Skip to main content
SpringerLink
Log in

Room-temperature interaction of n-hexane with ZSM-5 zeolites

Microcalorimetric and temperature-programmed desorption studies

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

In this work, room temperature interaction of n-hexane with HZSM-5 (Si/Al=20) and ion-exchanged samples containing one (CuZSM-5, FeZSM-5 and MnZSM-5) or two transition-metal cations (Fe,CuZSM-5; Cu,MnZSM-5 and Fe,MnZSM-5) was studied by microcalorimetry and TPD methods. Both differential heats and the amounts of n-hexane adsorbed per one unit cell were quantitatively determined. Higher heats of adsorption and higher amounts of adsorbed gas were found for ion-exchanged samples than for HZSM-5. The experiments of n-hexane adsorption on hydrated samples were also performed. The amounts of n-hexane adsorbed on hydrated ZSM-5 were lower in comparison with dehydrated samples, while the energies of interaction were similar.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. KK Sirkar (1997) Chem. Eng. Commun. 157 145 Occurrence Handle1:CAS:528:DyaK2sXisVeqsLg%3D

    CAS  Google Scholar 

  2. SP Bates RA van Santen (1998) Adv. Catal. 42 1 Occurrence Handle1:CAS:528:DyaK1cXjtFSmsbY%3D

    CAS  Google Scholar 

  3. BL Newalkar NV Choudary UT Turaga RP Vijayalakshmi P Kumar BLS Komarneni TSG Bhat (2003) Chem. Mater. 15 1474 Occurrence Handle10.1021/cm020889d Occurrence Handle1:CAS:528:DC%2BD3sXhslSlurc%3D

    Article  CAS  Google Scholar 

  4. NG Van-Den-Begin LVC Rees et al. (1989) Stud. Surf. Sci. Catal. Elsevier Amsterdam 915

    Google Scholar 

  5. SP Bates WJM vanWell RA van Santen B Smit (1996) J. Am. Chem. Soc. 118 6753 Occurrence Handle10.1021/ja953856q Occurrence Handle1:CAS:528:DyaK28Xjsl2ruro%3D

    Article  CAS  Google Scholar 

  6. WJM van Well JP Wolthuizen B Smit JHC van Hooff RA van Santen (1995) Angew. Chem., Int. Ed. Engl. 34 2543 Occurrence Handle10.1002/anie.199525431 Occurrence Handle1:CAS:528:DyaK2MXpslOms7g%3D

    Article  CAS  Google Scholar 

  7. MS Sun O Talu DB Shan (1996) J. Phys. Chem. 100 17276 Occurrence Handle1:CAS:528:DyaK28XlvF2is7s%3D

    CAS  Google Scholar 

  8. F Eder JA Lercher (1997) Zeolites 18 75 Occurrence Handle10.1016/S0144-2449(96)00127-3 Occurrence Handle1:CAS:528:DyaK2sXptFaquw%3D%3D

    Article  CAS  Google Scholar 

  9. PA Jacobs HK Beyer J Valyon (1981) Zeolites 1 161 Occurrence Handle10.1016/S0144-2449(81)80006-1 Occurrence Handle1:CAS:528:DyaL38XkvFyqsLY%3D

    Article  CAS  Google Scholar 

  10. GT Kokotailo SL Lawton DH Olson WM Meier (1978) Nature 272 437 Occurrence Handle10.1038/272437a0 Occurrence Handle1:CAS:528:DyaE1cXltlyltrw%3D

    Article  CAS  Google Scholar 

  11. DH Olson PT Reischman (1996) Zeolites 17 434 Occurrence Handle10.1016/S0144-2449(96)00087-5 Occurrence Handle1:CAS:528:DyaK28XmsVCrsL4%3D

    Article  CAS  Google Scholar 

  12. RE Richards LVC Rees (1987) Langmuir 3 335 Occurrence Handle10.1021/la00075a009 Occurrence Handle1:CAS:528:DyaL2sXhvVejtLY%3D

    Article  CAS  Google Scholar 

  13. F Eder M Stockenhuber JA Lercher (1997) J. Phys. Chem. B 101 5414 Occurrence Handle1:CAS:528:DyaK2sXjslOrs7k%3D

    CAS  Google Scholar 

  14. B Millot A Methivier H Jobic (1998) J. Phys. Chem. B 102 3210 Occurrence Handle10.1021/jp980090i Occurrence Handle1:CAS:528:DyaK1cXis1yqtbo%3D

