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Hydrothermal synthesis of sphere-shaped silver-based magnetic nanocomposite loaded on mesoporous KIT-5 for efficient photocatalytic degradation of tetracycline (TC)

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Abstract

KIT-5 mesoporous silica was loaded with silver-based magnetic nanocomposite with the help of an acid modulator under hydrothermal conditions. The morphology, bandgap, surface area, pore size, and magnetic properties of the magnetic nanocomposite-loaded KIT-5 material were determined using imaging, spectroscopic, BET analysis, and VSM studies, respectively. The magnetic nanocomposite-loaded mesoporous KIT-5 material was then screened for pharmaceutical waste degradation, and it was found that the material was able to photo-catalytically degrade the toxic tetracycline with 97% efficiency under visible light conditions. UV spectrophotometer was used to investigate the usage of functionalized nanomaterial for the degradation and removal of pharmaceutical waste, tetracycline. The recyclability and reusability of the magnetic nanocomposite-loaded mesoporous KIT-5 material in pharma waste degradation were also studied. A mechanism for the degradation of tetracycline by the magnetic mesoporous KIT-5 material was also discussed based on the crystallinity, surface area, and bandgap of the material.

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Acknowledgements

The authors thank DST SERB, the Government of India for the research grant released for project no. DST-SERB (SB/FT/CS-074/2012) and DST-SAIF Cochin for characterization and instrumentation support. The authors also thank the administrations of The Center for Nanoscience and Genomics, Karunya Institute of Technology & Sciences, Coimbatore, and SRM Research Institute, SRM Institute of Science and Technology, Chennai for providing research aid.

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Authors and Affiliations

  1. Center for Nanoscience and Genomics, Karunya Institute of Technology & Sciences, Karunya Nagar, 641114, Coimbatore, Tamilnadu, India

    Peter Daniel Nixon, Asir Eliet Magdalin & Israel. V. M. V. Enoch

  2. Department of Physics and Nanotechnology, SRM Institute of Science and Technology, 603203, Kattankulathur, Chennai, Tamilnadu, India

    V. Vinesh & Mani Preeyanghaa

  3. Department of Applied Chemistry, Karunya Institute of Technology & Sciences, Karunya Nagar, 641114, Coimbatore, Tamilnadu, India

    Elangovan Jayaseelan & Nallamuthu Ananthi

  4. Department of Chemistry, SRM Institute of Science and Technology, 603203, Kattankulathur, Chennai, Tamilnadu, India

    B. Neppolian

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  1. Peter Daniel Nixon
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Contributions

Peter Daniel Nixon contributed to the literature survey, experimentation, characterization analysis, interpretation, and drafting, V. Vinesh performed analysis and data interpretation, Elangovan Jayaseelan assisted in experimentation, Asir Eliet Magdalin assisted in drafting, Mani Preeyanghaa contributed to materials characterization, Israel V.M.V. Enoch assisted in revision for important intellectual content, B. Neppolian and Nallamuthu Ananthi involved in all aspects of works in ensuring the accuracy of any part of the work are appropriately investigated and resolved.

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Correspondence to Nallamuthu Ananthi.

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Nixon, P.D., Vinesh, V., Jayaseelan, E. et al. Hydrothermal synthesis of sphere-shaped silver-based magnetic nanocomposite loaded on mesoporous KIT-5 for efficient photocatalytic degradation of tetracycline (TC). J Porous Mater 30, 821–833 (2023). https://doi.org/10.1007/s10934-022-01387-y

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