Skip to main content
SpringerLink
Log in

A Nano Nickel (II) Metal–Organic Coordination Compound for Nano Nickel (II) Oxide: Sonochemical Synthesis and Characterization

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

A sonochemical method was used to synthesize a nickel (II) coordination complex, [Ni(phen)3](BF4)2·H2O}n (1) (phen = 1,10-phenamthroline), with particle sizes in the range of 40–120 nm. The new nanostructure was characterized by scanning electron microscopy (SEM), X-ray powder diffraction (PXRD), infrared, and elemental analyses. Compound 1 was structurally characterized by single-crystal X-ray diffraction, and the data show that the Ni(II) ions are coordinated by six N-donor atoms from three phen ligands. The charge was balanced by two tetrafluoroborate anions. The supramolecular features in these complexes are guided and controlled by weak directional intermolecular interactions. They are further extended into a three-dimensional (3-D) supramolecular structure by weak π–π directional intermolecular interactions. Cubic NiO nanoparticles with sizes of 5–40 nm were obtained by thermolysis of 1 at 180 °C.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  1. J.C. Bailar Jr., Prep. Inorg. React. 1, 1 (1964)

    CAS  Google Scholar 

  2. C. Janiak, J. Chem. Soc. Dalton Trans. 14, 2781 (2003)

    Article  CAS  Google Scholar 

  3. S. Kitagawa, S. Noro, Compreh. Coord. Chem. 7, 231 (2004)

    CAS  Google Scholar 

  4. W. Clegg, Compreh. Coord. Chem. 1, 579 (2004)

    CAS  Google Scholar 

  5. S. Kitagawa, R. Kitaura, S. Noro, Angew. Chem. Int. Ed. 43, 2334 (2004)

    Article  CAS  Google Scholar 

  6. C.N.R. Rao, S. Natarajan, R. Vaidhyanathan, Angew. Chem. Int. Ed. 43, 1466 (2004)

    Article  CAS  Google Scholar 

  7. N.W. Ockwig, O. Delgado-Friedrichs, M. O’Keeffe, O.M. Yaghi, Acc. Chem. Res. 38, 176 (2005)

    Article  CAS  PubMed  Google Scholar 

  8. U. Mueller, M. Schubert, F. Teich, H. Puetter, K. Schierle-Arndt, J. Pastre, J. Mater. Chem. 16, 626 (2006)

    Article  CAS  Google Scholar 

  9. B. Mirtamizdoust, Ultrason. Sonochem. 35, 263 (2017)

    Article  CAS  PubMed  Google Scholar 

  10. K.S. Suslick, Science 247, 1439 (1990)

    Article  CAS  PubMed  Google Scholar 

  11. A. Mehrani, A. Morsali, Y. Hanifehpour, S.W. Joo, Ultrason. Sonochem. 21, 1430 (2014)

    Article  CAS  PubMed  Google Scholar 

  12. B. Mirtamizdoust, Z. Trávníček, Y. Hanifehpour, P. Talemi, H. Hammud, S.W. Joo, Ultrason. Sonochem 34, 255 (2015)

    Article  CAS  Google Scholar 

  13. B. Mirtamizdoust, D. Bieńko, Y. Hanifehpour, E.R.T. Tiekink, V.T. Yilmaz, P. Talemi, S.W. Joo, J. Inorg. Organomet. Polym. 26, 819 (2016)

    Article  CAS  Google Scholar 

  14. A. Valipour, B. Mirtamizdoust, M. Ghaedi, F. Taghizadeh, P. Talemi, J. Inorg. Organomet. Polym. 26, 197 (2016)

    Article  CAS  Google Scholar 

  15. B. Shaabani, B. Mirtamizdoust, D. Viterbo, G. Croce, H. Hammud, P. Hojati-Lalemi, Z. A. Khandar, Anorg. Allg. Chem. 637, 713 (2011)

    Article  CAS  Google Scholar 

  16. B. Mirtamizdoust, B. Shaabani, S.W. Joo, D. Viterbo, G. Croce, Y. Hanifehpour, J. Inorg. Organomet. Polym. 22, 1397 (2012)

    Article  CAS  Google Scholar 

  17. B. Shaabani, B. Mirtamizdoust, M. Shadman, H.K. Fun, Z. Anorg. Allg. Chem. 635, 2642 (2009)

    CAS  Google Scholar 

  18. B. Mirtamizdoust, B. Shaabani, A. Khandar, H.K. Fun, S. Huang, M. Shadman, Z. P. Hojati-Talemi, Anorg. Allg. Chem. 638, 844 (2012)

    Article  CAS  Google Scholar 

  19. Y. Hanifehpour, B. Mirtamizdoust, S.W. Joo, J. Inorg. Organomet. Polym. 22, 916 (2012)

    Article  CAS  Google Scholar 

  20. Y. Hanifehpour, B. Mirtamizdoust, A.R. Farzam, S.W. Joo, J. Inorg. Organomet. Polym. 22, 957 (2012)

    Article  CAS  Google Scholar 

  21. B. Mirtamizdoust, S. Ali-Asgari, S.W. Joo, E. Maskani, Y. Hanifehpour, T.H. Oh, J. Inorg. Organomet. Polym. 23, 751 (2013)

