Abstract
Different morphologies of WO3 nanocrystals such as nanorods and nanoplates have been obtained under hydrothermal conditions using ammonium metatungstate as the precursor in presence of different organic acids such as citric, oxalic, and tartaric acid in the reaction medium. Detailed characterization of the crystal structure, particle morphology, and optical band gap of the synthesized powders have been done by X-ray diffraction, transmission electron microscopy, scanning electron microscopy and solid-state UV–visible spectroscopy study. The as-synthesized materials are WO3 hydrates with orthorhombic phase which transform to the hexagonal WO3 through dehydration upon heating at 350 °C. The resultant products are crystalline with nanoscale dimensions. Finally, the photoactivity of the synthesized materials annealed at 500 °C has been compared employing in photoelectrochemical water oxidation under the illumination of AM 1.5G simulated solar light (100 mWcm−2). The photocurrent measurements upon irradiation of light exhibit obvious photocatalytic activity with a photocurrent of about 0.77, 0.61, and 0.65 mAcm−2 for the WO3 film derived with the oxalic acid, tartaric, and citric acid assisting agents, respectively, at 1.8 V versus Ag/AgCl electrode.
Similar content being viewed by others
References
Amano F, Lib D, Ohtani B (2010) Fabrication and photoelectrochemical property of tungsten(VI) oxide films with a flake-wall structure. Chem Commun 46:2769–2771
Bamwenda G, Arakawa H (2001) The visible light induced photocatalytic activity of tungsten trioxide powders. App Catal A Gen 210:181–191
Boukriba M, Sediri F, Gharbi N (2010) Hydrothermal synthesis of WO3.1/3H2O nanorods and study of their electrical properties. Polyhedron 29:2070–2074
Butler MA (1977) Photoelectrolysis and physical properties of the semiconducting electrode WO3. J Appl Phys 48:1914–1920
Gu Z, Ma Y, Yang W, Zhang G, Yao J (2005) Self-assembly of highly oriented one-dimensional h-WO3 nanostructures. Chem Commun 3597–3599
Hjelm A, Granqvist CG, Wills JM (1996) Electronic structure and optical properties of WO3, LiWO3, NaWO3, and HWO3 Phys. Rev B 54:2436–2445
Hodes G, Cahen D, Manassen J (1976) Tungsten trioxide as a photoanode for photoelectrochemical cell (PEC). Nature 260:312–313
Hong SJ, Jun H, Borse PH, Lee JS (2009) Size effects of WO3 nanocrystals for photooxidation of water in particulate suspension and photoelectrochemical film systems. Int J Hydrogen Energy 34:3234–3242
Jiao Z, Wang J, Ke L, Sun XW, Demir HV (2011) Morphology-tailored synthesis of tungsten trioxide (hydrate) thin films and their photocatalytic properties. ACS Appl Mater Interfaces 3:23–229
Kominami H, Yabutani K, Yamamoto T, Kera Y, Ohtani B (2001) Synthesis of highly active tungsten(VI) oxide photocatalysts for oxygen evolution by hydrothermal treatment of aqueous tungstic acid solutions. J Mater Chem 11:3222–32227
Lassner E, Schubert WD (1999) Tungsten: properties, chemistry, technology of the element, alloys, and chemical compounds. Springer, Berlin
Lee K, Seo WS, Park JT (2003) Synthesis and optical properties of colloidal tungsten oxide nanorods. J Am Chem Soc 125:3408–3409
Lee SH, Deshpande R, Parilla PA, Jones KM, To B, Mahan AH, Dillon AC (2006) Crystalline WO3 nanoparticles for highly improved electrochromic applications. Adv Mater 18:763–766
Li XL, Liu JF, Li YD (2003) Large-scale synthesis of tungsten oxide nanowires with high aspect ratio. Inorg Chem 42:921–924
