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Two Cu(I\II) Coordination Polymers for Photocatalytic Degradation of Organic Dyes and Efficient Detection of Fe3+ Ions

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Abstract

In this work, two new copper-based coordination polymers (CPs), {[CuI(H2PO4)(dpe)]5(dpe)0.5(H2O)7}n (Cu-dpe(I)) and {[CuII(HPO4)(dpe)(H2O)](H2O)3}n (Cu-dpe(II)) (dpe = 1,2-di(4-pyridyl)ethylene), had been successfully constructed by hydrothermal method and solvent evaporation method, respectively, and their crystal structures were determined by single crystal X-ray diffraction. The differences of structure and properties between these two coordination polymers were discussed. The synthetic temperature caused their structure differences. They both exhibit excellent photocatalytic activity toward the degradation of methylene blue (MB) under visible light. The degradation rates of Cu-dpe(I) and Cu-dpe(II) to MB in 120 min under visible light were 88.1% and 97.2%, respectively. Some active free radicals such as ·OH, ·O2−, e− played an important role in degradation of MB. In addition, luminescent experiment revealed Cu-dpe(I) exhibits a relatively high sensitive and selective detection of Fe3+ ions in water solution via fluorescence quenching which was caused by competitive absorption of excitation wavelength energy between Fe3+ and Cu-dpe(I).

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Acknowledgements

The authors of this work gratefully appreciate the financial support provided by National Natural Science Foundation of China (Nos. 12104286), Program for Professor of Special Appointment in Shanghai (Youth Oriental Scholar, QD2019005).

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  1. Chenyan Xu and Wenqian Chen have equally contributed to this work.

Authors and Affiliations

  1. Key Laboratory of Organic Compound Pollution Control Engineering, Ministry of Education, School of Environmental and Chemical Engineering, Shanghai University, Shanghai, 200444, People’s Republic of China

    Chenyan Xu, Wenqian Chen, Jiajun Wang, Qiuyu Wu & Liang Tang

  2. School of Chemistry and Materials Science, Jiangsu Normal University, Jiangsu, 221116, People’s Republic of China

    Pengyan Wu

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  1. Chenyan Xu
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Xu, C., Chen, W., Wang, J. et al. Two Cu(I\II) Coordination Polymers for Photocatalytic Degradation of Organic Dyes and Efficient Detection of Fe3+ Ions. J Inorg Organomet Polym 33, 885–894 (2023). https://doi.org/10.1007/s10904-022-02489-5

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