Skip to main content
SpringerLink
Log in

The Effect of Implanted Al and/or Y on the Scale Formation on Low-Al Fe20Cr2Al Alloy

  • Original Paper
  • Published:
Oxidation of Metals Aims and scope Submit manuscript

Abstract

The very early stages of the oxidation of an Fe20Cr2Al alloy, unmodified and ion-implanted by aluminium, yttrium and a combination of both elements, Al and Y, were studied at 1100 °C in oxygen using two-stage-oxidation exposures with 18O2 as a tracer and subsequent characterisation of the scales using SIMS analyses of distribution of oxygen isotopes and oxide-related negative ion clusters, SEM observations of the surface morphology and photoluminescence spectroscopy analysis of the phase composition. The scales formed in all cases, except for the Al-implanted alloy, exhibited layered structures, with the outer part comprising Fe- and Cr-rich oxide, and the inner part being Al2O3, which grew due to a mixed outward–inward mechanism . The alumina sub-layers contained the transient oxides and α-Al2O3. Implanted Al significantly affected the mechanism of the scale growth, providing that the scale consisted essentially of α-Al2O3, and grew via a mixed inward-outward mechanism typical for scales on alumina formers.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. M. Schütze, W. J, Quadakkers, J. R. Nicholls, Lifetime Modelling of High Temperature Corrosion Processes, European Federation of Corrosion Monograph, Nr. 34, (Maney Publishing, London, 2001).

  2. M. J. Bennett, J. R. Nicholls, N. J. Simms, D. Naumenko, W. J. Quadakkers, V. Kochubey, R. Fordham, R. Bachorczyk, D. Goossens, H. Hattendorf, A. B. Smith and D. Britton, Materials and Corrosion 56, 854 (2005).

    Article  Google Scholar 

  3. J. Jedlinski, A. Nikiel, G. Borchardt and B. Rajchel, Materials Science Forum 163–165, 449 (1994).

    Article  Google Scholar 

  4. F. H. Stott, G. C. Wood and J. Stringer, Oxidation of Metals 44, 113 (1995).

    Article  Google Scholar 

  5. J.-M. Herbelin and M. Mantel, Journal de Physique IV Colloque 05, (C7), 365 (1995).

    Google Scholar 

  6. J. Jedlinski, G. Borchardt, B. Rajchel and M. Nocun, Materials Science Forum 461–464, 513 (2004).

    Article  Google Scholar 

  7. C. C. Tsaur, High Temperature Oxidation and NaCl-Induced Accelerated Corrosion of Hot-Dip Aluminized 9Cr-1Mo and 310 stainless steel, Ph.D. Thesis, Texas Agriculture and Mechanical University, College Station, 2004.

  8. H. Josefsson, F. Liu, J. E. Svensson, M. Halvarsson and L. G. Johansson, Materials and Corrosion 56, 801 (2005).

    Article  Google Scholar 

  9. M. F. Pillis and L. V. Ramanathan, Surface Engineering 2006, (22), 129 (2006).

    Article  Google Scholar 

  10. J. Engkvist, U. Bexell, M. Grehk and M. Olsson, Materials and Corrosion 60, 876 (2009).

    Article  Google Scholar 

  11. M. H. Bin Ani, T. Kodama, M. Ueda, K. Kawamura and T. Maruyama, Materials Transactions 50, 2656 (2009).

    Article  Google Scholar 

  12. M. P. Brady, P. F. Tortorelli, K. L. More and L. R. Walker, Oxidation of Metals 74, 1 (2010).

    Article  Google Scholar 

  13. N. Israelsson, High Temperature Oxidation and Chlorination of FeCrAl Alloys, Ph.D. Thesis, Chalmers University of Technology, Göteborg, Sweden, 2014.

  14. B. A. Pint, K. A. Unocic and K. A. Terrani, Materials at High Temperatures 32, 28 (2015 ).

    Article  Google Scholar 

  15. C. Wagner, Corrosion Science 5, 751 (1965).

    Article  Google Scholar 

  16. D. J. Young, High Temperature Oxidation and Corrosion of Metals, (Elsevier, Amsterdam, 2008), pp. 338–341.

    Google Scholar 

  17. J. Lindhard, M. Scharff and H. Schiott, Matematisk-fysiske Meddelelser udgivet af Det Kongelige Danske Videnskabernes Selskab 33, 1 (1963).

    Google Scholar 

  18. W. J. Quadakkers, J. Jedlinski, K. Schmidt, M. Krasovec, G. Borchardt and H. Nickel, Applied Surface Science 47, 261 (1991).

