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Supramolecular compounds of chloroaquacomplexes [Mo3Q4(H2O)9−x Clx](4−x)+ (Q = S, Se; x = 2, 3, 5) with cucurbit[n]urils

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Abstract

The following adducts of cucurbit[6]uril and cucurbit[8]uril with triangular cluster chloroaquacomplexes have been prepared and characterized: {[Mo3S4(H2O)7Cl2]2(CB[6])}Cl4·13H2O (I), (H3O)2{[Mo3Se4×(H2O)6Cl3](CB[6])}Cl3·3.5H2O (II) and (H3O)2{[Mo3S4(H2O)4Cl5](CB[8])}Cl·14H2O (III). It is shown that the formation of complementary hydrogen bonds in the systems cucurbit[6]uril/[M3Q4(H2O)9−x Clx](4−x)+ (x = 1–3) results in a selective isolation of isomers containing chlorine atom in the trans-position to the capping μ3-ligand. For large x, a selective inclusion of one or another form into the supramolecular compound is also affected by other factors (a system of hydrogen bonds, S⋯S and S…Cl interactions between cluster complexes, packing effects etc.).

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk

    E. V. Chubarova, M. N. Sokolov, D. G. Samsonenko & V. P. Fedin

  2. Departament de Ciencies Experimentals Castelló de la Plana, Universitat Jaume I, Espanya

    C. Vicent

Authors
  1. E. V. Chubarova
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  2. M. N. Sokolov
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  3. D. G. Samsonenko
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  4. C. Vicent
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  5. V. P. Fedin
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Original Russian Text Copyright © 2006 by E. V. Chubarova, M. N. Sokolov, D. G. Samsonenko, C. Vicent, and V. P. Fedin

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Translated from Zhurnal Strukturnoi Khimii, Vol. 47, No. 4, pp. 948–954, September–October, 2006.

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Chubarova, E.V., Sokolov, M.N., Samsonenko, D.G. et al. Supramolecular compounds of chloroaquacomplexes [Mo3Q4(H2O)9−x Clx](4−x)+ (Q = S, Se; x = 2, 3, 5) with cucurbit[n]urils. J Struct Chem 47, 939–945 (2006). https://doi.org/10.1007/s10947-006-0411-8

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  • DOI: https://doi.org/10.1007/s10947-006-0411-8

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