    Article  CAS  Google Scholar 

  15. W Makowski D Majda (2004) Thermochim. Acta 412 131 Occurrence Handle10.1016/j.tca.2003.09.003 Occurrence Handle1:CAS:528:DC%2BD2cXhvV2ntrg%3D

    Article  CAS  Google Scholar 

  16. AG Stepanov TO Shegai MV Luzgin H Jobic (2003) Eur. Phys. J. E 12 57 Occurrence Handle10.1140/epje/i2003-10037-3 Occurrence Handle1:CAS:528:DC%2BD3sXpvV2gsro%3D

    Article  CAS  Google Scholar 

  17. S Ashtekar AS McLeod MD Mantle PJ Barrie LF Gladden JJ Hastings (2000) J. Phys. Chem. B 104 5281 Occurrence Handle10.1021/jp993966+ Occurrence Handle1:CAS:528:DC%2BD3cXjtV2msbk%3D

    Article  CAS  Google Scholar 

  18. P-P Knops-Gerrits DE De Vos EJP Feijen PA Jacobs (1997) Microporous Mater. 8 3 Occurrence Handle1:CAS:528:DyaK2sXhslCjug%3D%3D

    CAS  Google Scholar 

  19. Y Huang H Wang (2003) Langmuir 19 9706 Occurrence Handle1:CAS:528:DC%2BD3sXotVGhtrg%3D

    CAS  Google Scholar 

  20. H Morell K Angermund AR Lewis DH Brouwer CA Fyfe H Gies (2002) Chem. Mater. 14 2192 Occurrence Handle10.1021/cm011267f Occurrence Handle1:CAS:528:DC%2BD38XivVGnsbY%3D

    Article  CAS  Google Scholar 

  21. JO Titloye SC Parker FS Stone CRA Catlow (1991) J. Phys. Chem. 95 4038

    Google Scholar 

  22. RL June AT Bell DN Theodorou (1990) J. Phys. Chem. 94 1508 Occurrence Handle1:CAS:528:DyaK3cXhtVGgurY%3D

    CAS  Google Scholar 

  23. TJH Vlugt R Krishna B Smit (1999) J. Phys. Chem. B 103 1102 Occurrence Handle10.1021/jp982736c Occurrence Handle1:CAS:528:DyaK1MXmsFyktQ%3D%3D

    Article  CAS  Google Scholar 

  24. MS Gruszkiewicz JM Simonson TD Burchell DR Cole (2005) J. Therm. Anal. Cal. 81 609 Occurrence Handle10.1007/s10973-005-0832-1 Occurrence Handle1:CAS:528:DC%2BD2MXpvVajtrw%3D

    Article  CAS  Google Scholar 

  25. VM Rakić V Dondur S Gajinov A Auroux (2004) Thermochim. Acta 42 51

    Google Scholar 

  26. H Zou M Li J Shen A Auroux (2003) J. Therm. Anal. Cal. 72 209 Occurrence Handle10.1023/A:1023984106581 Occurrence Handle1:CAS:528:DC%2BD3sXktVymtb8%3D

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Agriculture, Belrade-Zemun, Yugoslavia, 11080, Nemanjina 6

    Rac V. & Rakić Vesna

  2. Institut de Recherches sur la Catalyse, Villeurbanne Cedex, France, 69626, 2, Av. Einstein

    Auroux Aline

  3. Institute of General and Physical Chemistry, Belgrade, Yugoslavia, 11000, Studentski trg 12

    Gajinov S

  4. Faculty of Physical Chemistry, University of Belgrade, Belgrade, Yugoslavia

    Dondur Vera

Authors
  1. Rac V.
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Rakić Vesna
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Gajinov S
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Dondur Vera
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Auroux Aline
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Rac V..

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rac, V., Rakić, V., Gajinov, S. et al. Room-temperature interaction of n-hexane with ZSM-5 zeolites. J Therm Anal Calorim 84, 239–245 (2006). https://doi.org/10.1007/s10973-005-7164-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-005-7164-z

Keywords

Search

Navigation