Skip to main content
SpringerLink
Log in

Thermal Decomposition of Ammonium Perchlorate in the Presence of Cobalt Hydroxyl@Nano-Porous Polyaniline

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

In this report, nanoporous polyaniline (NP-PANi) as an intrinsic conductive polymer (ICPs) was sonochemically synthesized and coated by Cobalt Hydroxyl nanoparticles using precipitation method. The prepared Cobalt Hydroxyl@NP-PANi (CoPANi) merged two separated peaks of AP into a width peak revealed at 297 °C, and drastically increased the area under the peak about 90–334%. Dependency of activation energy (Eα) to the reaction progress (α) was investigated by Starink method and results showed that in the presence of CoPANi throughout the reaction, Eα of AP decomposition was completely shifted to the lower values. The thermal decomposition mechanisms of samples were evaluated by Complementary method using a MATLAB code. The best decomposition reaction model obtained for AP was Avrami Erofeyev (A2) which CoPANi changed it to (A4); this caused Ea reduced from 161 (KJ/mol) to 113 (KJ/mol). Reaction rate constant, pre-exponential factor, Characteristic temperatures (TSADT and Tb) and thermodynamic parameters have been also calculated, the noted parameters presented a descending trend when the CoPANi was used. As the results confirmed the strong modifying effect of Cobalt Hydroxyl@NP-PANi on AP decomposition reaction, this report would be helpful for further application of M(OH)x@ICPs as a new family of burning rate modifier materials used for decomposition of energetic material.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. S.G. Hosseini, E. Ayoman, A. Kashi, Part. Sci. Technol. 36, 7581 (2018)

    Article  CAS  Google Scholar 

  2. H. Kumar, P.N. Tengli, V.K. Mishra, P. Tripathi, A. Bhushan, P.K. Mishra, RSC Adv. 7, 36594 (2017)

    Article  CAS  Google Scholar 

  3. J. Wang, W. Zhang, Z. Zheng, Y. Gao, K. Ma, J. Ye, Y. Yang, J. Alloys Compd. 724, 720 (2017)

    Article  CAS  Google Scholar 

  4. M.R. Sovizi, G. Fakhrpour, A.R. Madram, Phys. Chem. Res. 4, 369 (2016)

    CAS  Google Scholar 

  5. M. Remanan, M. Kannan, R.S. Rao, S. Bhowmik, L. Varshney, M. Abraham, K. Jayanarayanan, J. Inorg. Organometall. Polym. Mater. 27, 1649 (2017)

