Achievements in the field of development of a new generation of refractory alloys based on the Nb – Si and Nb – C systems in the leading producing countries are reviewed. Results obtained for specimens of a patented domestic alloy with composition 45Nb – 16Si – 13Ti – 4Zr – 4Hf – 3.5Cr – 3.5Al – 9Mo – 2Y (at.%) are presented. Data on the structure and strength properties of the alloys based on the Nb – C system are discussed.
Similar content being viewed by others
References
V. A. Skibin, V. I. Solonin, and V. A. Palkin, Works of Leading Aircraft Engine Producing Companies on Creation of Advanced Aircraft Engines (an Analytical Review) [in Russian], TsIAM, Moscow (2004), 424 p.
M. Y. Ivanov, High-Temperature Gas Turbines [in Russian], TORUS PRESS, Moscow (2010), 304 p.
T. B. Massalski, Binary Alloy Phase Diagrams, ASM Int., The Materials Information Society.
M. R. Jackson and B. P. Bewlay, Silicide Composite with Niobium-Based Metallic Phase and Silicon-Modified Laves-Type Phase, US Patent 5942055, General Electric Company, 10.08.1998.
M. Palm, B. P. Bewlay, K. S. Kumar, and K. Yoshimi, Intermetallic-Based Alloys for Structural and Functional Applications, Vol. 1295 (MRS Proc.), Cambridge University Press (2011), 484 p.
M. Palm, B. P. Bewlay, Y.-H. He, et al., Wiezorek. Advanced Intermetallic-Based Alloys for Extreme Environment and Energy Applications, Vol. 1128 (MRS Proc.), Cambridge University Press (2014), 586 p.
Won-Yong Kim, Hisao Tanaka, and Shuji Hanada, “Effect of W alloying and NbC dispersion on high temperature strength at 1773 K and room temperature toughness in Nb5Si3/Nb in situ composites,” Mater. Trans., Japan Inst. of Metals, 43(6), 1415 – 1418 (2002).
R. Tanaka, A. Kasama, M. Fujikura, et al., “Research and development of niobium-based superalloys for hot components of gas turbines,” in: Proc. Int. Gas Turbine Congress, 2003, Tokyo, (2003) pp. 102 – 107.
M. Fujikura, A. Kasama, H. Tanaka, and S. Hanada, “Effect of alloy chemistry on the high temperature strength and room temperature fracture toughness of advanced Nb-based alloys,” Mater. Trans., Japan Inst. of Metals, 45(2), 493 – 501 (2004).
Yulong Li, Chaoli Ma, Hu Zhang, and Seiji Miura, “Mechanical properties of directionally solidified Nb – Mo – Si-based alloys with aligned Nbss/Nb5Si3 lamellar structure,” Mater. Sci. Eng. A, 528, 5772 – 5777 (2011).
Q. Huang, X. Guo, Y. Kang, et al., “Microstructures and mechanical properties of directionally solidified multi-element Nb – Si alloy,” Progr. Nat. Sci., Mater. Int., 21, 146 – 152 (2011).
S. Zhang and X. Guo, “Research progress in the effects of alloying elements on the microstructure and properties of niobium silicide based ultra-high temperature alloys,” Mater. Rev., 26, 95 – 99 (2012).
W. Ligang, J. Lina, C. Renji, et al., “Microstructure, mechanical properties and oxidation resistance of Nb – 22Ti – 14Si – 2Hf – 2Al – xCr alloys,” Chinese J. Aeronaut., 25, 292 – 296 (2012).
W. Mao and X. Guo, “Effects of alloying and high-temperature heat treatment on the microstructure of Nb – Ti – Si based ultrahigh temperature alloys,” Progr. Nat. Sci., Mater. Int., 22(2), 139 – 145 (2012).
L. Su, L. Jia, Y. Feng, et al., “Microstructures and room-temperature fracture toughness of directionally solidified Nb – Si – Ti – Cr – Al – Hf alloy,” Mater. Sci. Eng. A, 560, 672 – 677 (2013).
Y. Yan, H Ding, Y. Kang, and J. Song, “Microstructures evaluation and mechanical properties of Nb – Si based alloy processed by electromagnetic cold crucible directional solidification,” Mater. Design, 55, 450 – 455 (2014).
