Abstract
The synthesis of four new tetra-and di-carbonyl p-tert-butyl thiacalix[4]arenes is reported. The three tetracarbonyl compounds differ as conformational isomers (cone, partial cone, and 1,3-alternate). The influence of the alkali metal ion templates on the formation of the different conformational isomers of the compound was studied by the solvent extraction method.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
T. Araki and H. Tsukube, Liquid Membranes: Chemical Application, CRC Press, Inc., Boca Raton, Florida (1990), 213 p.
F. Vogtle, in: Comprehensive Supramolecular Chemistry, J. L. Atwood, J. E. D. Davies, D. D. MacNicol, and F. Vogtle (eds.), Vol. 2, Elsevier, Oxford (1996), 601 p.
J. H. Harley, T. D. James, and C. J. Ward, J. Chem. Soc., Perkin Trans. 1., No. 19, 3155–3184 (2000).
L. Mandolini and R. Ungaro (eds.), Calixarenes in Action, Imperial College Press, Londn (2000), 271 p.
J. Vicens and V. Bohmer, Calixarenes: a Versatile Class of Macrocyclic Compounds, Kluwer, Dordrecht (1991), 268 p.
G.J. Lumetta, R.D. Rogers, and A. S. Gopalan, Calixarenes for Separations, ACS, Washington, DC (2000), 365 p.
H. Kumagai, M. Hagesawa, S. Miyanari, et al., Tetrahedron Lett., 38, No. 22, 3971/3972 (1997).
N. Iki, F. Narumi, T. Fujimoto, et al., J. Chem. Soc., Perkin Trans. 2., 12, 2745–2750 (1998).
I. I. Stoikov, O. A. Omran, S. E. Solovieva, et al., Tetrahedron, 59, No. 9, 1469–1476 (2003).
R. Lamartine, C. Bavoux, F. Vocanson, et al., Tetrahedron Lett., 42, No. 6, 1021–1024 (2001).
V. V. Klochkov, B. I. Khairutdinov, A. V. Klochkov, et al., Izv. Akad. Nauk, Ser. Khim., 7, 1411–1415 (2004).
P. Lhotak, V. Stastny, P. Zlatuskova, et al., Collect. Czech. Chem. Commun., 65, No. 5, 757–771 (2000).
P. Lhotak, M. Himl, S. Pakhomova, and I. Stibor, Tetrahedron Lett., 39, No. 48, 8915–8918 (1998).
E. A. Shokova and V. V. Kovalev, Russ. J. Org. Chem., 39, No. 1, 13–40 (2003).
J.-L. M. Abboud and R. Notario, Pure Appl.Chem., 71, No. 4, 645–718 (1999).
Author information
Authors and Affiliations
Additional information
Original Russian Text Copyright © 2005 by L. I. Gafiullina, I. S. Vershinina, I. I. Stoikov, I. S. Antipin, and A. I. Konovalov
__________
Translated from Zhurnal Strukturnoi Khimii, Vol. 46, Supplement, pp. S25–S29, 2005.
Rights and permissions
About this article
Cite this article
Gafiullina, L.I., Vershinina, I.S., Stoikov, I.I. et al. New host molecules based on the thiacalix[4]arene platform for cation recognition. J Struct Chem 46 (Suppl 1), S22–S27 (2005). https://doi.org/10.1007/s10947-006-0146-6
Received:
Issue Date:
DOI: https://doi.org/10.1007/s10947-006-0146-6