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Octakis(Carboxyalkyl-Thioethyl)Silsesquioxanes and Derived Metal Complexes: Synthesis, Characterization and Catalytic Activity Assessments

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Abstract

Two octakis(carboxyalkyl-thioalkyl)silsesquioxanes (COOH-PSx) were obtained by click photo-induced thiol-ene addition reactions between octavinyl-T8-silsesquioxane and thioalkylcarboxylic acids. Their structures were confirmed by elemental and spectral analyses and in one case by single-crystal X-ray diffraction. The natrium salts of COOH-PSx were used as very efficient ligands for Cu, Ni and Cd ions. The formation of transition metals complexes was confirmed by FT-IR spectroscopy, showing the coordination pattern, and by EDX semiquantitative elemental analysis. They were analyzed in terms of thermal stability, morphology and moisture sorption. The catalytic activity was tested in alkaline decomposition of hydrogen peroxide, the copper complexes showing the best activity, that is 40% conversion after ~ 40 min. A copper complex was also efficient as catalyst in photodecomposition of Congo Red under UV light, without additional oxidation agents or pH adjustments, showing discoloration efficiency of ca. 89% after 145 min and recycling ability. Thus, the results indicated the compounds reported here, obtained by simple and reproducible synthetic protocols, as efficient, stable and re-usable heterogeneous catalyst. The possibilities of structural diversification (by the nature of the functional groups and the metal ion) are wide and of the application potential.

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This work was supported by grants of the Ministry of Research, Innovation and Digitization, CNCS/CCCDI–UEFISCDI, project number PN-III-P2-2.1-PED-2019-3652 (Contract 320/2020, 3DETSi) and project number PN-III-P2-2.1-PED-2019-1885 (Contract 463/2020, DYMATCO).

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Authors and Affiliations

  1. Department of Inorganic Polymers, ”Petru Poni” Institute of Macromolecular Chemistry, Aleea Grigore Ghica Voda 41A, 700487, Iasi, Romania

    Mihaela Dascalu, Alexandru-Constantin Stoica, Adrian Bele, Alexandra Bargan, George-Theodor Stiubianu, Carmen Racles, Sergiu Shova & Maria Cazacu

  2. Department of Polycondensation and Thermostable Polymers, ”Petru Poni” Institute of Macromolecular Chemistry, Aleea Grigore Ghica Voda 41A, 700487, Iasi, Romania

    Ana-Maria Macsim

  3. Centre of Advanced Research in Bionanoconjugates and Biopolymers, ”Petru Poni” Institute of Macromolecular Chemistry, Aleea Grigore Ghica Voda 41A, 700487, Iasi, Romania

    Cristian-Dragos Varganici

Authors
  1. Mihaela Dascalu
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  2. Alexandru-Constantin Stoica
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  3. Adrian Bele
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  4. Ana-Maria Macsim
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  5. Alexandra Bargan
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  6. Cristian-Dragos Varganici
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  7. George-Theodor Stiubianu
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  8. Carmen Racles
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  9. Sergiu Shova
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  10. Maria Cazacu
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Contributions

MD (conceptualization, project administration, supervision, writing–original draft, writing–review & editing), ACS (formal analysis, investigation, visualization), AB (investigation, visualization), AMM (investigation, visualization), AB (investigation, visualization), CDV (investigation, validation), GTS (investigation, visualization, funding acquisition), CR (investigation, validation, writing-original draft), SS (investigation, validation), MC (investigation, validation, writing-original draft, funding acquisition).

Corresponding author

Correspondence to Mihaela Dascalu.

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Dascalu, M., Stoica, AC., Bele, A. et al. Octakis(Carboxyalkyl-Thioethyl)Silsesquioxanes and Derived Metal Complexes: Synthesis, Characterization and Catalytic Activity Assessments. J Inorg Organomet Polym 32, 3955–3970 (2022). https://doi.org/10.1007/s10904-022-02408-8

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  • DOI: https://doi.org/10.1007/s10904-022-02408-8

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