Skip to main content
SpringerLink
Log in

Preparation of Chitin/Cellulose Films Compatibilized with Polymeric Ionic Liquids

  • Original Paper
  • Published:
Journal of Polymers and the Environment Aims and scope Submit manuscript

Abstract

This paper reports the preparation of chitin/cellulose films compatibilized with polymeric ionic liquids. In-situ (co)polymerization of polymerizable ionic liquids, 1-(3-methacryloyloxypropyl)-3-vinylimidazolium bromide (1) and 1-methyl-3-vinylbenzylimidazolium chloride (3), was carried out in the presence of a radical initiator, AIBN, in the chitin/cellulose solution with ionic liquid solvents (1-butyl-3-methylimidazolium acetate and chloride, BMIMOAc and BMIMCl, respectively), followed by the appropriate procedure to give the desired films. The presence of the polymeric ionic liquid in the film was confirmed by the IR measurement. The powder X-ray diffraction analysis suggested that crystalline structures of the polysaccharides were largely disrupted in the film, as same as that of a chitin/cellulose film prepared by the AMIMOAc/BMIMCl system. These results were different from the XRD result of a chitin/cellulose film prepared by the 1-allyl-3-methylimidazolium bromide/BMIMCl system reported in our previous study, in which some crystalline structures were still remained in the film. Furthermore, the mechanical properties of the present films were evaluated by tensile testing, which were affected by the molar ratios of the polymeric ionic liquids to the polysaccharides and the compositional ratios of the two units 1 and 3.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Schuerch C (1986) Polysaccharides. In: Mark HF, Bilkales N, Overberger CG (eds) Encyclopedia of polymer science and engineering, vol 13, 2nd edn. Wiley, New York, pp 87–162

    Google Scholar 

  2. Klemm D, Heublein B, Fink H-P, Bohn A (2005) Angew Chem Int Ed 44:3358

    Article  CAS  Google Scholar 

  3. Kurita K (2006) Mar Biotechnol 8:203

    Article  CAS  Google Scholar 

  4. Rinaudo M (2006) Prog Polym Sci 31:603

    Article  CAS  Google Scholar 

  5. Pillai CKS, Paul W, Sharma CP (2009) Prog Polym Sci 34:641

    Article  CAS  Google Scholar 

  6. Liebert T, Heinze T (2008) BioResources 3:576

    Google Scholar 

  7. Feng L, Chen ZI (2008) J Mol Liq 142:1

    Article  Google Scholar 

  8. Pinkert A, Marsh KN, Pang S, Staiger MP (2009) Chem Rev 109:6712

    Article  CAS  Google Scholar 

  9. Zakrzewska ME, Lukasik EB, Lukasik RB (2010) Energy Fuels 24:737

    Article  CAS  Google Scholar 

  10. Swatloski RP, Spear SK, Holbrey JD, Rogers RD (2002) J Am Chem Soc 124:4974

    Article  CAS  Google Scholar 

  11. Wu Y, Sasaki T, Irie S, Sakurai K (2008) Polymer 49:2321

    Article  CAS  Google Scholar 

  12. Prasad K, Murakami M, Kaneko Y, Takada A, Nakamura Y, Kadokawa J (2009) Int J Biol Macromol 45:221

    Article  CAS  Google Scholar 

  13. Qin Y, Lu X, Sun N, Rogers RD (2010) Green Chem 12:968

    Article  CAS  Google Scholar 

  14. Wang WT, Zhu J, Wang XL, Huang Y, Wang YZ (2010) J Macromol Sci Part B Phys 49:528

    Article  CAS  Google Scholar 

  15. Muzzarelli RAA (2011) Mar Drugs 9:1510

    Article  CAS  Google Scholar 

  16. Jaworska MM, Kozlecki T, Gorak A (2012) J Polym Eng 32:67

    Article  Google Scholar 

  17. Bochek AM, Murav’ev AA, Novoselov NP, Zaborski M, Zabivalova NM, Petrova VA, Vlasova EN, Volchek BZ, Lavrent’ev VK (2012) Russ J Appl Chem 85:1718

