Skip to main content
SpringerLink
Log in

DSC study of stabilization reactions in poly(acrylonitrile-co-itaconic acid) with peak-resolving method

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

The effect of itaconic acid (IA) content and heating rate on the stabilization reactions in poly(acrylonitrile-co-itaconic acid) (P(AN-co-IA)) was investigated by differential scanning calorimetry (DSC) with peak-resolving method. Increasing IA content was effective in decreasing the initial temperature and the heat evolved, and found to enhance oxidative reactions to some extent. While, promoting heating rate resulted in a shift of the exotherm to a higher temperature and a more rapid liberation of heat. The percentage of area of the first exothermic peak increased with increasing heating rate, which would be attributed to the enhancement of the free radical cyclization reactions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. K. Gupta, D. K. Paliwal and P. Bajaj, J. Macromol. Sci. Rev., 31 (1991) 1.

    Google Scholar 

  2. R. Devasia, C. P. Reghunadhan Nair and K. N. Ninan, Eur. Polym. J., 39 (2003) 537.

    Article  CAS  Google Scholar 

  3. R. Devasia, C. P. Reghunadhan Nair and K. N. Ninan, Eur. Polym. J., 38 (2002) 2003.

    Article  CAS  Google Scholar 

  4. P. Bajaj, K. Sen and S. Hajir Bahrami, J. Appl. Polym. Sci., 59 (1996) 1539.

    Article  CAS  Google Scholar 

  5. I. F. Catta Preta, S. L. Sakata, G. Garcia, J. P. Zimmermann, F. Galembeck and C. Giovedi, J. Therm. Anal. Cal., 87 (2007) 657.

    Article  CAS  Google Scholar 

  6. A. K. Gupta, D. K. Paliwal and P. Bajaj, J. Appl. Polym. Sci., 58 (1995) 1161.

    Article  CAS  Google Scholar 

  7. A. K. Gupta, D. K. Paliwal and P. Bajaj, J. Appl. Polym. Sci., 59 (1996) 1819.

    Article  CAS  Google Scholar 

  8. P. Bajaj, T. V. Sreekumar and K. Sen, Polymer, 42 (2001) 1707.

    Article  CAS  Google Scholar 

  9. M. G. Dunham and D. D. Edie, Carbon, 30 (1992) 435.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Key Laboratory of Carbon Materials, Shanxi Institute of Coal Chemistry, Chinese Academy of Sciences, 030001, Taiyuan, China

    Q. Ouyang, L. Cheng, H. J. Wang & K. X. Li

  2. Graduate University of Chinese Academy of Sciences, 100049, Beijing, China

    Q. Ouyang & L. Cheng

Authors
  1. Q. Ouyang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. Cheng
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. H. J. Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. K. X. Li
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to H. J. Wang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ouyang, Q., Cheng, L., Wang, H.J. et al. DSC study of stabilization reactions in poly(acrylonitrile-co-itaconic acid) with peak-resolving method. J Therm Anal Calorim 94, 85–88 (2008). https://doi.org/10.1007/s10973-007-8773-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-007-8773-5

Keywords

Search

Navigation