Li XL, Lou TJ, Sun XM, Li YD (2004) Highly sensitive WO3 hollow-sphere gas sensors. Inorg Chem 43:5442–5449
Lin HM, Hsu CM, Yang HY, Lee PY, Yang CC (1994) Nanocrystalline WO3-based H2S sensors. Sens Actuators B 22:63–68
Liu Y, Liu CY, Zhang ZY (2008) Effects of carboxylic acids on the microstructure and performance of titania nanocrystals. Chem Eng J 138:596–601
Llopis E, Ramirez JA, Cervilla A (1986) Tungsten (VI)-gluconic acid complexes: polarimetric and 13C-n.m.r. studies in an excess of tungsten (VI). Transition Met Chem 11:489–494
Michailovski A, Krumeich F, Patzke GR (2004) Hierarchical growth of mixed ammonium molybdenum/tungsten bronze nanorods. Chem Mater 16:1433–1440
Rajagopal S, Nataraj D, Mangalaraj D, Djaoued Y, Robichaud J, Khyzhun OY (2009) Controlled growth of WO3 nanostructures with three different morphologies and their structural, optical, and photodecomposition studies. Nanoscale Res Lett 4:1335–1342
Santato C, Ulmann M, Augustynski J (2001) Photoelectrochemical properties of nanostructured tungsten trioxide films. J Phys Chem B 105:936–940
Su J, Feng X, Sloppy JD, Guo L, Grimes CA (2011) Vertically aligned WO3 nanowire arrays grown directly on transparent conducting oxide coated glass: synthesis and photoelectrochemical properties. Nano Lett 11:203–208
Takeda Y, Kato N, Fukano T, Takeichi A, Motohiro T, Kawai S (2004) WO3/metal thin-film bilayered structures as optical recording materials. J Appl Phys 96:2417–2422
Wang H, Lindgren T, He J, Hagfeldt A, Lindquist SE (2000) Photoelectrochemistry of nanostructured WO3 thin film electrodes for water oxidation: mechanism of electron transport. J Phys Chem B 104:5686–5696
Xiong YJ, Xia YN (2007) Shape-controlled synthesis of metal nanostructures: the case of palladium. Adv Mater 19:3385–3391
Zhao ZG, Miyauchi M (2008) Nanoporous-walled tungsten oxide nanotube as highly active visible-light-driven photocatalysts. Angew Chem Int Ed 47:7051–7055
Zhao ZG, Liu ZF, Miyauchi M (2010) Nature-inspired construction, characterization, and photocatalytic properties of single-crystalline tungsten oxide octahedral. Chem Commun 46:3321–3323
Zheng H, Tachibana Y, Kalantar-zadeh K (2010) Dye-sensitized solar cells based on WO3. Langmuir 26:19148–19152
Zheng H, Ou JZ, Strano MS, Kaner RB, Mitchell A, Kalantar-zadeh K (2011) Nanostructured tungsten oxide—properties, synthesis, and applications. Adv Funct Mater 21:2175–2196
Zhou L, Zou J, Yu M, Lu P, Wei J, Qian Y, Wang Y, Yu C (2008a) Green synthesis of hexagonal-shaped WO3·0.33H2O nanodiscs composed of nanosheets. Cryst Growth Des 8:3993–3998
Zhou L, Wang W, Xu H (2008b) Controllable synthesis of three-dimensional well-defined BiVO4 mesocrystals via a facile additive-free aqueous strategy. Cryst Growth Des 8:728–733
Zhu J, Wang S, Xie S, Li H (2011) Hexagonal single crystal growth of WO3 nanorods along a [110] axis with enhanced adsorption capacity. Chem Commun 47:4403–4405
Acknowledgments
This research (paper) has been done for the Hydrogen Energy R&D Center that is one of the twenty-first century Frontier R&D Programs funded by the Ministry of Science and Technology, Republic of Korea.
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Biswas, S.K., Baeg, JO., Moon, SJ. et al. Morphologically different WO3 nanocrystals in photoelectrochemical water oxidation. J Nanopart Res 14, 667 (2012). https://doi.org/10.1007/s11051-011-0667-6
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11051-011-0667-6