Skip to main content
SpringerLink
Log in

In-situ PMMA modified p-cresol resin-nylon 6 polymer blends and evaluation of their hydrophobic and dielectric properties

  • ORIGINAL PAPER
  • Published:
Journal of Polymer Research Aims and scope Submit manuscript

Abstract

The synthesis of PMMA modified p-Cresol resin-nylon 6 blends by the in-situ polymer blending in various proportion is described. These new polymer blends has been characterized by FT-IR, DSC-TGA, SEM, and screened for the hydrophobic, mechanical and dielectric properties. The blended materials exhibit good thermal stability and increased hydrophobic nature. Compressive stress and the strain study show that the blends have improved mechanical property. The frequency dependent dielectric property of the blend has been lowered. Thus, PMMA modified p-Cresol resin-nylon 6 blends could be used as a potential material for the fabrication of electronic device application.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Scheme 2
Fig. 1
Scheme 3
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Drobny JG (2012) Polymers for electricity and electronics. Materials, properties, and applications. Wiley, New Jersey

    Book  Google Scholar 

  2. Nelson JK (2010) Dielectric polymer nanocomposites. Springer, New York

    Book  Google Scholar 

  3. Maier G (2004). IEEE Electr Insul Mag 20(2):6

    Article  Google Scholar 

  4. Maier G (2004). IEEE Electr Insul Mag 20(3):6

    Article  Google Scholar 

  5. Nalwa H (1999) Handbook of Low and High Dielectric Constant Materials and Their Applications. Academic, London

    Google Scholar 

  6. Shamiryan D, Abell T, Iacopi F, Maex K (2004). Mater Today 7:34–39

    Article  CAS  Google Scholar 

  7. Devaraju S, Prabunathan P, Selvi M, Alagar M (2013). Front Chem 1:19

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  8. Megson NJL (1958) Phenolic Resin Chemistry. Butter-worth Press, London

    Google Scholar 

  9. Knop A, Scheib W (1979) Chemistry and Application of Phenolic Resins. Springer-Verlag, New York

    Book  Google Scholar 

  10. Tanaka A, Nakatsuka R (1980). J Adhes Soc Japn 1:97

    Google Scholar 

  11. Matsumoto A, Hasegawa K, Fukuda A, Otsuki K (1990). J Appl Polym Sci 43:365

    Article  Google Scholar 

  12. Matsumoto A, Hasegawa K, Fukuda A, Otsuki K (1992). J Appl Polym Sci 44:205 1547

    Article  CAS  Google Scholar 

  13. Wu HD, Ma CCM, Lee MS, Wu YD (1996). Angew Macromol Chem 35:235

    Google Scholar 

  14. Ma CCM, Wu HD (1995 July 13-15) In Proceedings of the Interchain Symposium on Polymer Blends, Hsing Chu, Taiwan

  15. Lochte HW, Stranss EL, Conley RT (1965). J Appl Polym Sci 9:2799

    Article  CAS  Google Scholar 

  16. Conley RT (1963). J Appl Polym Sci 7:103

    Article  CAS  Google Scholar 

  17. Nielsen LE (1962) Mechanical Properties of Polymers. Van Nostrand Reinhold, New York

    Google Scholar 

  18. Kim S, Chiba T, Inoue T (1993). Polymer 34:2809

    Article  CAS  Google Scholar 

  19. Kim S, Chiba T, Inoue T (1995). Polymer 36:4367

    Google Scholar 

  20. Kim BS, Inoue T (1995). Polymer 36:1985

    Article  CAS  Google Scholar 

  21. Kim BS (1997). J Appl Polym Sci 65:85

    Article  CAS  Google Scholar 

  22. Wang F-Y, Ma C-CM, Wu W-J (1999). J Appl Polym Sci 73:881–887

    Article  CAS  Google Scholar 

  23. Mark HF, Bikales NM, Overberger CG, Menges G (1985) Encyclopaedia of polymer science and technology. John Wiley and Sons, New York

    Google Scholar 

  24. Mikhailov GP, Borisova TI, Dmitrochenko DA (1956). J Tech Phys (USSR) 26:1924 (see Sov. Phys. Tech. Phys. 1: (1956) 1857