    Article  Google Scholar 

  19. J. Jedlinski, Oxidation of Metals 39, 61 (1993 ).

    Article  Google Scholar 

  20. J. Jedlinski, A. Bernasik, K. Kowalski and M. Nocun, Materials at High Temperatures 12, 505 (2005).

    Article  Google Scholar 

  21. D. M. Lipkin and D. R. Clarke, Oxidation of Metals 45, 267 (1996).

    Article  Google Scholar 

  22. S. N. Basu and J. W. Halloran, Oxidation of Metals 27, 147 (1987).

    Article  Google Scholar 

  23. V. R. Deline, W. Katz, C. A. Evans Jr. and P. Williams, Applied Physics Letters 33, 832 (1978).

    Article  Google Scholar 

  24. J. Jedliński, J.-L. Grosseau-Poussard, K. Kowalski, J. Dąbek and G. Borchardt, Oxidation of Metals 79, 41 (2013).

    Article  Google Scholar 

  25. A. M. Ben Abderrazik, G. Moulin, A. M. Huntz, E. W. A. Young and J. H. W. de Wit, Soli State Ionics 22, 285 (1987).

    Article  Google Scholar 

  26. V. K. Tolpygo and D. R. Clarke, Materials at High Temperatures 20, 261 (2003).

    Article  Google Scholar 

  27. J. Jedlinski, Defect and Diffusion Forum 289–292, 385 (2009).

    Article  Google Scholar 

  28. D. R. Clarke, Acta Materialia 51, 1393 (2003).

    Article  Google Scholar 

  29. D. P. Whittle and J. Stringer, Philosophical Transactions of the Royal Society of London A 295, 309 (1980).

    Article  Google Scholar 

  30. J. Jedlinski, Solid State Phenomena 21, 22, 335 (1992).

    Article  Google Scholar 

  31. S. Chevalier, Materials and Corrosion 65, 109 (2014).

    Article  Google Scholar 

  32. K. D. Vernon-Parry, C. R. M. Grovenor, N. Needham and T. English, Materials Science and Technology 4, 461 (1988).

    Article  Google Scholar 

  33. R. Cueff, C. T. Nguyen, H. Buscail, E. Caudron, C. Issartel and F. Riffard, Materials Science Forum 595–598, 933 (2008).

    Article  Google Scholar 

  34. J. Jedlinski, Oxidation of Metals 39, 61 (1993).

    Article  Google Scholar 

  35. J. Jedlinski, Materials Science Forum 595–598, 995 (2008).

    Article  Google Scholar 

  36. S. Hayashi and B. Gleeson, Oxidation of Metals 71, 5 (2009).

    Article  Google Scholar 

  37. S. Hayashi and B. Gleeson, Oxidation of Metals 77, 237 (2012).

    Article  Google Scholar 

  38. J. Jedliński, M. Krasovec, G. Borchardt and J. W. Quadakkers, Journal de Physique IV 3, 591 (1993).

    Google Scholar 

  39. J. Jedlinski, G. Smola, K. Kowalski, A. Bernasik, M. Nocun, J. Camra and J. Bonarski, Materials at High Temperatures 26, 259 (2009).

    Article  Google Scholar 

  40. J. Jedliński, J. L. Grosseau Poussard, G. Smoła, G. Bonnet, M. Nocuń, K. Kowalski and J. Dąbek, Materials at High Temperatures 29, (2), 59–69 (2012).

    Article  Google Scholar 

Download references

Acknowledgements

The financial support from (1) University of La Rochelle and Region Poitou-Charentes, France (partial funding of the research and stay of Jerzy Jedliński), and (2) AGH University of Science and Technology, Poland (Grant No. 11.11.160.768) is gratefully acknowledged.

Author information

Authors and Affiliations

  1. Department of Physical Chemistry and Modeling of Processes, Faculty of Materials Science and Ceramics, AGH University of Science and Technology, al. Mickiewicza 30, 30-059, Kraków, Poland

    Jerzy Jedlinski, Jarosław Dabek & Grzegorz Smola

  2. LaSIE, Université de La Rochelle, Avenue Michel Crepeau Fermi, 17042, La Rochelle Cedex 01, France

    Jean Luc Grosseau Poussard

  3. Department of Surface Engineering and Materials Analysis, Faculty of Metals Engineering and Industrial Computer Science, AGH University of Science and Technology, al. Mickiewicza 30, 30-059, Kraków, Poland

    Kazimierz Kowalski

  4. Department of Glass Technology and Amorphous Coatings, Faculty of Materials Science and Ceramics, AGH University of Science and Technology, al. Mickiewicza 30, 30-059, Kraków, Poland

    Marek Nocun

  5. Institute of Inorganic Chemistry and Technology, Cracow University of Technology, ul. Warszawska 24, 31-155, Kraków, Poland

    Zbigniew Żurek

Authors
  1. Jerzy Jedlinski
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jean Luc Grosseau Poussard
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jarosław Dabek
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Kazimierz Kowalski
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Marek Nocun
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Grzegorz Smola
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Zbigniew Żurek
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Jerzy Jedlinski.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Jedlinski, J., Poussard, J.L.G., Dabek, J. et al. The Effect of Implanted Al and/or Y on the Scale Formation on Low-Al Fe20Cr2Al Alloy. Oxid Met 88, 371–382 (2017). https://doi.org/10.1007/s11085-017-9720-x

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11085-017-9720-x

Keywords

Search

Navigation