H. Guo, X. Goo, and H. Zhao, “Research progress in directional solidification of Nb – Si based high-temperature alloys,” Metal Mater. Eng., 43(4), 1019 – 1024 (2014).
G. Kang, Y.-W. Xiao, and C. B. Cailiao Gongcheng, “Microstructure and room temperature fracture toughness of Nb – Si materials alloyed by rare earth elements (La, Sm, Tb),” J. Mater. Eng., 44(10), 8 – 16 (2016).
Y. Gou, L. Jia, S. Sun, et al., “Rapid fabrication of Nb – Si based alloy by severe laser melting: Microstructure, hardness and initial oxidation behavior,” Mater. Design, 109, 37 – 46 (2016).
S. Drawin, “P/M manufacturing of niobium silicide based materials,” in: 18th Int. Plansee Seminar (2013), RM105.
S. Drawin, M. Heilmaier, P. Jehanno, et al., “Creep and oxidation resistance of refractory metal silicide based materials,” in: 17th Int. Plansee Seminar (2009), V. 4, pp. 33-1 – 33-10.
S. Drawin and J. Justin, “Advanced lightweight silicide and nitride based materials for turbo-engine applications,” ONERA J., Issue 3, 1 – 3 (2011).
M. I. Karpov, V. I. Vnukov, V. P. Korzhov, et al., “Structure and mechanical properties of a refractory alloy of the Nb – Si system with eutectic composition obtained by methods of directional crystallization,” Deform. Razrush. Mater., No. 12, 2 – 8 (2012).
M. I. Karpov, T. S. Stroganova, V. P. Korzhov, et al., “Effect of titanium and molybdenum on the structure and mechanical properties of an in-situ composite based on the niobium-silicon system,” Izv. Ross. Akad. Nauk, Ser. Fiz., 79(9), 1302 – 1306 (2015).
M. I. Karpov, I. L. Svetlov, N. A. Kuz’mina, et al., “Effect of the crystallization rate on the microstructure, phase composition and strength of in-situ Nb/Nb5Si3 composite,” Izv. Ross. Akad. Nauk, Ser. Fiz., 79(9), 1296 – 1301 (2015).
E. N. Kablov, M. I. Karpov, I. L. Svetlov, et al., “Niobium-based composite material reinforced with niobium silicide and articles fabricated from it, RF Patent No. 2557117,” Byull. Izobr. Polezn. Modeli, No. 20 (2015).
Stan A. David and Harold D. Brody, “Growth of niobium-niobium carbide (Nb2C) eutectic and hypereutectic composites by zone melting,” Metall. Trans., 5, 2316 – 2320 (1974).
Stan A. David and Harold D. Brody, “Banding in niobium-niobium carbide (Nb2C) composite grown by zone melting and freezing,” Metall. Trans., 5, 2608 – 2612 (1974).
Y. Tan, C. L. Ma, A. Kasama, et al., “Effect of alloy composition on microstructure and high temperature properties of Nb – Zr – C ternary alloys,” Mater. Sci. Eng. A., 341(1 – 2), 282 – 288 (2003).
R. Ding, I. P. Jones, and H. Jiao, “Effect of Mo and Hf on the mechanical properties and microstructure of Nb – Ti – C alloys,” Mater. Sci. Eng. A, 458(1 – 2), 126 – 135 (2007).
H. Jiao, I. P. Jones, and M. Aindow, “Microstructures and mechanical properties of Nb – Ti – C alloys,” Mater. Sci. Eng. A, 485(1 – 2), 359 – 366 (2008).
V. I. Kotlyarov, V. T. Beshkarev, V. E. Kartsev, et al., “Fabrication of spherical powders for additive technologies based on metals of group IV,” Fiz. Khim. Obrab. Mater., No. 2, 63 – 70 (2016).
Yu. V. Tsvetkov, A. V. Samokhin, A. A. Fadeev, et al., “Spheroidization of metallic powders in the thermal plasma of arc discharge,” Tekhnol. Legk. Splavov, No. 2, 19 – 24 (2016).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 1, pp. 9 – 14, January, 2018.
Rights and permissions
About this article
Cite this article
Karpov, M.I. Niobium-Base Refractory Alloys with Silicide and Carbide Hardening Current Status and Prospects. Met Sci Heat Treat 60, 7–12 (2018). https://doi.org/10.1007/s11041-018-0232-3
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11041-018-0232-3