    CAS  Google Scholar 

  25. Mikhailov GP, Borisova TI (1961). Polym Sci (USSR) 2:387

    Google Scholar 

  26. Adachi K (1997) In: Runt JP, Fitzgerald JJ (eds) Dielectric Spectroscopy of Polymeric Materials: Fundamentals and Applications. ACS, Washington, p 261

    Google Scholar 

  27. Mead DJ, Fuoss RM (1942). J Am Chem Soc 64:2389

    Article  CAS  Google Scholar 

  28. Deutsch K, Hoff EAW, Reddish W (1954). J Polym Sci 13:565

    Article  CAS  Google Scholar 

  29. Lavina S, Negro E, Pace G, Gross S, Depaoli G, Vidali M, Di Noto V (2007). J Non Cryst Solids 353:2878

  30. J Heijboer, Kolloid Z (1956) 134:149.

  31. Brouckere L, Offergeld G (1958). J Polym Sci 30:105

    Article  Google Scholar 

  32. Mikhailov GP, Borisova TI (1958). Sov Phys Tech Phys 3:120

    CAS  Google Scholar 

  33. Saito S, Nakajima T (1959). J Appl Polym Sci 2:93

    Article  CAS  Google Scholar 

  34. Ishida Y, Yamafuji K (1961). Kolloid Z 177:97

    Article  CAS  Google Scholar 

  35. Gomez-Ribelles JL, Diaz-Calleja R (1985). J Polym Sci Polym Phys Ed 23:1297

    Article  CAS  Google Scholar 

  36. Schmidt-Rohr K, Kulik AS, Beckham HW, Ohlemacher A, Pawelzik U, Boeffel C, Spiess HW (1994). Macromolecules 27:4733

    Article  CAS  Google Scholar 

  37. Dimitrakopoulos CD, Malenfant PRL (2002). Adv Mater 14:99

    Article  CAS  Google Scholar 

  38. Guillaud G, Simon J, Germain JP, Coord (1998). Chem Rev 1433:178–180

    Google Scholar 

  39. Wilkinson AN, Ryan AJ (1998) Polymer processing: structure development. Kluwer, Dordrecht

    Google Scholar 

  40. Khaydarov AA, Kazlauciunas A, Mounterey PE, Perrier S (2011). Polym Bull 66:1089–1098

    Article  CAS  Google Scholar 

  41. Wu T, Xie T, Yang G (2009). J Appl Polym Sci 111:101–107

    Article  CAS  Google Scholar 

  42. Robeson LM (2007) Polymer blends a comprehensive review. Munich, Carl Hanser Verlag

    Book  Google Scholar 

  43. Paul DR, Barlow JW (1979) A brief review of polymer blend technology. In: Multiphase Polymers; Advances in Chemistry; American Chemical Society: Washington, DC; Vol. 176, Chapter 17: 315-335

  44. Rozentsveig IB, Levkovskaya GGG, Mirskova AN (1999). Russ J Org Chem 35:895–898

    CAS  Google Scholar 

  45. Wang F-Y, Ma C-CM, Wu H-D (1999). J Appl Polym Sci 74:2283–2289

    Article  CAS  Google Scholar 

  46. Preda N, Rusen E, Musuc A, Enculescu M, Matei E, Marculescu B, Fruth V, Enculescu I (2010). Mater Res Bull 45:1008–1012