    Article  CAS  Google Scholar 

  6. X. Fengjuan, S. Minmei, P. Lei, L. Yunjun, Z. Junchai, J. Inorg. Organometall. Polym. Mater. 21, 175 (2011)

    Article  CAS  Google Scholar 

  7. S. Vyazovkin, C.A. Wight, Chem. Mater. 11, 3386 (1999)

    Article  CAS  Google Scholar 

  8. R. Bogusz, P. Magnuszewska, B. Florczak, A. Maranda, K. Drożdżewska, Cent. Eur. J. Energ. Mater. 13, 1051 (2016)

    Article  CAS  Google Scholar 

  9. S.G. Hosseini, R. Abazari, RSC Adv. 5, 96777 (2015)

    Article  CAS  Google Scholar 

  10. N.M. Juibari, A. Eslami, J. Thermal Anal. Calorim. 128, 115 (2017)

    Article  CAS  Google Scholar 

  11. Q.-L. Yan, F.-Q. Zhao, K.K. Kuo, X.-H. Zhang, S. Zeman, L.T. DeLuca, Prog. Energy Combust. Sci. 57, 75 (2016)

    Article  Google Scholar 

  12. X. Zheng, P. Li, S. Zheng, Y. Zhang, Powder Technol. 268, 446 (2014)

    Article  CAS  Google Scholar 

  13. W. Chen, F. Li, J. Liu, H. Song, J. Yu, Chin. J. Catal. 26, 1073 (2005)

    CAS  Google Scholar 

  14. J. Zhu, H. Chen, B. Xie, X. Yang, L. Lu, X. Wang, Chin. J. Catal. 25, 637 (2004)

    CAS  Google Scholar 

  15. Z. Ma, F. Li, P. Cui, H. Bai, Chin. J. Catal. 24, 795 (2003)

    CAS  Google Scholar 

  16. X. Cao, F. Li, Y. Yang, J. Liu, Chin. J. Catal. 27, 157 (2006)

    CAS  Google Scholar 

  17. L. Tan, J. Xu, X. Zhang, Z. Hang, Y. Jia, S.J.A.S.S. Wang, Appl. Surf. Sci. 356, 447 (2015)

    Article  CAS  Google Scholar 

  18. W. Wang, D.J.R.A. Zhang, RSC Adv. 8, 32221 (2018)

    Article  CAS  Google Scholar 

  19. M. Chawla, R. Dubey, G. Singh, S.K. Sengupta, P.F. Siril, Thermochim. Acta 654, 130 (2017)

    Article  CAS  Google Scholar 

  20. X. Jing, S. Song, J. Wang, L. Ge, S. Jamil, Q. Liu, T. Mann, Y. He, M. Zhang, H. Wei, Powder Technol. 217, 624 (2012)