    Article  CAS  Google Scholar 

  18. Takegawa A, Murakami M, Kaneko Y, Kadokawa J (2010) Carbohydr Polym 79:85

    Article  CAS  Google Scholar 

  19. Kadokawa J, Hirohama K, Mine S, Kato T, Yamamoto K (2012) J Polym Environ 20:37

    Article  CAS  Google Scholar 

  20. Kadokawa J (2012) Preparation of functional ion gels of polysaccharides with ionic liquids. In: Mun J, Sim H (eds) Handbook of ionic liquids: properties, applications and hazards, chap 18. Nova Science Publishers, Hauppauge, pp 455–466

    Google Scholar 

  21. Silva SS, Duarte ARC, Carvalho AP, Mano JF, Reis RL (2011) Acta Biomater 7:1166

    Article  CAS  Google Scholar 

  22. Ma HY, Hsiao BS, Chu B (2011) Polymer 12:2594

    Article  Google Scholar 

  23. Giernoth R (2010) Angew Chem Int Ed 49:2834

    Article  CAS  Google Scholar 

  24. Kadokawa J (2011) Preparation of polysaccharide-based materials compatibilized with ionic liquids. In: Kokorin A (ed) Ionic liquids, application and perspectives, chap 6. InTech, Rijeka, pp 95–114

    Google Scholar 

  25. Kadokawa J, (2013) J Biobased Mater Bioenergy (in press)

  26. Green O, Grubjesic S, Lee S, Firestone MA (2009) J Macromol Sci Part C Polym Rev 49:339

    CAS  Google Scholar 

  27. Mecerreyes D (2011) Prog Polym Sci 36:1629

    Article  CAS  Google Scholar 

  28. Murakami M, Kaneko Y, Kadokawa J (2007) Carbohydr Polym 69:378

    Article  CAS  Google Scholar 

  29. Kadokawa J, Murakami M, Kaneko Y (2008) Compos Sci Technol 68:493

    Article  CAS  Google Scholar 

  30. Takegawa A, Murakami M, Kaneko Y, Kadokawa J (2009) Polym Compos 30:183

    Article  Google Scholar 

  31. Prasad K, Mine S, Kaneko Y, Kadokawa J (2010) Polym Bull 64:341

    Article  CAS  Google Scholar 

  32. Wakizono S, Yamamoto K, Kadokawa J (2011) J Photochem Photobiol, A 222:283

    Article  CAS  Google Scholar 

  33. Wakizono S, Yamamoto K, Kadokawa J (2012) J Mater Chem 22:10619

    Article  CAS  Google Scholar 

  34. Poirier M, Charlet G (2002) Carbohydr Polym 50:363

    Article  CAS  Google Scholar 

  35. Shigemasa Y, Matsuura H, Sashiwa H, Saimoto H (1996) Int J Biol Macromol 18:237

    Article  CAS  Google Scholar 

  36. Yamazaki S, Takegawa A, Kaneko Y, Kadokawa J, Yamagata M, Ishikawa M (2009) Electrochem Commun 11:68

    Article  CAS  Google Scholar 

  37. Yamazaki S, Takegawa A, Kaneko Y, Kadokawa J, Yamagata M, Ishikawa M (2010) J Electrochem Soc 157:A203

    Article  CAS  Google Scholar 

  38. Yamazaki S, Takegawa A, Kaneko Y, Kadokawa J, Yamagata M, Ishikawa M (2010) J Power Sources 195:6245

    Article  CAS  Google Scholar 

  39. Prasad K, Kadokawa J (2010) Polym Compos 31:799

    CAS  Google Scholar 

  40. Yamagata M, Soeda K, Yamazaki S, Ishikawa M (2011) Electrochem Solid State Lett 14:A165

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Graduate School of Science and Engineering, Kagoshima University, 1-21-40 Korimoto, Kagoshima, 890-0065, Japan

    Miwa Setoyama, Takeshi Kato, Kazuya Yamamoto & Jun-ichi Kadokawa

  2. Muroran Institute of Technology, Research Center for Environmentally Friendly Materials Engineering, 27-1 Mizumoto-cho, Muroran, Hokkaido, 050-8585, Japan

    Jun-ichi Kadokawa

Authors
  1. Miwa Setoyama
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Takeshi Kato
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Kazuya Yamamoto
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jun-ichi Kadokawa
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Jun-ichi Kadokawa.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Setoyama, M., Kato, T., Yamamoto, K. et al. Preparation of Chitin/Cellulose Films Compatibilized with Polymeric Ionic Liquids. J Polym Environ 21, 795–801 (2013). https://doi.org/10.1007/s10924-013-0580-4

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10924-013-0580-4

Keywords

Search

Navigation