    Article  CAS  Google Scholar 

  47. Guo Z, Henry LL, Palshin V, Podlaha EJ (2006). J Mater Chem 16:1772–1777

    Article  CAS  Google Scholar 

  48. Huang C-F, Kuo S-W, Lina H-C, Chena J-K, Chena Y-K, Xub H, Changa F-C (2004). Polymer 45:5913–5921

    Article  CAS  Google Scholar 

  49. Wang F-Y, Ma C-CM, Hung AYC, Wu H-D (2001). Macromol Chem Phys 202:11

    Google Scholar 

  50. Hosakawa M, Akiyama S (1999). Polym J 3:13–20

    Article  Google Scholar 

  51. Davis RD, Jarrett WL, Mathias LJ (2001). Polymer 42:2621

    Article  CAS  Google Scholar 

  52. Choi YS, Ham HT, Chung IJ (2003). Polymer 44:8147–8154

    Article  CAS  Google Scholar 

  53. Dias RCM, Goes AM, Serakides R, Ayres E, Orefice RL (2010). Mater Res 13:211

    Article  CAS  Google Scholar 

  54. Chiou C-W, Lin Y-C, Wang L, Maeda R, Hayakawa T, Kuo S-W (2014). Macromolecules 47:8709–8721

    Article  CAS  Google Scholar 

  55. Baskaran R, Selvasekarapandian S, Kuwata N, Kawamura J, Hattori T (2006). Solid State Ionics 177:2679–2682

    Article  CAS  Google Scholar 

  56. Kashiwagi T, Inaba A, Brown JE, Hatada K, Kitayama T, Masuda E (1986). Macromolecules 19:2160–2168

    Article  CAS  Google Scholar 

  57. Manring LE (1989). Macromolecules 22:2673–2677

    Article  CAS  Google Scholar 

  58. Manring LE, Sogah DY, Cohen GM (1989). Macromolecules 22:4652–4654

    Article  CAS  Google Scholar 

  59. Viratyaporn W, Lehman RL (2011). J Therm Anal Calorim 103:267–273

    Article  CAS  Google Scholar 

  60. Madhukar K, Sesha Sainath AV, Sanjeeva Rao B, Suresh Kumar D, Bikshamaiah N, Srinivas Y, Mohan Babu N, Ashok B (2012). Polym Eng Sci 53:397–402

    Article  CAS  Google Scholar 

  61. Redjel B (1995). Plast Rubb Compos Applic 24:221

    CAS  Google Scholar 

  62. St John NA, Brown JR (1998). Compos Part A 29A:939–946

    Article  CAS  Google Scholar 

  63. Richeton J, Azhi S, Vecchio KS, Jiang FC, Adharapurapu RR (2006). Int J Solids Struct 43:2318

    Article  CAS  Google Scholar 

  64. Mulliken AD, Boyce MC (2006). Int J Solids Struct 43:1331

    Article  CAS  Google Scholar 

  65. Young T (1805). Philos Trans R Soc Lond 95:65–87

    Article  Google Scholar 

  66. Lin JJ, Wang XD (2007). Polymer 48:318–329

    Article  CAS  Google Scholar 

  67. Deligoz H, Yalcinyuva T, Ozgumus S, Yildirim S (2006). J Appl Polym Sci 100:810–818

    Article  CAS  Google Scholar 

  68. Zhu L (2014). J Phys Chem Lett 5(21):3677–3687

    Article  CAS  PubMed  Google Scholar 

  69. Treufeld I, Wang DH, Kurdish BA, Tan L-S, Zhu L (2014). J Mater Chem A 2(48):20683–20696

    Article  CAS  Google Scholar 

  70. Gardziella A, Pilato LA, Knop A (2000) Phenolic Resins Chemistry, Applications, Standardization, and Ecology. Springer-Verlag, Berlin Heidelberg

    Google Scholar 

  71. Knop A, Pilato LA (1985) Phenolic Safety Resins: Chemistry, Applications, and Performance. Springer-Verlag, Berlin Heidelberg

    Book  Google Scholar 

  72. Gross S, Camozzo D, Di Noto V, Armelao L, Tondello E (2007). Eur Polym J 43:673–696

    Article  CAS  Google Scholar 

Download references

Acknowledgements

We gratefully acknowledge the Defense Research and Development Organization [DRDO]-INDIA for the financial support [Project. No: ERIP/ER/1203109/M/01/1502]. We also gratefully acknowledge Prof. K. K. Balasubramanian, INSA Senior Scientist, Dept. of Biotechnology, IIT Madras for his kind help and valuable suggestions.

Author information

Authors and Affiliations

  1. Condensed Matter Research Lab, CCG, VIT University, -632014, Vellore, India

    Thiruvengadam Vedamurthy & Malathi Murugesan

Authors
  1. Thiruvengadam Vedamurthy
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Malathi Murugesan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Malathi Murugesan.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Vedamurthy, T., Murugesan, M. In-situ PMMA modified p-cresol resin-nylon 6 polymer blends and evaluation of their hydrophobic and dielectric properties. J Polym Res 25, 209 (2018). https://doi.org/10.1007/s10965-018-1588-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10965-018-1588-1

Keywords

Search

Navigation