Abstract
In this current study, aminated graphene oxide (AGO) doped on alginate (Alg) matrix offers AGO@Alg hybrid spheres was developed to investigate its potential for retention of fluoride from water. The sophisticated characterization methods likely TGA, SEM, XPS and FTIR studies of AGO@Alg hybrid spheres were attained to recognize its physicochemical properties like thermal stability, morphology, elemental binding energy and functional groups determination. The responsible parameters for fluoride adsorption on AGO@Alg hybrid spheres were optimized under a batch mode to achieve improve defluoridation capacity (DC). The developed AGO@Alg hybrid spheres follow the electrostatic interaction mechanism on fluoride removal. The adsorption isotherms (Langmuir, Temkin, Dubinin–Radushkevich (D–R) and Fruendlich models), kinetics (reaction and diffusion based models) and thermodynamic parameters (ΔS°, ΔG° and ΔH°) were investigated at 303, 313 and 323 K. To minimize the cost-effectiveness of AGO@Alg hybrid spheres the reusability test was carried out. The suitability of AGO@Alg hybrid spheres was also analyzed for the fluoride contaminated field sample taken from fluoride prevalent village.
Similar content being viewed by others
References
N. Singh, S. Kumari, S. Khan, Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 254, 119637 (2021)
S. Kumari, S. Khan, Sci. Rep. 7, 1–12 (2017)
C. Li, N. Chen, Y. Zhao, R. Li, C. Feng, Chemosphere 163, 81–89 (2016)
J. Zhang, N. Chen, Z. Tang, Y. Yu, Q. Hu, C. Feng, Phys. Chem. Chem. Phys. 17, 12041–12050 (2015)
A. Jeyaseelan, M. Naushad, N. Viswanathan, J. Chem. Eng. Data 65, 2990–3001 (2020)
M.V.N. Samrat, K.K. Rao, A.K. SenGupta, J. Riotte, J.R. Mudakavi, J. Water Process. Eng. 23, 327–337 (2018)
A. Azari, R.R. Kalantary, G. Ghanizadeh, B. Kakavandi, M. Farzadkia, E. Ahmadi, RSC Adv. 5, 87377–87391 (2015)
A. Jeyaseelan, N. Viswanathan, J. Chem. Eng. Data 65, 5328–5340 (2020)
S.M. Prabhu, S. Meenakshi, J. Water Process. Eng. 2, 96–104 (2014)
S. George, P. Pandit, A.B. Gupta, Water Res. 44, 3055–3064 (2010)
J.A. Arcibar-Orozco, A.I. Flores-Rojas, J.R. Rangel-Mendez, P.E. Díaz-Flores, Environ. Technol. 41, 1554–1567 (2020)
C.E. Choong, M. Kim, S. Yoon, G. Lee, C.M. Park, J. Taiwan Inst. Chem. Eng. 93, 306–314 (2018)
M.K. Uddin, S.S. Ahmed, M. Naushad, Desalin. Water Treat. 145, 232–248 (2019)
S. De Gisi, G. Lofrano, M. Grassi, M. Notarnicola, Sustain. Mater. Technol. 9, 10–40 (2016)
E.F. Sheka, Y.A. Golubev, N.A. Popova, Nanomaterials 10, 2021 (2020)
N. Ashraf, A. Majid, M. Rafique, M.B. Tahir, Chin. J. Phys. 66, 246 (2020)
S. Stankovich, D.A. Dikin, R.D. Piner, K.A. Kohlhaas, A. Kleinhammes, Y. Jia, Y. Wu, S.T. Nguyen, R.S. Ruoff, Carbon 45, 1558–1565 (2007)
P. Steurer, R. Wissert, R. Thomann, R. Mülhaupt, Macromol. Rapid Commun. 30, 316–327 (2009)
M.J. McAllister, J.L. Li, D.H. Adamson, H.C. Schniepp, A.A. Abdala, J. Liu, M. Herrera-Alonso, D.L. Milius, R. Car, R.K. Prud’homme, I.A. Aksay, Chem. Mater. 19, 4396–4404 (2007)
