Skip to main content
Log in

Synthesis of TiO2/Bi2WO6 nanofibers with electrospinning technique for photocatalytic methyl blue degradation

  • ORIGINAL PAPER
  • Published:
Journal of Sol-Gel Science and Technology Aims and scope Submit manuscript

Abstract

TiO2/Bi2WO6 composite nanofibers have been successfully synthesized by a simple electrospinning process. XRD, SEM, HR-TEM, nitrogen adsorption–desorption isotherms and UV–visible diffuse reflectance spectra were used to characterize the composite nanofibers. The composite fibers with diameters about 100 nm was composed of nanoparticles and possessed of high specific surface area (49.6 m2 g−1) and porous structure. Besides, the TiO2/Bi2WO6 composite nanofibers exhibited excellent visible photocatalytic property in the photodegradation of methylene blue (MB), and over 97.2 % of MB was degraded within 5.5 h.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Zhang LS, Wong KH, Chen ZG, Yu JC, Zhao JC, Hu C, Chan CY, Wong PK (2009) AgBr-Ag-Bi2WO6 nanojunction system: a novel and efficient photocatalyst with double visible-light active components. Appl Catal A 363:221–229

    Article  CAS  Google Scholar 

  2. Ge M, Li YF, Liu L, Zhou Z, Chen W (2011) Bi2O3–Bi2WO6 composite microspheres: hydrothermal synthesis and photocatalytic performances. J Phys Chem C 115:5220–5225

    Article  CAS  Google Scholar 

  3. Zhang PY, Hu JC, Li JL (2011) Controllable morphology and photocatalytic performance of bismuth silicate nanobelts/nanosheets. RSC Adv 1:1072–1077

    Article  CAS  Google Scholar 

  4. Kong L, Jiang Z, Xiao TC, Lu LF, Jones MO, Edwards PP (2011) Exceptional visible-light-driven photocatalytic activity over BiOBr–ZnFe2O4 heterojunctions. Chem Commun 47:5512–5514

    Article  CAS  Google Scholar 

  5. Zhang XF, Quan X, Chen S, Yu HT (2011) Constructing graphene/InNbO4 composite with excellent adsorptivity and charge separation performance for enhanced visible-light-driven photocatalytic ability. Appl Catal B Environ 105:237–242

    Article  CAS  Google Scholar 

  6. Gao EP, Wang WZ, Shang M, Xu JH (2011) Synthesis and enhanced photocatalytic performance of graphene-Bi2WO6 composite. Phys Chem Chem Phys 13:2887–2893

    Article  CAS  Google Scholar 

  7. Ng YH, Iwase A, Kudo A, Amal R (2010) Reducing graphene oxide on a visible-light BiVO4 photocatalyst for an enhanced photoelectrochemical water splitting. J Phys Chen Lett 1:2607–2612

    Article  CAS  Google Scholar 

  8. Lu QF, Liu SW, Ren MM, Song LJ, Zhao G (2012) Preparation and characterization of hollow In2O3/Co3O4 heterostructured microribbons by electrospinning process. J Sol–Gel Sci Technol 61:169–174

    Article  CAS  Google Scholar 

  9. Meng FK, Li JT, Hong ZL, Zhi MJ, Sakla A, Xiang CC, Wu NQ (2013) Photocatalytic generation of hydrogen with visible-light nitrogen-doped lanthanum titanium oxides. Catal Today 199:48–52

    Article  CAS  Google Scholar 

  10. Li JT, Meng FK, Suri S, Ding WQ, Huang FQ, Wu NQ (2012) Photoelectrochemical performance enhanced by a nickel oxide–hematite p–n junction photoanode. Chem Commun 48:8213–8215

    Article  CAS  Google Scholar 

  11. Bessekhouad Y, Robert D, Weber JV (2004) Bi2S3/TiO2 and CdS/TiO2 heterojunctions as an available configuration for photocatalytic degradation of organicpollutant. J Photochem Photobiol A 163:569–580