    Article  CAS  Google Scholar 

  22. Y. Hanifehpour, A. Morsali, B. Mirtamizdoust, S.W. Joo, J. Mol. Struct. 1079, 67 (2015)

    Article  CAS  Google Scholar 

  23. B. Mirtamizdoust, M.S. Shalamzari, S. Behrouzi, M.H. Florencio, H.K. Fun, J. Inorg. Organomet. Polym. 22, 1358 (2012)

    Article  CAS  Google Scholar 

  24. Y. Hanifehpour, B. Mirtamizdoust, A. Morsali, S.W. Joo, Ultrason. Sonochem. 23, 275 (2015)

    Article  CAS  PubMed  Google Scholar 

  25. Y. Hanifehpour, B. Mirtamizdoust, A. Morsali, S.W. Joo, Ultrason. Sonochem. 31, 201 (2016)

    Article  CAS  PubMed  Google Scholar 

  26. G.H. Shahverdizadeh, F. Hakimi, B. Mirtamizdoust, A. Soudi, P. Hojati-Talemi, J. Inorg. Organomet. Polym. 22, 903 (2012)

    Article  CAS  Google Scholar 

  27. Y. Hanifehpour, V. Safarifard, A. Morsali, B. Mirtamizdoust, S.W. Joo, Ultrason. Sonochem. 23, 282 (2015)

    Article  CAS  PubMed  Google Scholar 

  28. Y. Hanifehpour, B. Mirtamizdoust, B. Khomami, S.W. Joo, Z. Anorg. Allg. Chem. 641, 2466 (2015)

    Article  CAS  Google Scholar 

  29. Y. Hanifehpour, B. Mirtamizdoust, M. Hatami, B. Khomami, S.W. Joo, J. Mol. Struct. 1091, 43 (2015)

    Article  CAS  Google Scholar 

  30. Mercury 1.4.1, Copyright Cambridge Crystallographic Data Centre,, 12 Union Road, Cambridge, CB2 1EZ, UK, 2001–2005.

  31. Bruker (2000). SHELXTL. Version 6.14. Bruker AXS Inc., Madison

  32. Bruker (2010). APEX2. Version 2010.3–0. Bruker AXS Inc., Madison

  33. Bruker (2009). SAINT. Version 7.68 A. Bruker AXS Inc., Madison

  34. Bruker (2008). SADABS. Version 2008/1. Bruker AXS Inc., Madison

  35. Bruker (2008). XPREP. Version 2008/2. Bruker AXS Inc., Madison

  36. G.M. Sheldrick, Acta Cryst. A64, 112–122 (2008)

    Article  CAS  Google Scholar 

  37. D.T. Cromer, J.T. Waber, International tables for X-ray crystallography. Vol. 4, Kynoch Press, Birmingham (1974), [Table 2.2 A].

    Google Scholar 

  38. L. Hashemi, A. Morsali, Ultrason. Sonochem. 24, 146 (2015)

    Article  CAS  PubMed  Google Scholar 

  39. K. Akhbari, S. Beheshti, A. Morsali, G. Bruno, H. Amiri Rudbari, Inorg. Chim. Acta. 423, 101 (2014)

    Article  CAS  Google Scholar 

  40. L. Hashemi, A. Morsali, Ultrason. Sonochem 21, 1417 (2014)

    Article  CAS  PubMed  Google Scholar 

  41. C.A. Hunter, J.K. Sanders, J. Am. Chem. Soc. 112, 5525 (1990)

    Article  CAS  Google Scholar 

  42. S. Uhlenbrock, C. Scharfschwerdt, M. Neumannt, G. Illing, H.J. Freund, J. Phys. 4, 7973 (1992)

    CAS  Google Scholar 

Download references

Acknowledgements

The kind support for this investigation by the University of Qom is gratefully acknowledged. This work was funded by grant NRF-2015-002423 from the National Research Foundation of Korea.

Author information

Authors and Affiliations

  1. School of Mechanical Engineering, WCU Nano Research Center, Yeungnam University, Gyeongsan, 712-749, South Korea

    Younes Hanifehpour & Sang Woo Joo

  2. Department of Chemistry, Faculty of Science, University of Qom, PO Box 37185-359, Qom, Iran

    Babak Mirtamizdoust & Saeed Anbarteh

  3. Department of Chemistry, Xi’an Jiaotong-Liverpool University, Suzhou, People’s Republic of China

    Ruiyao Wang

Authors
  1. Younes Hanifehpour
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Babak Mirtamizdoust
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ruiyao Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Saeed Anbarteh
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Sang Woo Joo
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Younes Hanifehpour, Babak Mirtamizdoust or Sang Woo Joo.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Hanifehpour, Y., Mirtamizdoust, B., Wang, R. et al. A Nano Nickel (II) Metal–Organic Coordination Compound for Nano Nickel (II) Oxide: Sonochemical Synthesis and Characterization. J Inorg Organomet Polym 27, 1045–1052 (2017). https://doi.org/10.1007/s10904-017-0554-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-017-0554-4

Keywords

Search

Navigation