R. Hassandoost, S.R. Pouran, A. Khataee, Y. Orooji, S.W. Joo, J. Hazard. Mater. 376, 200–211 (2019)
M.D. Firouzjaei, F.A. Afkhami, M.R. Esfahani, C.H. Turner, S. Nejati, J. Water Process. Eng. 34, 101180 (2020)
J. Wang, X. Duan, Q. Dong, F. Meng, X. Tan, S. Liu, S. Wang, Carbon 144, 781–790 (2019)
K. Zuo, X. Huang, X. Liu, E.M. Gil Garcia, J. Kim, A. Jain, L. Chen, P. Liang, A. Zepeda, R. Verduzco, J. Lou, Environ. Sci. Technol. 54, 13322–13332 (2020)
M.A. Ahsan, V. Jabbari, M.T. Islam, R.S. Turley, N. Dominguez, H. Kim, E. Castro, J.A. Hernandez-Viezcas, M.L. Curry, J. Lopez, J.L. Gardea-Torresdey, Sci. Total Environ. 673, 306–317 (2019)
S. Ploychompoo, Q. Liang, X. Zhou, C. Wei, H. Luo, Phys. E: Low-Dimens. Syst. Nanostruct. 125, 114377 (2021)
M.H. Saghi, B. Chabot, S. Rezania, M. Sillanpää, A.A. Mohammadi, M. Shams, A. Alahabadi, Sep. Purif. Technol. 270, 118645 (2021)
N. Singh, S. Kumari, N. Goyal, S. Khan, Environ. Nanotechnol. Monit. Manage. 15, 100444 (2021)
N. Singh, S. Kumari, S. Khan, Mater. Today Commun. 28, 102521 (2021)
M. Manzano, V. Aina, C.O. Arean, F. Balas, V. Cauda, M. Colilla, M.R. Delgado, M. Vallet-Regi, Chem. Eng. J. 137, 30–37 (2008)
M. Bilal, T. Rasheed, F. Nabeel, H.M. Iqbal, In Biofibers and Biopolymers for Biocomposites (Springer, Cham, 2020), pp. 135–157
G.E. Luckachan, C.K.S. Pillai, J. Polym. Environ. 19, 637–676 (2011)
N.M. Mahmoodi, J. Taiwan Inst. Chem. Eng. 44, 322–330 (2013)
K. Pandi, N. Viswanathan, RSC Adv. 6, 75905–75915 (2016)
B.S. Ge, T. Wang, H.X. Sun, W. Gao, H.R. Zhao, Polym. Adv. Technol. 29, 1334–1343 (2018)
K. Pandi, N. Viswanathan, J. Appl. Polym. Sci. (2015). https://doi.org/10.1002/app.41937
J.E. Harwood, Water Res. 3, 273–280 (1969)
J.B. Wu, M.L. Lin, X. Cong, H.N. Liu, P.H. Tan, Chem. Soc. Rev. 47, 1822–1873 (2018)
B. Wang, B. Luo, M. Liang, A. Wang, J. Wang, Y. Fang, Y. Chang, L. Zhi, Nanoscale 3, 5059–5066 (2011)
S. Babu Maddinedi, B.K. Mandal, S.H. Patil, V.V. Andhalkar, S. Ranjan, N. Dasgupta, J. Photochem. Photobiol. B. 166, 252–258 (2017)
J.A. Luceño-Sánchez, G. Maties, C. Gonzalez-Arellano, A.M. Diez-Pascual, Nanomaterials 8, 870 (2018)
S.K. Papageorgiou, E.P. Kouvelos, E.P. Favvas, A.A. Sapalidis, G.E. Romanos, F.K. Katsaros, Carbohydr. Res. 345, 469–473 (2010)
Z. Yi, L. Huajie, L. Mingchun, X. Meihua, J. Mol. Struct. 1209, 127973 (2020)
M. Sarvestani, R. Azadi, Appl. Organomet. Chem. 32, e3906 (2018)
V. Gopalakannan, N. Viswanathan, Int. J. Biol. Macromol. 72, 862–867 (2015)
A. Navaee, A. Salimi, RSC Adv. 5, 59874–59880 (2015)
D. Hulicova-Jurcakova, M. Kodama, S. Shiraishi, H. Hatori, Z.H. Zhu, G.Q. Lu, Adv. Funct. Mater. 19, 1800–1809 (2009)
L.F. Lai, G.M. Huang, X.F. Wang, J. Weng, Carbon 48, 3145–3156 (2010)
C. Struzzi, M. Scardamaglia, N. Reckinger, H. Sezen, M. Amati, L. Gregoratti, J.F. Colomer, C. Ewels, R. Snyders, C. Bittencourt, Phys. Chem. Chem. Phys. 19, 31418–31428 (2017)