    Article  CAS  Google Scholar 

  12. Li YY, Liu JP, Huang XT, Li GY (2007) Hydrothermal synthesis of Bi2WO6 uniform hierarchical microspheres. Cryst Growth Des 7:1350–1355

    Article  Google Scholar 

  13. Wu J, Duan F, Zheng Y, Xie Y (2007) Synthesis of Bi2WO6 nanoplate-built hierarchical nest-like structures with visible-light-induced photocatalytic activity. J Phys Chem C 111:12866–12871

    Article  CAS  Google Scholar 

  14. Kudo A, Hijii S (1999) H2 or O2 evolution from aqueous solutions on layered oxide photocatalysts consisting of Bi3+ with 6s2 configuration and d0 transition metal ions. Chem Lett 28:1103–1104

    Article  Google Scholar 

  15. Zhang LS, Wang WZ, Zhou L, Xu HL (2007) Bi2WO6 Nano- and microstructures: shape control and associated visible-light-driven photocatalytic activities. Small 3:1618–1625

    Article  CAS  Google Scholar 

  16. Zhang C, Zhu YF (2005) Synthesis of square Bi2WO6 nanoplates as high-activity visible-light-driven photocatalysts. Chem Mater 17:3537–3545

    Article  CAS  Google Scholar 

  17. Ma DK, Huang SM, Chen WX, Hu SW, Shi FF, Fan KL (2009) Self-assembled three-dimensional hierarchical umbilicate Bi2WO6 microspheres from nanoplates: controlled synthesis, photocatalytic activities, and wettability. J Phys Chem C 113:4369–4374

    Article  CAS  Google Scholar 

  18. De AA Soler-Illia GJ, Sanchez Clement, Lebeau Benedicte, Patarin Joel (2002) Chemical strategies to design textured materials: from microporous and mesoporous oxides to nanonetworks and hierarchical structures. Chem Rev 102:4093–4138

    Article  Google Scholar 

  19. Feteira A, Sinclair DC (2008) Microwave dielectric properties of low firing temperature Bi2W2O9 ceramics. J Am Ceram Soc 91:1338–1341

    Article  CAS  Google Scholar 

  20. Huang Y, Ai ZH, Ho WK, Chen MJ, Lee SH (2011) Ultrasonic spray pyrolysis synthesis of porous Bi2WO6 microspheres and their visible-light-induced photocatalytic removal of NO. J Phys Chem C 114:6342–6349

    Article  Google Scholar 

  21. Amano F, Nogami K, Abe R, Ohtani B (2008) Preparation and characterization of bismuth tungstate polycrystalline flake-ball particles for photocatalytic reactions. J Phys Chem C 112:9320–9326

    Article  CAS  Google Scholar 

  22. Maeda K, Teramura K, Lu D, Takata T, Saito N, Inoue Y, Domen K (2006) Photocatalyst releasing hydrogen from water. Nature 440:295–295

    Article  CAS  Google Scholar 

  23. Asahi R, Morikawa T, Ohwaki T, Aoki K, Taga Y (2001) Visible-light photocatalysis in nitrogen-doped titamiun oxides. Science 293:269–273

    Article  CAS  Google Scholar 

  24. Ho W, Yu CY, Lee S (2006) Synthesis of hierarchical nanoporous F-doped TiO2 spheres with visible light photocatalytic activity. Chem Commun 10:1115–1117

    Article  Google Scholar 

  25. Mori K, Maki K, Kawasaki S, Yuan S, Yamashita H (2008) Hydrothermal synthesis of TiO2 photocatalysts in the presence of NH4F and their application for degradation of organic compounds. Chem Eng Sci 63:5066–5070

    Article  CAS  Google Scholar 

  26. Peng CW, Ke TY, Brohan L, Richard-Plouet M, Huang JC, Puzenat E, Chiu HT, Lee CY (2008) (101)-Exposed anatase TiO2 nanosheets. Chem Mater 20:2426–2428

