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High performance thermosets based on multifunctional intermediates containing allyl, maleimide and benzoxazine groups

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Abstract

High performance thermosets were prepared by thermally curing of multifunctional intermediates containing allyl, maleimide, furyl and benzoxazine rings. The multifunctional intermediates were obtained by cycloaddition reaction of 2,2′-bis(8-allyl-3-furfuryl-3,4-dihydro-2H-1,3-benzoxazinyl)isopropane or bis(3-furfuryl-3,4-dihydro-2H-1,3-benzoxazinyl)isopropane with 4,4′-bismaleimidodiphenylmethane in molar ratio of 1:1 and 1:2, in THF at reflux. The chemical structure of multifunctional intermediates was elucidated by FTIR and 1H-NMR spectroscopy and curing parameter by differential scanning calorimetry. The thermal analysis showed that decomposition of these materials takes place in two stages and DSC measurements of networks did not exhibit the glass transition temperature up to 300 °C.

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Authors and Affiliations

  1. “Petru Poni” Institute of Macromolecular Chemistry, 41 A Gr.Ghica Voda Alley, Iasi, RO-700487, Romania

    Constantin Gaina, Oana Ursache, Viorica Gaina & Valentina-Elena Musteata

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  1. Constantin Gaina
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  2. Oana Ursache
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  3. Viorica Gaina
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  4. Valentina-Elena Musteata
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Correspondence to Viorica Gaina.

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Gaina, C., Ursache, O., Gaina, V. et al. High performance thermosets based on multifunctional intermediates containing allyl, maleimide and benzoxazine groups. J Polym Res 20, 263 (2013). https://doi.org/10.1007/s10965-013-0263-9

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