N. Viswanathan, I. Aswin Kumar, S. Meenakshi, Int. J. Biol. Macromol. 133, 811–816 (2019)
A. Jeyaseelan, M.D. Albaqami, N. Viswanathan, J. Environ. Chem. Eng. 9, 104995 (2020)
I. Langmuir, J. Am. Chem. Soc. 38, 2221–2295 (1916)
H.M.F. Freundlich, Z. Phys, Chem. 57, 385–470 (1906)
M.M. Dubinin, E.D. Zaverina, L.V. Radushkevich, J. Phys. Chem 21, 1351–1362 (1947)
A. Jeyaseelan, N. Viswanathan, J. Mol. Liq. 326, 115163 (2021)
I. Aswin Kumar, A. Jeyaseelan, N. Viswanathan, M. Naushad, A.J.M. Valente, J Solid State Chem. 302, 122446 (2021)
A.A. Khan, R.P. Singh, Colloids Surf. 24, 33–42 (1987)
H.N. Tran, S.J. You, H.P. Chao, J. Environ. Chem. Eng. 4, 2671–2682 (2016)
Y.S. Ho, G. McKay, Process Biochem. 34, 451–465 (1999)
Y.C. Wong, Y.S. Szeto, J. Appl. Polym. Sci. 92, 1633–1645 (2004)
H.A. Kramers, Physica 7, 284–304 (1940)
G.H. Graaf, H. Scholtens, E.J. Stamhuis, A.A.C.M. Beenackers, Chem. Eng. Sci. 45, 773–783 (1990)
A. Jeyaseelan, K.M.M. Katubi, N.S. Alsaiari, M. Naushad, N. Viswanathan, Diam. Relat. Mater. 117, 108446 (2021)
S.K. Swain, T. Patnaik, V.K. Singh, U. Jha, R.K. Patel, R.K. Dey, Chem. Eng. J. 171, 1218–1226 (2011)
K. Pandi, N. Viswanathan, Carbohydr. Polym. 112, 662–667 (2014)
F. Ke, G. Luo, P. Chen, J. Jiang, Q. Yuan, H. Cai, C. Peng, X. Wan, J. Porous Mater. 23, 1065–1073 (2016)
N. Viswanathan, S. Meenakshi, Appl. Clay Sci. 48, 607–611 (2010)
R.L. Ramos, J. Ovalle-Turrubiartes, M.A. Sanchez-Castillo, Carbon 37, 609 (1999)
A. Jeyaseelan, N.S. Alsaiari, K.M.M. Katubi, M. Naushad, N. Viswanathan, Int. J. Biol. Macromol. 182, 1843–1851 (2021)
A. Bansiwal, D. Thakre, N. Labhshetwar, S. Meshram, S. Rayalu, Colloids Surf. B. 129, 173 (2009)
C.S. Sundaram, N. Viswanathan, S. Meenakshi, J. Hazard. Mater. 172, 147–151 (2009)
K. Pandi, N. Viswanathan, Carbohydr. Polym. 134, 732–739 (2015)
C. Sairam -Sundaram, N. Viswanathan, S. Meenakshi, J. Hazard. Mater. 163, 618–624 (2009)
P. Liang, Y. Zhang, D. Wang, Y. Xu, L. Luo, J. Rare Earths 31, 817–822 (2013)
G. Sharma, A. Kumar, S. Sharma, M. Naushad, P. Dhiman, D.V.N. Vo, F.J. Stadler, Mater. Lett. 278, 128359 (2020)
Acknowledgements
The authors (A. Jeyaseelan and N. Viswanathan) thank the Council of Scientific and Industrial Research (CSIR) (F.No. 01(2965)/19/EMR-II), New Delhi, India for the financial support to carry out this research work. The authors are grateful to the Researchers Supporting Project Number (RSP-2021/8), King Saud University, Riyadh, Saudi Arabia for the financial support.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Jeyaseelan, A., Viswanathan, N., Naushad, M. et al. Fabrication of Multi-functionalized Graphene Oxide Doped Alginate Hybrid Spheres for Enhanced Fluoride Adsorption. J Inorg Organomet Polym 32, 216–228 (2022). https://doi.org/10.1007/s10904-021-02163-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10904-021-02163-2