalysis Aims and scope Submit manuscript

Abstract

The ketonization of stearic acid was investigated in a stainless steel reactor under catalyst-free conditions. The reaction was selective towards formation of 18-pentatriacontanone following quasi-zero kinetics. A reaction mechanism explaining such behavior is discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Srivastava A, Prasad R (2000) Renew Sust Energy Rev 4:111–133

    Article  CAS  Google Scholar 

  2. Bozell JJ, Petersen GR (2010) Green Chem 12:539–554

    Article  CAS  Google Scholar 

  3. Alonso DM, Bond JQ, Dumesic JA (2010) Green Chem 12:1493–1513

    Article  CAS  Google Scholar 

  4. Murzin DYu, Simakova IL (2013) In: Schlögl R, Niemantsverdriet JW (eds) Comprehensive inorganic chemistry II. From elements to applications, vol 7. Elsevier, Amsterdam, pp 559–586

    Chapter  Google Scholar 

  5. Corma A, Iborra S, Velty A (2007) Chem Rev 107:2411–2502

    Article  CAS  PubMed  Google Scholar 

  6. Murzin DYu, Mäki-Arvela P, Simakova IL (2012) Kirk-Othmer encyclopedia of chemical technology. Wiley, New York. https://doi.org/10.1002/0471238961.trigmurz.a01

    Article  Google Scholar 

  7. Simakova IL, Murzin DYu (2016) J Energy Chem 25:208–224

    Article  Google Scholar 

  8. Kupareva A, Mäki-Arvela P, Murzin DYu (2013) J Chem Technol Biotechnol 88:1780–1793

    Article  CAS  Google Scholar 

  9. Murzin DYu (2018) Chemical product technology. DeGruyter, Berlin

    Book  Google Scholar 

  10. IG Farben (1939) Patent GB 506678 19390602

  11. Curtis RG, Dobson AG, Hatt HH (1947) J Soc Chem Ind Trans Commun 66:402–407

    Article  CAS  Google Scholar 

  12. Corma A, Renz M, Schaverien C (2008) ChemSusChem 1:739–741

    Article  CAS  PubMed  Google Scholar 

  13. Oliver-Tomas B, Renz M, Corma A (2017) Ind Eng Chem Res 56:12870–12877

    Article  CAS  Google Scholar 

  14. Back O, Leroy R, Marion P (2018) PCT international applications WO 2018087181 A1 20180517

  15. Renz M (2005) Eur J Org Chem 2005:979–988

    Article  CAS  Google Scholar 

  16. Pham TN, Sooknoi T, Crossley SP, Resasco DE (2013) ACS Catal 3:2456–2473

    Article  CAS  Google Scholar 

  17. Pham TN, Shi D, Resasco DE (2014) Top Catal 57:706–714

    Article  CAS  Google Scholar 

  18. Pham TN, Shi D, Resasco DE (2014) J Catal 314:149–158

    Article  CAS  Google Scholar 

  19. Gaertner CA, Serrano-Ruiz JC, Braden DJ, Dumesic JA (2010) Ind Eng Chem Res 49:6027–6033

    Article  CAS  Google Scholar 

  20. Murzin DYu, Salmi T (2016) Catalytic kinetics. Elsevier, Amsterdam

    Google Scholar 

  21. Haario H (2001) Modest 6.0—a user’s guide. ProfMath, Helsinki

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Johan Gadolin Process Chemistry Centre, Åbo Akademi University, 20500, Åbo/Turku, Finland

    Dmitry Yu. Murzin, Andreas Bernas, Johan Wärnå & Tapio Salmi

  2. Neste Corp, Porvoo, Finland

    Jukka Myllyoja

Authors
  1. Dmitry Yu. Murzin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Andreas Bernas
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Johan Wärnå
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jukka Myllyoja
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Tapio Salmi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Dmitry Yu. Murzin.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Murzin, D.Y., Bernas, A., Wärnå, J. et al. Ketonization kinetics of stearic acid. Reac Kinet Mech Cat 126, 601–610 (2019). https://doi.org/10.1007/s11144-018-1472-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11144-018-1472-3

Keywords

Search

Navigation