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Synthesis of 4H-benzo[b]pyrans in the presence of sulfated MCM-41 nanoparticles as efficient and reusable solid acid catalyst

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Abstract

A one-pot three-component reaction of various types of aldehydes, dimedone, and malononitrile was studied in the presence of sulfated MCM-41 (SO4 2−/MCM-41) nanoparticles for the synthesis of 4H-benzo[b]pyrans. MCM-41 was synthesized in nanosize by the sol–gel method and then SO4 2−/MCM-41 samples with different calcination temperatures were prepared and characterized by XRD, FT-IR, SEM, and BET techniques. The characterization results show the insertion of sulfate in the mesoporous structure of MCM-41 and the catalytic performance experiments show that SO4 2−/MCM-41 with a calcination temperature of 550 °C has the best catalytic activity. The reusability experiments show that the catalyst is reusable with moderate decrease in activity.

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Authors and Affiliations

  1. Department of Chemistry, Yazd University, 89195-741, Yazd, Iran

    Mohammad Abdollahi-Alibeik & Fahime Nezampour

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  1. Mohammad Abdollahi-Alibeik
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  2. Fahime Nezampour
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Correspondence to Mohammad Abdollahi-Alibeik.

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Abdollahi-Alibeik, M., Nezampour, F. Synthesis of 4H-benzo[b]pyrans in the presence of sulfated MCM-41 nanoparticles as efficient and reusable solid acid catalyst. Reac Kinet Mech Cat 108, 213–229 (2013). https://doi.org/10.1007/s11144-012-0504-7

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  • DOI: https://doi.org/10.1007/s11144-012-0504-7

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