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Thermal behaviour and adsorption properties of some benzothiazole derivatives

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Abstract

The thermal stability and the adsorption properties have been investigated for three benzothiazole compounds: 2-mercaptobenzothiazole (MBT), N-cyclohexyl-2-benzothiazole sulfenamide (NCBSA), and 2,2′-dibenzothiazole disulphide (BTD), reported in our early studies as corrosion inhibitors for carbon steel in different media. The electrochemical results were used to calculate the degree of surface coverage (θ). The adsorption mechanism of the three inhibitors was discussed according to the free energy of adsorption (\( \Delta G_{{\text{ads}}}^{\circ } \)) value obtained from Temkin adsorption isotherm, this being the best way to quantitatively express the adsorption process of their molecules on carbon steel surface. Thus, a mixed type mechanism involving the synergism between physisorption and chemisorption was proposed. The thermal analysis curves showed that, for the occurred events up to 470 °C, mass losses take place with endothermic effects followed by the total oxidation of the residue with an exothermic effect around 520 °C. Consequently, their effectiveness follows the order: BTD > NCBSA ≥ MBT, while the thermal stability ranges as follows: NCBSA < BTD ≤ MBT.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Craiova, 107i Calea Bucuresti, Craiova, Romania

    Adriana Samide, Cătălina Ionescu, Bogdan Tutunaru & Anca Moanţă

  2. Department of Physics, Faculty of Mathematics and Natural Sciences, University of Craiova, 13 A.I. Cuza Street, 200585, Craiova, Romania

    Petre Rotaru

  3. Equipe SyGReM, Institut des Biomolécules Max Mousseron (IBMM), UMR 5247, CNRS-UM1-UM2, ENSCM, 8, rue de l’Ecole Normale, 34296, Montpellier cedex 05, France

    Véronique Barragan-Montero

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  1. Adriana Samide
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  2. Petre Rotaru
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  3. Cătălina Ionescu
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  4. Bogdan Tutunaru
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  5. Anca Moanţă
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  6. Véronique Barragan-Montero
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Correspondence to Adriana Samide.

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Samide, A., Rotaru, P., Ionescu, C. et al. Thermal behaviour and adsorption properties of some benzothiazole derivatives. J Therm Anal Calorim 118, 651–659 (2014). https://doi.org/10.1007/s10973-014-3644-3

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  • DOI: https://doi.org/10.1007/s10973-014-3644-3

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