    Article  CAS  Google Scholar 

  21. Y. Zhao, X. Xu, Y. Zhao, H. Zhou, J. Li, H. Jin, J. Alloy. Compd. 654, 523 (2016)

    Article  CAS  Google Scholar 

  22. M.J.R. Cardoso, M.F.S. Lima, D.M. Lenz, Mater. Res. 10, 425 (2007)

    Article  CAS  Google Scholar 

  23. J. Stejskal, I. Sapurina, Pure Appl. Chem. 77, 815 (2005)

    Article  CAS  Google Scholar 

  24. H. Zeghioud, S. Lamouri, Y. Mahmoud, T. Hadj-Ali, J. Serb. Chem. Soc. 80, 1435 (2015)

    Article  CAS  Google Scholar 

  25. A. Zięba, A. Drelinkiewicz, E. Konyushenko, J. Stejskal, Appl. Catal. A 383, 169 (2010)

    Article  CAS  Google Scholar 

  26. S. Vyazovkin, Thermochim. Acta 355, 155 (2000)

    Article  CAS  Google Scholar 

  27. L. Zhang, M. Huang, C. Zhou, Am. J. Anal. Chem. 4, 749 (2013)

    Article  CAS  Google Scholar 

  28. M. Starink, Thermochim. Acta 404, 163 (2003)

    Article  CAS  Google Scholar 

  29. M. Abd-Elghany, T.M. Klapötke, A. Elbeih, S. Zeman, J. Anal. Appl. Pyrol. 126, 267 (2017)

    Article  CAS  Google Scholar 

  30. H.E. Kissinger, J. Res. Natl. Bur. Stand. 57, 217 (1956)

    Article  CAS  Google Scholar 

  31. M. Sovizi, S. Hajimirsadeghi, B. Naderizadeh, J. Hazard. Mater. 168, 1134 (2009)

    Article  CAS  PubMed  Google Scholar 

  32. M. Sovizi, J. Therm. Anal. Calorim. 102, 285 (2010)

    Article  CAS  Google Scholar 

  33. S. Ebrahimi, A. Shakeri, T. Alizadeh, ChemistrySelect 3, 11103 (2018)

    Article  Google Scholar 

  34. D. Zhang, D. Wang, X. Zong, G. Dong, Y. Zhang, Sens. Actuat. B 262, 531 (2018)

    Article  CAS  Google Scholar 

  35. C.M. Correa, R. Faez, M.A. Bizeto, F.F. Camilo, Rsc Adv. 2, 3088 (2012)

    Article  CAS  Google Scholar 

  36. H. Gao, G. Wang, M. Yang, L. Tan, J. Yu, Nanotechnology 23, 015607 (2011)

    Article  CAS  Google Scholar 

  37. X. Lei, Z. Shi, X. Wang, T. Wang, J. Ai, P. Shi, R. Xue, H. Guo, W. Yang, Colloids Surf. A 549, 76 (2018)

    Article  CAS  Google Scholar 

  38. Y. Zhang, C. Meng, J. Alloy. Compd. 674, 259 (2016)

    Article  CAS  Google Scholar 

  39. A.K. Galwey, R. Kinetics, Mech. Catal. 114, 1 (2015)

    CAS  Google Scholar 

  40. F. Yakuphanoglu, B. Şenkal, J. Phys. Chem. C 111, 1840 (2007)

    Article  CAS  Google Scholar 

  41. J. Wang, Y. Li, H. Wang, T. Tian, S. Zhu, J. Zhou, X. Wu, W. Qin, Eur. J. Inorg. Chem. 2017, 3154 (2017)

    Article  CAS  Google Scholar 

  42. E. Alizadeh-Gheshlaghi, B. Shaabani, A. Khodayari, Y. Azizian-Kalandaragh, R. Rahimi, Powder Technol. 217, 330 (2012)

    Article  CAS  Google Scholar 

  43. A.A. Vargeese, K. Muralidharan, Appl. Catal. A 447, 171 (2012)

    Article  CAS  Google Scholar 

  44. F. Azimfar, I. Kohsari, S. Pourmortazavi, J. Inorg. Organomet. Polym. Mater. 19, 181 (2009)

    Article  CAS  Google Scholar 

  45. M.R. Sovizi, G. Fakhrpour, A.R. Madram, J. Therm. Anal. Calorim. 129, 401 (2017)

    Article  CAS  Google Scholar 

  46. M. León, E. Díaz, A. Vega, S. Ordóñez, Chem. Eng. J. 175, 341 (2011)

    Article  CAS  Google Scholar 

  47. A.W. Coats, J. Redfern, Nature 201, 68 (1964)

    Article  CAS  Google Scholar 

  48. A. Khawam, D.R. Flanagan, J. Phys. Chem. B 109, 10073 (2005)

    Article  CAS  PubMed  Google Scholar 

  49. Z. Tonglai, H. Rongzu, X. Yi, L. Fuping, Thermochim. Acta 244, 171 (1994)

    Article  Google Scholar 

  50. S. Chaturvedi, P.N. Dave, J. Saud. Chem. Soc. 17, 135 (2013)

    Article  CAS  Google Scholar 

  51. D. Hongzhen, L. Xiangyang, L. Guanpeng, X. Lei, L. Fengsheng, Chin. J. Chem. Eng. 16, 325 (2008)

    Article  Google Scholar 

  52. S. Jamil, X. Jing, J. Wang, J. Liu, M. Zhang, Mater. Res. Bull. 48, 4513 (2013)

    Article  CAS  Google Scholar 

  53. S. Lu, X. Jing, J. Liu, J. Wang, Q. Liu, Y. Zhao, S. Jamil, M. Zhang, L. Liu, J. Solid State Chem. 197, 345 (2013)

    Article  CAS  Google Scholar 

  54. A. Yu, W. Zhang, Y. Gao, Y. Chen, K. Ma, J. Ye, R. Shen, Y. Yang, Mater. Res. Bull. 97, 483 (2018)

    Article  CAS  Google Scholar 

  55. S.G. Hosseini, S.J.H. Toloti, K. Babaei, A. Ghavi, J. Therm. Anal. Calorim. 124, 1243 (2016)

    Article  CAS  Google Scholar 

  56. Y. Zhang, C. Meng, J. Alloys Compd. 674, 259 (2016)

    Article  CAS  Google Scholar 

  57. Y. Zongxue, C. Lifen, L. Lude, Y. Xujie, W. Xin, Chin. J. Catal. 30, 19 (2009)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. School of Chemistry, College of Science, University of Tehran, Tehran, Iran

    Sajjad Ebrahimi, Alireza Shakeri & Taher Alizadeh

Authors
  1. Sajjad Ebrahimi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Alireza Shakeri
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Taher Alizadeh
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Alireza Shakeri.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOCX 1655 KB)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ebrahimi, S., Shakeri, A. & Alizadeh, T. Thermal Decomposition of Ammonium Perchlorate in the Presence of Cobalt Hydroxyl@Nano-Porous Polyaniline. J Inorg Organomet Polym 29, 1716–1727 (2019). https://doi.org/10.1007/s10904-019-01133-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-019-01133-z

Keywords

Search

Navigation