    Article  CAS  Google Scholar 

  27. Farhangi N, Chowdhury RR, Medina-Gonzalez Y, Ray MB, Charpentier PA (2011) Visible light active Fe doped TiO2 nanowires grown on graphene using supercritical CO2. Appl Catal B Environ 110:25–32

    Article  CAS  Google Scholar 

  28. Shang M, Wang WZ, Zhang L, Sun SM, Wang L, Zhou L (2009) 3D Bi2WO6/TiO2 hierarchical heterostructure: controllable synthesis and enhanced visible photocatalytic degradation performances. J Phys Chem C 113:14727–14731

    Article  CAS  Google Scholar 

  29. Zhi MJ, Manivannan A, Meng FK, Wu NQ (2012) Highly conductive electrospun carbon nanofiber/MnO2 coaxial nano-cables for high energy and power density supercapacitors. J Power Sources 208:345–353

    Article  CAS  Google Scholar 

  30. Patel AC, Li S, Wang C, Zhang W, Wei Y (2007) Electrospinning of porous silica nanofibers containing silver nanoparticles for catalytic applications. Chem Mater 19:1231–1238

    Article  CAS  Google Scholar 

  31. Hou ZY, Li CX, Yang J, Lian HZ, Yang PP, Chai RT, Cheng ZY, Lin J (2009) One-dimensional CaWO4 and CaWO4:Tb3+ nanowires and nanotubes: electrospinning preparation and luminescent properties. J Mater Chem 19:2737–2746

    Article  CAS  Google Scholar 

  32. Li D, Xia YN (2003) Fabrication of titania nanofibers by electrospinning. Nano Lett 3:555–560

    Article  CAS  Google Scholar 

  33. Gu YX, Jian FF, Wang X (2008) Synthesis and characterization of nanostructured Co3O4 fibers used as anode materials for lithium ion batteries. Thin Solid Films 517:652–655

    Article  CAS  Google Scholar 

  34. Liu HQ, Yang JX, Liang JH, Huang YX, Tang CY (2008) ZnO nanofiber and nanoparticle synthesized through electrospinning and their photocatalytic activity under visible light. J Am Ceram Soc 91:1287–1291

    Article  CAS  Google Scholar 

  35. Feng L, Li SH, Li HJ, Zhai J, Song YL, Jiang L, Zhu DB (2002) Super-hydrophobic surface of aligned polyacrylonitrile nanofibers. Angew Chem Int Ed 41:1221–1223

    Article  CAS  Google Scholar 

  36. Wang CH, Shao CL, Liu YC, Zhang LN (2008) Photocatalytic properties BiOCl and Bi2O3 nanofibers prepared by electrospinning. Scripta Mater 59:332–335

    Article  CAS  Google Scholar 

  37. Binotto G, Larcher D, Prakash AS, Herrera Urbina R, Hegde MS, Tarascon J-M (2007) Synthesis, characterization, and Li-electrochemical performance of highly porous Co3O4 powders. Chem Mater 19:3023–3040

    Article  Google Scholar 

  38. Zhao G, Liu SW, Lu QF, Song LJ (2012) Controllable synthesis of Bi2WO6 Nanofibrous mat by electrospinning and enhanced visible photocatalytic degradation performances. Ind Eng Chem Res 51:10307–10312

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the National Natural Science Foundation of China (Grant No: 51172133), the Key Project of Chinese Ministry of Education (Grant No.: 211098), the Ministry of Education of Shandong Province (Grant No: J09LD23), and the science and technology development plan of Shandong Province (2011SJGZ13). The authors also thank the Analytical Center of Shandong Polytechnic University for the technological support.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Suwen Liu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhao, G., Liu, S., Lu, Q. et al. Synthesis of TiO2/Bi2WO6 nanofibers with electrospinning technique for photocatalytic methyl blue degradation. J Sol-Gel Sci Technol 66, 406–412 (2013). https://doi.org/10.1007/s10971-013-3023-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10971-013-3023-8

Keywords

Navigation