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Correlation of the Solubilizing Abilities of 1-Butyl-1-methyl-pyrrolidinium Tris(pentafluoroethyl)trifluorophosphate, 1-Butyl-1-methylpyrrolidinium Triflate and 1-Methoxyethyl-1-methylmorpholinium Tris(pentafluoroethyl)trifluorophosphate

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Abstract

Chromatographic retention data were measured for a wide range of organic solutes on 1-butyl-1-methylpyrolidinium tris(pentafluoroethyl)trifluorophosphate ([BMPyrr]+[FAP]−), 1-butyl-1-methylpyrrolidinium triflate, ([BMPyrr]+[Trif]−), and 1-methoxyethyl-1-methylmorpholinium tris(pentafluoroethyl)trifluorophosphate, ([MeoeMMorp]+[FAP]−), stationary phases at (323, 353 and 383) K. The measured retention factors were combined with published infinite dilution activity coefficient and gas-to-water partition coefficient data to yield gas-to-anhydrous ionic liquid (IL) and water-to-anhydrous IL partition coefficients. The three sets of partition coefficients were analyzed using the Abraham model. The derived Abraham model correlations describe the observed gas-to-IL (log10 K) and water-to-IL (log10 P) partition coefficient data to within average standard deviations of about 0.11 and 0.15 log10 units, respectively.

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Authors and Affiliations

  1. Department of Chemistry, The University of Toledo, 2801 W. Bancroft Street MS 602, Toledo, OH, 43606, USA

    Pamela Twu & Jared L. Anderson

  2. Department of Chemistry, University of North Texas, 1155 Union Circle Drive #305070, Denton, TX, 76203-5017, USA

    Timothy W. Stephens, Anastasia Wilson & William E. Acree Jr.

  3. Department of Chemistry, University College London, 20 Gordon Street, London, WC1H 0AJ, UK

    Michael H. Abraham

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  1. Pamela Twu
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  2. Jared L. Anderson
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Correspondence to William E. Acree Jr..

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Twu, P., Anderson, J.L., Stephens, T.W. et al. Correlation of the Solubilizing Abilities of 1-Butyl-1-methyl-pyrrolidinium Tris(pentafluoroethyl)trifluorophosphate, 1-Butyl-1-methylpyrrolidinium Triflate and 1-Methoxyethyl-1-methylmorpholinium Tris(pentafluoroethyl)trifluorophosphate. J Solution Chem 42, 772–799 (2013). https://doi.org/10.1007/s10953-013-9994-9

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